Citation: Feng-Ge Wang, Xin Liu, Qian-Xi Lv, Bin Liu, Yong-Ming Chai, Bin Dong. Transition Metal Boride-Based Materials for Electrocatalytic Water Splitting[J]. Chinese Journal of Structural Chemistry, ;2022, 41(9): 220900. doi: 10.14102/j.cnki.0254-5861.2022-0117 shu

Transition Metal Boride-Based Materials for Electrocatalytic Water Splitting

Feng-Ge Wang ¹ ,
Xin Liu ¹ ,
Qian-Xi Lv ¹ ,
Bin Liu ^1,, ,
Yong-Ming Chai ¹ ,
Bin Dong ^1,,

1.
State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China

Author Bio: Feng-Ge Wang received her B.Eng. degree in Chemical Engineering and Process from Weifang University in 2020. She is currently a master's student in the research group of Associate Professors Dong Bin and Liu Bin at China University of Petroleum (East China). Her research interests focus on nanostructures for electrocatalysis
Xin Liu received her B.Eng. degree in Chemical Engineering and Technology from Qingdao University of Science and Technology in 2021. She is currently a master's student in chemical engineering at China University of Petroleum (East China). Her research interest covers electrocatalytic nanostructures
Qian-Xi Lv received his B.S. degree in Chemistry from China University of Petroleum (East China) in 2022. He is currently a M.S. student in Prof. Bin Dong's group at China University of Petroleum (East China). His research direction is electrolytic water catalyst
Dr. Bin Liu received his B.Eng. degree in Chemical Engineering and Process from China University of Petroleum (East China) in 2007, and Ph.D. degree in Chemical Engineering and Technology from China University of Petroleum (East China) in 2012. He is currently an associate professor at University of Petroleum (East China). His research interests include green petroleum refining process, clean oil hydrogenation catalyst and process, biomass efficient catalytic hydrogenation conversion, new energy catalytic conversion and waste green resource utilization
Prof. Yong-Ming Chai received his Ph.D. from China University of Petroleum (East China) in 2008. Now he is a professor in State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China). He was doing research as a visiting scholar in Marquette University from 2015.03 to 2016.03. His research interests are catalyst of hydrodesulfurization process of heavy oil and transition metal-based electrocatalysts
Dr. Bin Dong received his B.S. and Ph.D. from Lanzhou University in 2002 and 2008, respectively. He was doing research as a visiting scholar in Marquette University from 2014.03 to 2015.03. Now Dr. Dong is an Associate Professor in College of Chemistry and Chemical Engineering, China University of Petroleum (East China). His research interests mainly focus on the transition metal-based functional materials for energy conversion and storage including electrocatalysis and photoelectrocatalysis for small molecules
Corresponding author: Bin Liu, liubin@upc.edu.cn Bin Dong, dongbin@upc.edu.cn
Received Date: 10 May 2022
Accepted Date: 19 May 2022
Available Online: 26 May 2022

Figures(13)

Electrocatalytic water splitting to produce hydrogen is an eco-friendly way to achieve sustainable utilization of renewable energy.The industrial application of water electrolysis, which is severely limited by slow kinetic reactions on electrode surfaces, requires the development of highly reactive, low-cost and stable electrocatalytic materials. Transition metal borides/borates have recently emerged as promising electrocatalytic materials for catalyzing hydrogen/oxygen evolution reactions (HER/OER) in inexpensive electrolyzers. However, so far, there has been little comprehensive summary of transition metal borides/borates. Here, this review provides the latest research progress on transition metal borides/borates for electrocatalytic water splitting. The structural characteristics of transition metal borides/borates and their synthesis methods in recent years are discussed. Then, the theoretical and experimental progress of transition metal borides including single-metal borides, multi-metal borides, borate derived and other nanocomposites containing boron (boron-doped nanocomposites/substrate with boron) in electrocatalytic reaction and the role of boron in regulating electrocatalytic performance are further emphasized. Finally, the potential challenges and future prospects of transition metal borides/borates in electrocatalysis are presented.
- transition metal borides/borates,
- electrocatalysts,
- hydrogen evolution reaction (HER),
- oxygen evolution reaction (OER),
- overall water splitting
1. [1]
  Dong, B.; Xie, J. Y.; Wang, N.; Gao, W. K.; Ma, Y.; Chen, T. S.; Yan, X. T.; Li, Q. Z.; Zhou, Y. L.; Chai, Y. M. Zinc ion induced three-dimensional Co₉S₈ nano-neuron network for efficient hydrogen evolution. Renew. Energ. 2020, 157, 415-423. doi: 10.1016/j.renene.2020.05.057
2. [2]
  Radwan, A.; Jin, H.; He, D.; Mu, S. Design engineering, synthesis protocols, and energy applications of MOF-derived electrocatalysts. Nanomicro. Lett. 2021, 13, 132.
3. [3]
  Zhang, L. C.; Zhao, H. T.; Xu, S. R.; Liu, Q.; Li, T. S.; Luo, Y. L.; Gao, S. Y.; Shi, X. F.; Asiri, A.; Sun X. P. Recent advances in 1D electrospun nanocatalysts for electrochemical water splitting. Small Struct. 2021, 2, 2000048. doi: 10.1002/sstr.202000048
4. [4]
  Wang, Y.; Huang, J.; Wang, L.; She, H.; Wang, Q. Research progress of ferrite materials for photoelectrochemical water splitting. Chin. J. Struct. Chem. 2022, 41, 2201054-2201068.
5. [5]
  Zhang, J. Y.; Wang, H.; Tian, Y.; Yan, Y.; Xue, Q.; He, T.; Liu, H.; Wang, C.; Chen, Y.; Xia, B. Y. Anodic hydrazine oxidation assists energy-efficient hydrogen evolution over a bifunctional cobalt perselenide nanosheet electrode. Angew. Chem. Int. Ed. 2018, 57, 7649-7653. doi: 10.1002/anie.201803543
6. [6]
  Gong, L.; Yang, H.; Wang, H.; Qi, R.; Wang, J.; Chen, S.; You, B.; Dong, Z.; Liu, H.; Xia, B. Y. Corrosion formation and phase transformation of nickel-iron hydroxide nanosheets array for efficient water oxidation. Nano Res. 2021, 14, 4528-4533. doi: 10.1007/s12274-021-3366-3
7. [7]
  Long, X.; Meng, J.; Gu, J.; Ling, L.; Li, Q.; Liu, N.; Wang, K.; Li, Z. Interfacial engineering of NiFeP/NiFe-LDH heterojunction for efficient overall water splitting. Chin. J. Struct. Chem. 2022, 41, 2201019-2201024.
8. [8]
  Shao, L. Y.; Sun, H. M.; Miao, L. C.; Chen, X.; Han, M.; Sun, J. C.; Liu, S.; Li, L.; Cheng, F. Y.; Chen, J. Facile preparation of NH₂- functionalized black phosphorene for the electrocatalytic hydrogen evolution reaction. J. Mater. Chem. A 2018, 6, 2494-2499. doi: 10.1039/C7TA10884B
9. [9]
  Yang, Y.; Yu, Y.; Li, J.; Chen, Q.; Du, Y.; Rao, P.; Li, R.; Jia, C.; Kang, Z.; Deng, P.; Shen, Y.; Tian, X. Engineering ruthenium-based electrocatalysts for effective hydrogen evolution reaction. Nanomicro. Lett. 2021, 13, 160.
10. [10]
  Yang, S.; Qin, L.; Zhang, W.; Cao, R. The mechanism of water oxidation from mn-based heterogeneous electrocatalysts. Chin. J. Struct. Chem. 2022, 41, 2204022-2204033.
11. [11]
  Qin, J. F.; Yang, M.; Chen, T. S.; Dong, B.; Hou, S.; Ma, X.; Zhou, Y. N.; Yang, X. L.; Nan, J.; Chai, Y. M. Ternary metal sulfides MoCoNiS derived from metal organic frameworks for efficient oxygen evolution. Int. J. Hydrogen Energy 2020, 45, 2745-2753. doi: 10.1016/j.ijhydene.2019.11.156
12. [12]
  Huang, C. Q.; Yu, L.; Zhang, W.; Xiao, Q.; Zhou, J. Q.; Zhang, Y. L.; An, P. F.; Zhang, J.; Yu, Y. N-doped Ni-Mo based sulfides for high-efficiency and stable hydrogen evolution reaction. Appl. Catal. B 2020, 276, 119137. doi: 10.1016/j.apcatb.2020.119137
13. [13]
  Yuan, J.; Cheng, X.; Wang, H.; Lei, C.; Pardiwala, S.; Yang, B.; Li, Z.; Zhang, Q.; Lei, L.; Wang, S.; Hou, Y. A superaerophobic bimetallic selenides heterostructure for efficient industrial‑level oxygen evolution at ultra‑high current densities. Nanomicro. Lett. 2020, 12, 104.
14. [14]
  Li, M.; Feng, L. NiSe₂-CoS₂ with a hybrid nanorods and nanoparticles structure for efficient oxygen evolution reaction. Chin. J. Struct. Chem. 2022, 41, 2201019-2201024.
15. [15]
  Yan, T.; Zhang, X.; Liu, H.; Jin, Z. CeO₂ particles anchored to Ni₂P nanoplate for efficient photocatalytic hydrogen evolution. Chin. J. Struct. Chem. 2022, 41, 2201047-2201053.
16. [16]
  Shi, Y.; Li, M.; Yu, Y.; Zhang, B. Recent advances in nanostructured transition metal phosphides: synthesis and energy-related applications. Energy Environ. Sci. 2020, 13, 4564-4582. doi: 10.1039/D0EE02577A
17. [17]
  Li, P.; Hong, W.; Liu, W. Fabrication of large scale self-supported WC/Ni(OH)₂ electrode for high-current-density hydrogen evolution. Chin. J. Struct. Chem. 2021, 40, 1365-1371.
18. [18]
  Han, N.; Yang, K. R.; Lu, Z.; Li, Y.; Xu, W.; Gao, T.; Cai, Z.; Zhang, Y.; Batista, V. S.; Liu, W.; Sun, X. Nitrogen-doped tungsten carbide nanoarray as an efficient bifunctional electrocatalyst for water splitting in acid. Nat. Commun. 2018, 9, 924. doi: 10.1038/s41467-018-03429-z
19. [19]
  Shu, X.; Chen, S.; Pan, W.; Zhang, J. Cobalt nitride embedded holey N-doped graphene as advanced bifunctional electrocatalysts for Zn-air batteries and overall water splitting. Carbon 2020, 157, 234-243. doi: 10.1016/j.carbon.2019.10.023
20. [20]
  Saad, A.; Shen, H.; Cheng, Z.; Arbi, R.; Guo, B.; Hui, L. S.; Liang, K.; Liu, S.; Attfield, J. P.; Turak, A.; Wang, J.; Yang, M. Mesoporous ternary nitrides of earth-abundant metals as oxygen evolution electrocatalyst. Nanomicro. Lett. 2020, 12, 79.
21. [21]
  Guo, B. Y.; Zhang, X. Y.; Ma, X.; Chen, T. S.; Chen, Y.; Wen, M. L.; Qin, J. F.; Nan, J.; Chai, Y. M.; Dong, B. RuO₂/Co₃O₄ nanocubes based on Ru ions impregnation into Prussian blue precursor for oxygen evolution. Inter. J. Hydrogen Energy 2020, 45, 9575-9582. doi: 10.1016/j.ijhydene.2020.01.182
22. [22]
  Xie, J. Y.; Fan, R. Y.; Fu, J. Y.; Zhen, Y. N.; Li, M. X.; Liu, H. J.; Ma, Y.; Wang, F. L.; Chai, Y. M.; Dong, B. Double doping of V and F on Co₃O₄ nanoneedles as efficient electrocatalyst for oxygen evolution. Int. J. Hydrogen Energy 2021, 46, 19962-19970. doi: 10.1016/j.ijhydene.2021.03.141
23. [23]
  Fu, C.; Wang, Y.; Huang, J. Hybrid of quaternary layered double hydroxides and carbon nanotubes for oxygen evolution reaction. Chin. J. Struct. Chem. 2020, 39, 1807-1816.
24. [24]
  Li, R.; Xu, H.; Yang, P.; Wang, D.; Li, Y.; Xiao, L.; Lu, X.; Wang, B.; Zhang, J.; An, M. Synergistic interfacial and doping engineering of hetero-structured NiCo(OH)_x-CoyW as an efficient alkaline hydrogen evolution electrocatalyst. Nanomicro. Lett. 2021, 13, 120.
25. [25]
  Shi, L.; Chen, H.; Liang, X.; Liu, Y.; Zou, X. Theoretical insights into nonprecious oxygen-evolution active sites in Ti-Ir-based perovskite solid solution electrocatalysts. J. Mater. Chem. A 2020, 8, 218-223. doi: 10.1039/C9TA10059H
26. [26]
  Chen, D.; Qiao, M.; Liu, Y. R.; Hao, L.; Liu, D.; Dong, C. L.; Li, Y.; Wang, S. Preferential cation vacancies in perovskite hydroxide for the oxygen evolution reaction. Angew. Chem. Int. Ed. 2018, 57, 8691-8696. doi: 10.1002/anie.201805520
27. [27]
  Chen, Y.; Li, H.; Wang, J.; Du, Y.; Xi, S.; Sun, Y.; Sherburne, M.; Ager, J. W.; Fisher, A. C.; Xu, Z. J. Exceptionally active iridium evolved from a pseudo-cubic perovskite for oxygen evolution in acid. Nat. Commun. 2019, 10, 572. doi: 10.1038/s41467-019-08532-3
28. [28]
  Guo, H. P.; Ruan, B. Y.; Luo, W. B.; Deng, J. Q.; Wang, J. Z.; Liu, H. K.; Dou, S. X. Ultrathin and edge-enriched holey nitride nanosheets as bifunctional electrocatalysts for the oxygen and hydrogen evolution reactions. ACS Catal. 2018, 8, 9686-9696. doi: 10.1021/acscatal.8b01821
29. [29]
  Li, R. C.; Zhou, D.; Luo, J. X.; Xu, W. M.; Li, J. W.; Li, S. S.; Cheng, P. P.; Yuan, D. S. The urchin-like sphere arrays Co₃O₄ as a bifunctional catalyst for hydrogen evolution reaction and oxygen evolution reaction. J. Power Sources 2017, 341, 250-256. doi: 10.1016/j.jpowsour.2016.10.096
30. [30]
  Chen, H.; Zou, X. X. Intermetallic borides: structures, synthesis and applications in electrocatalysis. Inorg. Chem. Front. 2020, 7, 2248-2264. doi: 10.1039/D0QI00146E
31. [31]
  Gupta, S.; Patel, N.; Fernandes, R.; Kadrekar, R.; Dashora, A.; Yadav, A. K.; Bhattacharyya, D.; Jha, S. N.; Miotello, A.; Kothari, D. C. Co-Ni-B nanocatalyst for efficient hydrogen evolution reaction in wide pH range. Appl. Catal. B 2016, 192, 126-133. doi: 10.1016/j.apcatb.2016.03.032
32. [32]
  Gupta, S.; Patel, N.; Miotello, A.; Kothari, D. C. Cobalt-boride: an efficient and robust electrocatalyst for hydrogen evolution reaction. J. Power Sources 2015, 279, 620-625. doi: 10.1016/j.jpowsour.2015.01.009
33. [33]
  Masa, J.; Andronescu, C.; Antoni, H.; Sinev, I.; Seisel, S.; Elumeeva, K.; Barwe, S.; Marti-Sanchez, S.; Arbiol, R. C.; Muhler, S. W. Role of boron and phosphorus in enhanced electrocatalytic oxygen evolution by nickel borides and nickel phosphides. ChemElectroChem 2019, 6, 235-240. doi: 10.1002/celc.201800669
34. [34]
  Hulm, J. K.; Matthias, B. T. New superconducting borides and nitrides. Phys. Rev. 1951, 82, 273-274. doi: 10.1103/PhysRev.82.273
35. [35]
  Hardy, G. F.; Hulm, J. K. The superconductivity of some transition metal compounds. Phys. Rev. 1954, 93, 1004-1016. doi: 10.1103/PhysRev.93.1004
36. [36]
  Chung, H. Y.; Weinberger, M. B.; Levine, J. B.; Kavner, A.; Yang, J. M.; Tolbert, S. H.; Kaner, R. B. Synthesis of ultra-incompressible superhard rhenium diboride at ambient pressure. Science 2007, 316, 436-438. doi: 10.1126/science.1139322
37. [37]
  Gabani, S.; Flachbart, K.; Siemensmeyer, K.; Mori, T. Magnetism and superconductivity of rare earth borides. J. Alloy. Compd. 2020, 821, 153201. doi: 10.1016/j.jallcom.2019.153201
38. [38]
  Sussardi, A.; Tanaka, T.; Khan, A. U.; Schlapbach, L.; Mori, T. Enhanced thermoelectric properties of samarium boride. J. Materiomics 2015, 1, 196-204. doi: 10.1016/j.jmat.2015.07.007
39. [39]
  Chen, Z. J.; Duan, X. G.; Wei, W.; Wang, S. B.; Zhang, Z. J.; Ni, B. J. Boride-based electrocatalysts: emerging candidates for water splitting. Nano Res. 2020, 13, 293-314. doi: 10.1007/s12274-020-2618-y
40. [40]
  Gupta, S.; Patel, M. K.; Miotello, A.; Patel, N. Metal boride-based catalysts for electrochemical water-splitting: a review. Adv. Funct. Mater. 2019, 30, 1906481.
41. [41]
  Jiang, Y. Y.; Lu, Y. Z. Designing transition-metal-boride-based electrocatalysts for applications in electrochemical water splitting. Nanoscale 2020, 12, 9327-9351. doi: 10.1039/D0NR01279C
42. [42]
  Guo, F. F.; Wu, Y. Y.; Ai, X.; Chen, H.; Li, G. D.; Chen, W.; Zou, X. X. A class of metal diboride electrocatalysts synthesized by a molten salt-assisted reaction for the hydrogen evolution reaction. Chem. Commun. 2019, 55, 8627-8630. doi: 10.1039/C9CC03638E
43. [43]
  Chen, Y. L.; Yu, G. T.; Chen, W.; Liu, Y. P.; Li, G. D.; Zhu, P. W.; Tao, Q.; Li, Q. J.; Liu, J. W.; Shen, X. P.; Li, H.; Huang, X. R.; Wang, D. J.; Asefa, T.; Zou, X. X. Highly active, nonprecious electrocatalyst comprising borophene subunits for the hydrogen evolution reaction. J. Am. Chem. Soc. 2017, 139, 12370-12373. doi: 10.1021/jacs.7b06337
44. [44]
  Jothi, P. R.; Zhang, Y.; Yubuta, K.; Culver, D. B.; Conley, M.; Fokwa, B. P. T. Abundant vanadium diboride with graphene-like boron layers for hydrogen evolution. ACS Appl. Energy Mater. 2019, 2, 176-181. doi: 10.1021/acsaem.8b01615
45. [45]
  Park, C. H.; Zhang, Y.; Scheifers, J. P.; Jothi, P. R.; Encinas, A.; Fokwa, B. P. T. Graphene- and phosphorene-like boron layers with contrasting activities in highly active Mo₂B₄ for hydrogen evolution. J. Am. Chem. Soc. 2017, 139, 12915-12918. doi: 10.1021/jacs.7b07247
46. [46]
  Park, H.; Zhang, Y. M.; Lee, E.; Shankhari, P.; Fokwa, B. P. T. High-current-density HER electrocatalysts: graphene-like boron layer and tungsten as key ingredients in metal diborides. ChemSusChem 2019, 12, 3726-3731. doi: 10.1002/cssc.201901301
47. [47]
  Yuan, W. Y.; Zhao, X. S.; Hao, W. J.; Li, J. X.; Wang, L. C.; Ma, X. H.; Guo, Y. H. Performance of surface-oxidized Ni₃B, Ni₂B, and NiB₂ electrocatalysts for overall water splitting. ChemElectroChem 2019, 6, 764-770. doi: 10.1002/celc.201801354
48. [48]
  Sun, J. K.; Zhang, W.; Wang, S. Y.; Ren, Y. B.; Liu, Q. Y.; Sun, Y. F.; Tang, L.; Guo, J. X.; Zhang, X. Ni-Co-B nanosheets coupled with reduced graphene oxide towards enhanced electrochemical oxygen evolution. J. Alloy. Compd. 2019, 776, 511-518. doi: 10.1016/j.jallcom.2018.10.296
49. [49]
  Chen, H. Y.; Ouyang, S.; Zhao, M.; Li, Y. X.; Ye, J. H. Synergistic activity of Co and Fe in amorphous Cox-Fe-B catalyst for efficient oxygen evolution reaction. ACS Appl. Mater. Interfaces 2017, 9, 40333-40343. doi: 10.1021/acsami.7b13939
50. [50]
  Masa, J.; Piontek, S.; Wilde, P.; Antoni, H.; Eckhard, T.; Chen, Y. T.; Muhler, M.; Apfel, U. P.; Schuhmann, W. Ni-metalloid (B, Si, P, As, and Te) alloys as water oxidation electrocatalysts. Adv. Energy Mater. 2019, 9, 1900796.
51. [51]
  Jiang, W. J.; Niu, S.; Tang, T.; Zhang, Q. H.; Liu, X. Z.; Zhang, Y.; Chen, Y. Y.; Li, J. H.; Gu, L.; Wan, L. J.; Hu, J. S. Crystallinity-modulated electrocatalytic activity of a nickel(II) borate thin layer on Ni₃B for efficient water oxidation. Angew. Chem. Int. Ed. 2017, 56, 6572-6577. doi: 10.1002/anie.201703183
52. [52]
  Wang, N.; Xu, A.; Ou, P. F.; Hung, S. F.; Ozden, A.; Lu, Y. R.; Abed, J.; Wang, Z. Y.; Yan, Y.; Sun, M. J.; Xia, Y. J.; Han, M.; Han, J. R.; Yao, K. L.; Wu, F. Y.; Chen, P. H.; Vomiero, A.; Seifitokaldani, A.; Sun, X. H.; Sinton, D.; Liu, Y. C.; Sargent, E. H.; Liang, H. Y. Boride-derived oxygen-evolution catalysts. Nat. Commun. 2021, 12, 6089. doi: 10.1038/s41467-021-26307-7
53. [53]
  Li, J. H.; Chen, H.; Liu, Y. P.; Gao, R. Q.; Zou, X. X. In situ structural evolution of a nickel boride catalyst: synergistic geometric and electronic optimization for the oxygen evolution reaction. J. Mater. Chem. A 2019, 7, 5288-5294. doi: 10.1039/C9TA00489K
54. [54]
  Guo, F. F.; Wu, Y. Y.; Chen, H.; Liu, Y. P.; Yang, L.; Ai, X.; Zou, X. X. High-performance oxygen evolution electrocatalysis by boronized metal sheets with self-functionalized surfaces. Energy Environ. Sci. 2019, 12, 684-692. doi: 10.1039/C8EE03405B
55. [55]
  Li, J.; Liu, Y.; Chen, H.; Zhang, Z.; Zou, X. Design of a multilayered oxygen-evolution electrode with high catalytic activity and corrosion resistance for saline water splitting. Adv. Funct. Mater. 2021, 31, 2101820. doi: 10.1002/adfm.202101820
56. [56]
  Wang, L. C.; Li, J. X.; Zhao, X. S.; Hao, W. J.; Ma, X. H.; Li, S. J.; Guo, Y. H. Surface-activated amorphous iron borides (Fe_xB) as efficient electrocatalysts for oxygen evolution reaction. Adv. Mater. Interfaces 2019, 6, 1801690. doi: 10.1002/admi.201801690
57. [57]
  Gong, Z. C.; Liu, R.; Gong, H. S.; Ye, G. L.; Liu, J. J.; Dong, J. C.; Liao, J. W.; Yan, M. M.; Liu, J. B.; Huang, K.; Xing, L. L.; Liang, J. F.; He, Y. M.; Fei, H. L. Constructing a graphene-encapsulated amorphous/crystalline heterophase NiFe alloy by microwave thermal shock for boosting the oxygen evolution reaction. ACS. Catal. 2021, 11, 12284-12292. doi: 10.1021/acscatal.1c03333
58. [58]
  Sun, H. M.; Xu, X. B.; Yan, Z. H.; Chen, X.; Jiao, L. F.; Cheng, F. Y.; Chen, J. Superhydrophilic amorphous Co-B-P nanosheet electrocatalysts with Pt-like activity and durability for the hydrogen evolution reaction. J. Mater. Chem. A 2018, 6, 22062-22069. doi: 10.1039/C8TA02999G
59. [59]
  He, T.; Nsanzimana, J. M. V.; Qi, R. J.; Zhang, J. Y.; Miao, M.; Yan, Y.; Qi, K.; Liu, H. F.; Xia, B. Y. Synthesis of amorphous boride nanosheets by the chemical reduction of prussian blue analogs for efficient water electrolysis. J. Mater. Chem. A 2018, 6, 23289-23294. doi: 10.1039/C8TA09609K
60. [60]
  Masa, J.; Weide, P.; Peeters, D.; Sinev, I.; Xia, W.; Sun, Z. Y.; Somsen, C.; Muhler, M.; Schuhmann, W. Amorphous cobalt boride (Co₂B) as a highly efficient nonprecious catalyst for electrochemical water splitting: oxygen and hydrogen evolution. Adv. Energy Mater. 2016, 6, 1502313. doi: 10.1002/aenm.201502313
61. [61]
  Xu, N.; Cao, G. X.; Chen, Z. J.; Kang, Q.; Dai, H. B.; Wang, P. Cobalt nickel boride as an active electrocatalyst for water splitting. J. Mater. Chem. A 2017, 5, 12379-12384. doi: 10.1039/C7TA02644G
62. [62]
  Cao, G. X.; Xu, N.; Chen, Z. J.; Kang, Q.; Dai, H. B.; Wang, P. Cobalt-tungsten-boron as an active electrocatalyst for water electrolysis. ChemistrySelect. 2017, 2, 6187-6193. doi: 10.1002/slct.201701459
63. [63]
  Jiang, J.; Wang, M.; Yan, W. S.; Liu, X. F.; Liu, J. X.; Yang, J. L.; Sun, L. C. Highly active and durable electrocatalytic water oxidation by a NiB_0.45/NiO_x core-shell heterostructured nanoparticulate film. Nano Energy 2017, 38, 175-184. doi: 10.1016/j.nanoen.2017.05.045
64. [64]
  Masa, J.; Sinev, I.; Mistry, H.; Ventosa, E.; Mata, M.; Arbiol, J.; Muhler, M.; Roldan, C. B.; Schuhmann, W. Ultrathin high surface area nickel boride (Ni_xB) nanosheets as highly efficient electrocatalyst for oxygen evolution. Adv. Energy Mater. 2017, 7, 1700381. doi: 10.1002/aenm.201700381
65. [65]
  Park, H.; Encinas, A.; Scheifers, J. P.; Zhang, Y. M.; Fokwa, B. P. T. Boron-dependency of molybdenum boride electrocatalysts for the hydrogen evolution reaction. Angew. Chem. Int. Ed. 2017, 56, 5575-5578. doi: 10.1002/anie.201611756
66. [66]
  Li, H.; Wen, P.; Li, Q.; Dun, C.; Xing, J.; Lu, C.; Adhikari, S.; Jiang, L.; Carroll, D. L.; Geyer, S. M. Earth-abundant iron diboride (FeB₂) nanoparticles as highly active bifunctional electrocatalysts for overall water splitting. Adv. Energy Mater. 2017, 7, 1700513. doi: 10.1002/aenm.201700513
67. [67]
  Zhang, R. Q.; Liu, H. X.; Wang, C. F.; Wang, L. C.; Yang, Y. J.; Guo, Y. H. Electroless plating of transition metal boride with high boron content as superior HER electrocatalyst. ChemCatChem 2020, 12, 3068-3075. doi: 10.1002/cctc.202000315
68. [68]
  Ma, X. Z.; Wen, J.; Zhang, S.; Yuan, H. R.; Li, K. Y.; Yan, F.; Zhang, X. T.; Chen, Y. J. Crystal Co_xB (x = 1-3) synthesized by a ball-milling method as high-performance electrocatalysts for the oxygen evolution reaction. ACS Sustain. Chem. Eng. 2017, 5, 10266-10274. doi: 10.1021/acssuschemeng.7b02281
69. [69]
  Ai, X.; Zou, X.; Chen, H.; Su, Y. T.; Feng, X. L.; Li, Q. J.; Liu, Y. P.; Zhang, Y.; Zou, X. X. Transition-metal-boron intermetallics with strong interatomic d-sp orbital hybridization for high-performance electrocatalysis. Angew. Chem. Int. Ed. 2020, 59, 3961-3965. doi: 10.1002/anie.201915663
70. [70]
  Zou, X.; Wang, L.; Ai, X.; Chen, H.; Zou, X. X. Crystal phase-dependent electrocatalytic hydrogen evolution performance of ruthenium-boron intermetallics. Chem. Commun. 2020, 56, 3061-3064. doi: 10.1039/D0CC00070A
71. [71]
  Xu, Q. C.; Liu, Y.; Jiang, H.; Hu, Y. J.; Liu, H. L.; Li, C. Z. Unsatu-rated sulfur edge engineering of strongly coupled MoS₂ nanosheet-carbon macroporous hybrid catalyst for enhanced hydrogen generation. Adv. Energy Mater. 2019, 9, 1802553. doi: 10.1002/aenm.201802553
72. [72]
  Dinca, M.; Surendranath, Y.; Nocera, D. G. Nickel-borate oxygen-evolving catalyst that functions under benign conditions. PNAS 2010, 107, 10337-10341. doi: 10.1073/pnas.1001859107
73. [73]
  Surendranath, Y.; Dinca, M.; Nocera, D. G. Electrolyte-dependent electrosynthesis and activity of cobalt-based water oxidation catalysts. J. Am. Chem. Soc. 2009, 131, 2615-2620. doi: 10.1021/ja807769r
74. [74]
  Nsanzimana, J. M. V.; Peng, Y. C.; Xu, Y. Y.; Thia, L.; Wang, C.; Xia, B. Y.; Wang, X. An efficient and earth-abundant oxygen-evolving electrocatalyst based on amorphous metal borides. Adv. Energy Mater. 2018, 8, 1701475. doi: 10.1002/aenm.201701475
75. [75]
  Zhang, J.; Li, X. X.; Liu, Y. T.; Zeng, Z. W.; Cheng, X.; Wang, Y. D.; Tu, W. M.; Pan, M. Bi-metallic boride electrocatalysts with enhanced activity for the oxygen evolution reaction. Nanoscale 2018, 10, 11997-12002. doi: 10.1039/C8NR02198H
76. [76]
  Gupta, S.; Patel, N.; Fernandes, R.; Hanchate, S.; Miotello, A.; Kothari, D. C. Co-Mo-B nanoparticles as a non-precious and efficient bifunctional electrocatalyst for hydrogen and oxygen evolution. Electrochim. Acta 2017, 232, 64-71. doi: 10.1016/j.electacta.2017.02.100
77. [77]
  Schuch, J.; Klemenz, S.; Schuldt, P.; Zieschang, A. M.; Dolique, S.; Connor, P.; Kaiser, B.; Kramm, U. I.; Albert, B.; Jaegermann, W. Efficient oxygen evolution electrocatalyst by incorporation of nickel into nanoscale dicobalt boride. ChemCatChem 2021, 13, 1772-1780. doi: 10.1002/cctc.202002030
78. [78]
  Yang, Y. S.; Zhuang, L. Z.; Rufford, T. E.; Wang, S. B.; Zhu, Z. H. Efficient water oxidation with amorphous transition metal boride catalysts synthesized by chemical reduction of metal nitrate salts at room temperature. RSC Adv. 2017, 7, 32923-32930. doi: 10.1039/C7RA02558K
79. [79]
  Guo, Y. H.; Zhang, R. Q.; Hao, W. J.; Zhang, J. K.; Yang, Y. J. Multifunctional Co-B-O@Co_xB catalysts for efficient hydrogen generation. Int. J. Hydrogen Energy 2020, 45, 380-390. doi: 10.1016/j.ijhydene.2019.09.008
80. [80]
  Zeng, M.; Wang, H.; Zhao, C.; Wei, J. K.; Qi, K.; Wang, W. L.; Bai, X. D. Nanostructured amorphous nickel boride for high-efficiency electrocatalytic hydrogen evolution over a broad pH range. ChemCatChem 2016, 8, 708-712. doi: 10.1002/cctc.201501221
81. [81]
  Wang, C.; Zhai, P. L.; Xia, M. Y.; Wu, Y. Z.; Zhang, B.; Li, Z. W.; Ran, L.; Gao, J. F.; Zhang, X. M.; Fan, Z. Z.; Sun, L. C.; Hou, J. G. Engineering lattice oxygen activation of iridium clusters stabilized on amorphous bimetal borides array for oxygen evolution reaction. Angew. Chem. Int. Ed. 2021, 60, 27126-27134. doi: 10.1002/anie.202112870
82. [82]
  Li, Y.; Jiang, X. L.; Tang, M. Y.; Zheng, Q. J.; Huo, Y.; Xie, F. Y.; Lin, D. M. A high-performance oxygen evolution electrocatalyst based on partially amorphous bimetallic cobalt iron boride nanosheet. Int. J. Hydrogen Energy 2020, 45, 28586-28597. doi: 10.1016/j.ijhydene.2020.07.140
83. [83]
  Hao, W. J.; Wu, R. B.; Zhang, R. Q.; Ha, Y.; Chen, Z. L.; Wang, L. C.; Yang, Y. J.; Ma, X. H.; Sun, D. L.; Fang, F.; Guo, Y. H. Electroless plating of highly efficient bifunctional boride-based electrodes toward practical overall water splitting. Adv. Energy Mater. 2018, 8, 1801372. doi: 10.1002/aenm.201801372
84. [84]
  Chen, Z. J.; Kang, Q.; Cao, G. X.; Xu, N.; Dai, H. B.; Wang, P. Study of cobalt boride-derived electrocatalysts for overall water splitting. Int. J. Hydrogen Energy 2018, 43, 6076-6087. doi: 10.1016/j.ijhydene.2018.01.161
85. [85]
  Zhang, P. L.; Wang, M.; Yang, Y.; Yao, T. Y.; Han, H. X.; Sun, L. C. Electroless plated Ni-B films as highly active electrocatalysts for hydrogen production from water over a wide pH range. Nano Energy 2016, 19, 98-107. doi: 10.1016/j.nanoen.2015.11.020
86. [86]
  Yang, Y.; Wang, M.; Zhang, P. L.; Wang, W. H.; Han, H. X.; Sun, L. C. Evident enhancement of photoelectrochemical hydrogen production by electroless deposition of M-B (M = Ni, Co) catalysts on silicon nanowire arrays. ACS Appl. Mater. Interfaces 2016, 8, 30143-30151. doi: 10.1021/acsami.6b09600
87. [87]
  Kim, J.; Kim, H.; Kim, S. K.; Ahn, S. H. Electrodeposited amorphous Co-P-B ternary catalyst for hydrogen evolution reaction. J. Mater. Chem. A 2018, 6, 6282-6288. doi: 10.1039/C7TA11033B
88. [88]
  Wu, Y. H.; Gao, Y.; He, H. W.; Zhang, P. Novel electrocatalyst of nickel sulfide boron coating for hydrogen evolution reaction in alkaline solution. Appl. Surf. Sci. 2019, 480, 689-696. doi: 10.1016/j.apsusc.2019.03.025
89. [89]
  Mann, D. K.; Xu, J.; Mordvinova, N. E.; Yannello, V.; Ziouani, Y.; Gonzalez-Ballesteros, N.; Sousa, J. P. S.; Lebedev, O. I.; Kolen'ko, Y. V.; Shatruk, M. Electrocatalytic water oxidation over AlFe₂B₂. Chem. Sci. 2019, 10, 2796-2804. doi: 10.1039/C8SC04106G
90. [90]
  Lee, E.; Park, H.; Joo, H.; Fokwa, B. P. T. Unexpected correlation between boron chain condensation and hydrogen evolution reaction (HER) activity in highly active vanadium borides: enabling predictions. Angew. Chem. Int. Ed. 2020, 59, 11774-11778. doi: 10.1002/anie.202000154
91. [91]
  Carenco, S.; Portehault, D.; Boissiere, C.; Mezailles, N.; Sanchez, C. Nanoscaled metal borides and phosphides: recent developments and perspectives. Chem. Rev. 2013, 113, 7981-8065. doi: 10.1021/cr400020d
92. [92]
  Li, Q. J.; Zou, X.; Ai, X.; Chen, H.; Sun, L.; Zou, X. X. Revealing activity trends of metal diborides toward pH-universal hydrogen evolution electrocatalysts with Pt-like activity. Adv. Energy Mater. 2019, 9, 1803369.
93. [93]
  Jothi, P. R.; Zhang, Y. M.; Scheifers, J. P.; Park, H.; Fokwa, B. P. T. Molybdenum diboride nanoparticles as a highly efficient electrocatalyst for the hydrogen evolution reaction. Sustain. Energy Fuels 2017, 1, 1928-1934. doi: 10.1039/C7SE00397H
94. [94]
  Jothi, P. R.; Yubuta, K.; Fokwa, B. P. T. A simple, general synthetic route toward nanoscale transition metal borides. Adv. Mater. 2018, 30, 1704181. doi: 10.1002/adma.201704181
95. [95]
  Xiao, M.; Zhang, L.; Luo, B.; Lyu, M.; Wang, Z. L.; Huang, H. M.; Wang, S. C.; Du, A. J.; Wang, L. Z. Molten-salt-mediated synthesis of an atomic nickel Co-catalyst on TiO₂ for improved photocatalytic H₂ evolution. Angew. Chem. Int. Ed. 2020, 59, 7230-7234. doi: 10.1002/anie.202001148
96. [96]
  Wang, F. G.; Liu, B.; Wang, H. Y.; Lin, Z. Y.; Dong, Y. W.; Yu, N.; Luan, R. N.; Chai, Y. M.; Dong, B. Motivating borate doped FeNi layered double hydroxides by molten salt method toward efficient oxygen evolution. J. Colloid Interface Sci. 2022, 610, 173-181. doi: 10.1016/j.jcis.2021.12.031
97. [97]
  Zhou, Y. N.; Wang, F. L.; Dou, S. Y.; Shi, Z. N.; Dong, B.; Yu, W. L.; Zhao, H. Y.; Wang, F. G.; Yu, J. F.; Chai, Y. M. Motivating high-valence Nb doping by fast molten salt method for NiFe hydroxides toward efficient oxygen evolution reaction. Chem. Eng. J. 2022, 427, 131643. doi: 10.1016/j.cej.2021.131643
98. [98]
  Wang, X. F.; Tai, G. A.; Wu, Z. H.; Hu, T. S.; Wang, R. Ultrathin molybdenum boride films for highly efficient catalysis of the hydrogen evolution reaction. J. Mater. Chem. A 2017, 5, 23471-23475. doi: 10.1039/C7TA08597D
99. [99]
  Chen, X. C.; Yu, Z. X.; Wei, L.; Zhou, Z.; Zhai, S. L.; Chen, J. S.; Wang, Y. Q.; Huang, Q. W.; Karahan, H. E.; Liao, X. Z.; Chen, Y. Ultrathin nickel boride nanosheets anchored on functionalized carbon nanotubes as bifunctional electrocatalysts for overall water splitting. J. Mater. Chem. A 2019, 7, 764-774. doi: 10.1039/C8TA09130G
100. [100]
  Cao, X. Y.; Cui, L.; Wang, X. X.; Yang, W. R.; Liu, J. Q. Nickel-borate/reduced graphene oxide nanohybrid: a robust and efficient electrocatalyst for oxygen evolution reaction in alkaline and near neutral media. ChemCatChem 2018, 10, 2826-2832. doi: 10.1002/cctc.201800312
101. [101]
  Chen, P. Z.; Xu, K.; Zhou, T. P.; Tong, Y.; Wu, J. C.; Cheng, H.; Lu, X. L.; Ding, H.; Wu, C. Z.; Xie, Y. Strong-coupled cobalt borate nanosheets/graphene hybrid as electrocatalyst for water oxidation under both alkaline and neutral conditions. Angew. Chem. 2016, 128, 2534-2538. doi: 10.1002/ange.201511032
102. [102]
  Wang, F. G.; Liu, B.; Lin, Z. Y.; Liu, X.; Ma, Y.; Zhou, Y. L.; Yu, J. F.; Chai, Y. M.; Dong, B. Constructing partially amorphous borate doped iron-nickel nitrate hydroxide nanoarrays by rapid microwave activation for oxygen evolution. Appl. Surf. Sci. 2022, 592, 153245. doi: 10.1016/j.apsusc.2022.153245
103. [103]
  Sun, J. Q.; Yang, D. J.; Lowe, S.; Zhang, L. J.; Wang, Y. Z.; Zhao, S. L.; Liu, P. R.; Wang, Y.; Tang, Z. Y.; Zhao, H. J.; Yao, X. D. Sandwich‐like reduced graphene oxide/carbon black/amorphous cobalt borate nanocomposites as bifunctional cathode electrocatalyst in rechargeable zinc‐air batteries. Adv. Energy Mater. 2018, 8, 1801495. doi: 10.1002/aenm.201801495
104. [104]
  Yang, L. B.; Liu, D. N.; Hao, S.; Kong, R. M.; Asiri, A. M.; Zhang, C. X.; Sun, X. P. A cobalt-borate nanosheet array: an efficient and durable non-noble-metal electrocatalyst for water oxidation at near neutral pH. J. Mater. Chem. A 2017, 5, 7305-7308. doi: 10.1039/C7TA00982H
105. [105]
  Ji, X. Q.; Cui, L.; Liu, D. N.; Hao, S.; Liu, J. Q.; Qu, F. L.; Ma, Y. J.; Du, G.; Asiri, A. M.; Sun, X. P. A nickel-borate nanoarray: a highly active 3D oxygen-evolving catalyst electrode operating in near-neutral water. Chem. Commun. 2017, 53, 3070-3073. doi: 10.1039/C6CC09893B
106. [106]
  Ma, M.; Qu, F. L.; Ji, X. Q.; Liu, D. N.; Hao, S.; Du, G.; Asiri, A. M.; Yao, Y. D.; Chen, L.; Sun, X. P. Bimetallic nickel-substituted cobalt-borate nanowire array: an earth-abundant water oxidation electrocatalyst with superior activity and durability at near neutral pH. Small 2017, 13, 1700394. doi: 10.1002/smll.201700394
107. [107]
  Sun, H. M.; Yan, Z. H.; Liu, F. M.; Xu, W. C.; Cheng, F. Y.; Chen, J. Self-supported transition-metal-based electrocatalysts for hydrogen and oxygen evolution. Adv. Mater. 2020, 32, 1806326. doi: 10.1002/adma.201806326
108. [108]
  She, Z. W.; Kibsgaard, J.; Dickens, C. F.; Chorkendorff, I.; Norskov, J. K.; Jaramillo, T. F. Combining theory and experiment in electrocatalysis: insights into materials design. Science 2017, 355, 146.
109. [109]
  Zheng, Y.; Jiao, Y.; Vasileff, A.; Qiao, S. Z. The hydrogen evolution reaction in alkaline solution: from theory, single crystal models, to practicalelectrocatalysts. Angew. Chem. Int. Ed. 2018, 57, 7568-7579. doi: 10.1002/anie.201710556
110. [110]
  Peng, L. S.; Zheng, X. Q.; Li, L.; Zhang, L.; Yang, N.; Xiong, K.; Chen, H. M.; Li, J.; Wei, Z. D. Chimney effect of the interface in metal oxide/metal composite catalysts on the hydrogen evolution reaction. Appl. Catal. B 2019, 245, 122-129. doi: 10.1016/j.apcatb.2018.12.035
111. [111]
  Zhao, Z. P.; Liu, H. T.; Gao, W. P.; Xue, W.; Liu, Z. Y.; Huang, J.; Pan, X. Q.; Huang, Y. Surface-engineered PtNi-O nanostructure with record-high performance for electrocatalytic hydrogen evolution reaction. J. Am. Chem. Soc. 2018, 140, 9046-9050. doi: 10.1021/jacs.8b04770
112. [112]
  Li, Y. X.; Zhang, W. Z.; Li, H.; Yang, T. Y.; Peng, S. Q.; Kao, C.; Zhang, W. Y. Ni-B coupled with borate-intercalated Ni(OH)₂ for efficient and stable electrocatalytic and photocatalytic hydrogen evolution under low alkalinity. Chem. Eng. J. 2020, 394, 124928. doi: 10.1016/j.cej.2020.124928
113. [113]
  Bao, X. H.; Li, Y. T.; Wang, J.; Zhong, Q. Amorphous‐crystalline Co-B-P catalyst for synergistically enhanced hydrogen evolution reaction. ChemCatChem 2020, 12, 6259-6264. doi: 10.1002/cctc.202001343
114. [114]
  Han, H.; Choi, H.; Mhin, S.; Hong, Y. R.; Kim, K. M.; Kwon, J.; Ali, G.; Chung, K. Y.; Je, M.; Umh, H. N.; Lim, D. H.; Davey, K.; Qiao, S. Z.; Paik, U.; Song, T. Advantageous crystalline-amorphous phase boundary for enhanced electrochemical water oxidation. Energy Environ. Sci. 2019, 12, 2443-2454. doi: 10.1039/C9EE00950G
115. [115]
  Vrubel, H.; Hu, X. Molybdenum boride and carbide catalyze hydrogen evolution in both acidic and basic solutions. Angew. Chem. Int. Ed. 2012, 51, 12703-12706. doi: 10.1002/anie.201207111
116. [116]
  Zhuang, Z. C.; Li, Y.; Li, Z. L.; Lv, F.; Lang, Z. Q.; Zhao, K. N.; Zhou, L.; Moskaleva, L.; Guo, S. J.; Mai, L. Q. MoB/g-C₃N₄ interface materials as a schottky catalyst to boost hydrogen evolution. Angew. Chem. Int. Ed. 2018, 57, 496-500. doi: 10.1002/anie.201708748
117. [117]
  Li, Q.; Wang, L. N.; Ai, X.; Chen, H.; Zou, J. Y.; Li, G. D.; Zou, X. X. Multiple crystal phases of intermetallic tungsten borides and phase-dependent electrocatalytic property for hydrogen evolution. Chem. Commun. 2020, 56, 13983-13986. doi: 10.1039/D0CC06072K
118. [118]
  Zhang, J.; Wang, T.; Pohl, D.; Rellinghaus, B.; Dong, R. H.; Liu, S. H.; Zhuang, X. D.; Feng, X. L. Interface engineering of MoS₂/Ni₃S₂ hetero-structures for highly enhanced electrochemical overall-water-splitting activity. Angew. Chem. Int. Ed. 2016, 55, 6702-6707. doi: 10.1002/anie.201602237
119. [119]
  Diao, J. X.; Qiu, Y.; Liu, S. Q.; Wang, W. T.; Chen, K.; Li, H. L.; Yuan, W. Y.; Qu, Y. T.; Guo, X. H. Interfacial engineering of W₂N/WC hetero-structures derived from solid-state synthesis: a highly efficient trifunctional electrocatalyst for ORR, OER, and HER. Adv. Mater. 2020, 32, 1905679. doi: 10.1002/adma.201905679
120. [120]
  Huang, H. W.; Jung, H.; Jun, H.; Woo, D. Y.; Han, J. W.; Lee, J. Design of grain boundary enriched bimetallic borides for enhanced hydrogen evolution reaction. Chem. Eng. J. 2021, 405, 126977. doi: 10.1016/j.cej.2020.126977
121. [121]
  Lao, J.; Li, D.; Jiang, C. L.; Luo, C. H.; Qi, R. J.; Lin, H. C.; Huang, R.; Waterhouse, G. I. N.; Peng, H. Synergistic effect of cobalt boride nanoparticles on MoS₂ nanoflowers for a highly efficient hydrogen evolution reaction in alkaline media. Nanoscale 2020, 12, 10158-10165. doi: 10.1039/C9NR10230B
122. [122]
  Ren, Y. M.; Wang, J. J.; Hu, W. J.; Wen, H.; Qiu, Y. P.; Tang, P. P.; Chen, M. H.; Wang, P. Hierarchical nanostructured Co-Mo-B/CoMoO_4-x amorphous composite for the alkaline hydrogen evolution reaction. ACS Appl. Mater. Interfaces 2021, 13, 42605-42612. doi: 10.1021/acsami.1c08350
123. [123]
  Lin, Q.; Shang, C. Q.; Chen, Z. H.; Wang, X.; Zhou, G. F. Boron-doped molybdenum carbide as a pH-independent electrocatalyst for the hydrogen evolution reaction. Int. J. Hydrogen Energy 2020, 45, 30659-30665. doi: 10.1016/j.ijhydene.2020.08.033
124. [124]
  Cao, E. P.; Chen, Z. M.; Wu, H.; Yu, P.; Wang, Y.; Xiao, F.; Chen, S.; Du, S. C.; Xie, Y.; Wu, Y.; Ren, Z. Y. Boron-induced electronic-structure reformation of CoP nanoparticles drives enhanced pH-universal hydrogen evolution. Angew. Chem. Int. Ed. 2020, 59, 4154-4160. doi: 10.1002/anie.201915254
125. [125]
  Wu, J.; Zhang, Q.; Shen, K.; Zhao, R.; Zhong, W. D.; Yang, C. F.; Xiang, H.; Li, X. K.; Yang, N. J. Modulating interband energy separation of boron-doped Fe₇S₈/FeS₂ electrocatalysts to boost alkaline hydrogen evolution reaction. Adv. Funct. Mater. 2021, 32, 2107802.
126. [126]
  Liu, M. Y.; He, Q.; Huang, S. W.; Zou, W. H.; Cong, J.; Xiao, X. Q.; Li, P.; Cai, J. G.; Hou, L. X. NiCo-layered double hydroxide-derived B-doped CoP/Ni₂P hollow nanoprisms as high-efficiency electrocatalysts for hydrogen evolution reaction. ACS Appl. Mater. Interfaces 2021, 13, 9932-9941. doi: 10.1021/acsami.0c20294
127. [127]
  Yang, H. Y.; Chen, Z. L.; Guo, P. F.; Fei, B.; Wu, R. B. B-doping-induced amorphization of LDH for large-current-density hydrogen evolution reaction. Appl. Catal. B 2020, 261, 118240. doi: 10.1016/j.apcatb.2019.118240
128. [128]
  Ye, S. H.; Luo, F. Y.; Xu, T. T.; Zhang, P. Y.; Shi, H. D.; Qin, S. Q.; Wu, J. P.; He, C. X.; Ouyang, X. P.; Zhang, Q. L.; Liu, J. H.; Sun, X. L. Boosting the alkaline hydrogen evolution of Ru nanoclusters anchored on B/N-doped graphene by accelerating water dissociation. Nano Energy 2020, 68, 104301. doi: 10.1016/j.nanoen.2019.104301
129. [129]
  Bat-Erdene, M.; Batmunkh, M.; Sainbileg, B.; Hayashi, M.; Bati, A. S. R.; Qin, J. D.; Zhao, H. J.; Zhong, Y. L.; Shapter, J. G. Highly dispersed Ru nanoparticles on boron-doped Ti₃C₂T_x (MXene) nanosheets for synergistic enhancement of electrocatalytic hydrogen evolution. Small 2021, 17, 2102218. doi: 10.1002/smll.202102218
130. [130]
  Zhao, X.; Zheng, M.; Zhang, Z. Y.; Wang, Y. F.; Zhou, Y. T.; Zhou, X. H.; Zhang, H. B. Supramolecular nanosheet evolution into BC₃N matrix improves the hydrogen evolution reaction activity in the pH universality of highly dispersed Pt nanoparticles. J. Mater. Chem. A 2021, 9, 16427-16435. doi: 10.1039/D1TA04142H
131. [131]
  Song, J. J.; Wei, C.; Huang, Z. F.; Liu, C. T.; Zeng, L.; Wang, X.; Xu, Z. C. A review on fundamentals for designing oxygen evolution electrocatalysts. Chem. Soc. Rev. 2020, 49, 2196-2214. doi: 10.1039/C9CS00607A
132. [132]
  Gupta, S.; Jadhav, H.; Sinha, S.; Miotello, A.; Patel, M. K.; Sarkar, A.; Patel, N. Cobalt-boride nanostructured thin films with high performance and stability for alkaline water oxidation. ACS Sustain. Chem. Eng. 2019, 7, 16651-16658. doi: 10.1021/acssuschemeng.9b03995
133. [133]
  Liang, X. G.; Dong, R. T.; Li, D. P.; Bu, X. M.; Li, F. Z.; Shu, L.; Wei, R. J.; Ho, J. Coupling of nickel boride and Ni(OH)₂ nanosheets with hierarchical interconnected conductive porous structure synergizes the oxygen evolution reaction. ChemCatChem 2018, 10, 4555-4561. doi: 10.1002/cctc.201800993
134. [134]
  Hong, Y. R.; Kim, K. M.; Ryu, J. H.; Mhin, S.; Kim, J.; Ali, G.; Chung, K. Y.; Kang, S.; Han, H. Dual-phase engineering of nickel boride-hydroxide nanoparticles toward high-performance water oxidation electrocatalysts. Adv. Funct. Mater. 2020, 30, 2004330. doi: 10.1002/adfm.202004330
135. [135]
  Leng, X.; Wu, K. H.; Su, B. J.; Jang, L. Y.; Gentle, I.; Wang, D. W. Hydrotalcite-wrapped Co-B alloy with enhanced oxygen evolution activity. Chin. J. Catal. 2017, 38, 1021-1027. doi: 10.1016/S1872-2067(17)62811-0
136. [136]
  Xie, C.; Wang, Y. Y.; Yan, D. F.; Tao, L.; Wang, S. Y. In situ growth of cobalt@cobalt-borate core-shell nanosheets as highly-efficient electrocatalysts for oxygen evolution reaction in alkaline/neutral medium. Nanoscale 2017, 9, 16059-16065. doi: 10.1039/C7NR06054H
137. [137]
  Chen, S.; Li, Y. Q.; Zhang, Z. H.; Fu, Q.; Bao, X. H. The synergetic effect of h-BN shells and subsurface B in CoB_x@h-BN nanocatalysts for enhanced oxygen evolution reactions. J. Mater. Chem. A 2018, 6, 10644-10648. doi: 10.1039/C8TA02312C
138. [138]
  Zou, S. H.; Burke, M.; Kast, M.; Fan, J.; Danilovic, N.; Boettcher, S. Fe (Oxy)hydroxide oxygen evolution reaction electrocatalysis: intrinsic activity and the roles of electrical conductivity, substrate, and dissolution. Chem. Mater. 2015, 27, 8011-8020. doi: 10.1021/acs.chemmater.5b03404
139. [139]
  Liu, Q. H.; Zhao, H.; Jiang, M.; Kang, Q.; Zhou, W.; Wang, P. C.; Zhou, F. M. Boron enhances oxygen evolution reaction activity over Ni foam-supported iron boride nanowires. J. Mater. Chem. A 2020, 8, 13638-13645. doi: 10.1039/C9TA14256H
140. [140]
  Yuan, H. F.; Wang, S. M.; Gu, X. D.; Tang, B.; Li, J. P.; Wang, X. G. One-step solid-phase boronation to fabricate self-supported porous FeNiB/FeNi foam for efficient electrocatalytic oxygen evolution and overall water splitting. J. Mater. Chem. A 2019, 7, 19554-19564. doi: 10.1039/C9TA04076E
141. [141]
  Ren, H.; Sun, X. L.; Du, C. F.; Zhao, J.; Liu, D. B.; Fang, W.; Kumar, S.; Chua, R.; Meng, S.; Kidkhunthod, P.; Song, L.; Li, S. Q.; Madhavi, S.; Yan, Q. Y. Amorphous Fe-Ni-P-B-O nanocages as efficient electrocatalysts for oxygen evolution reaction. ACS Nano. 2019, 13, 12969-12979. doi: 10.1021/acsnano.9b05571
142. [142]
  Ji, X. Q.; Ren, X.; Hao, S.; Xie, F. Y.; Qu, F. L.; Du, G.; Asiri, A.; Sun, X. P. Remarkable enhancement of the alkaline oxygen evolution reaction activity of NiCo₂O₄ by an amorphous borate shell. Inorg. Chem. Front. 2017, 4, 1546-1550. doi: 10.1039/C7QI00340D
143. [143]
  Gorlin, M.; Ferreira de Araujo, J.; Schmies, H.; Bernsmeier, D.; Dresp, S.; Gliech, M.; Jusys, Z.; Chernev, P.; Kraehnert, R.; Dau, H.; Strasser, P. Tracking catalyst redox states and reaction dynamics in Ni-Fe oxyhydroxide oxygen evolution reaction electrocatalysts: the role of catalyst support and electrolyte pH. J. Am. Chem. Soc. 2017, 139, 2070-2082. doi: 10.1021/jacs.6b12250
144. [144]
  Nsanzimana, J. M. V.; Gong, L. Q.; Dangol, R.; Reddu, V.; Jose, V.; Xia, B. Y.; Yan, Q. Y.; Lee, J. M.; Wang, X. Tailoring of metal boride morphology via anion for efficient water oxidation. Adv. Energy Mater. 2019, 9, 1901503. doi: 10.1002/aenm.201901503
145. [145]
  Chen, H. Y.; Chen, J. X.; Ning, P.; Chen, X.; Liang, J. H.; Yao, X.; Chen, D.; Qin, L. S.; Huang, Y. X.; Wen, Z. H. 2D heterostructure of amorphous CoFeB coating black phosphorus nanosheets with optimal oxygen intermediate absorption for improved electrocatalytic water oxidation. ACS Nano. 2021, 15, 12418-12428. doi: 10.1021/acsnano.1c04715
146. [146]
  Mao, H.; Guo, X.; Fu, Y. L.; Yang, H. R.; Zhang, Y.; Zhang, R.; Song, X. M. Enhanced electrolytic oxygen evolution by the synergistic effects of trimetallic FeCoNi boride oxides immobilized on polypyrrole/reduced graphene oxide. J. Mater. Chem. A 2020, 8, 1821-1828. doi: 10.1039/C9TA10756H
147. [147]
  Chua, X. J.; Luxa, J.; Eng, A. Y. S.; Tan, S. M.; Sofer, Z.; Pumera, M. Negative electrocatalytic effects of p-doping niobium and tantalum on MoS₂ and WS₂ for the hydrogen evolution reaction and oxygen reduction reaction. ACS Catal. 2016, 6, 5724-5734. doi: 10.1021/acscatal.6b01593
148. [148]
  Haq, T.; Mansour, S. A.; Munir, A.; Haik, Y. Gold-supported gadolinium doped CoB amorphous sheet: a new benchmark electrocatalyst for water oxidation with high turnover frequency. Adv. Func. Mater. 2020, 30, 1910309. doi: 10.1002/adfm.201910309
149. [149]
  Kwon, J.; Han, H.; Jo, S.; Choi, S.; Chung, K. Y.; Ali, G.; Park, K.; Paik, U.; Song, T. Amorphous nickel-iron borophosphate for a robust and efficient oxygen evolution reaction. Adv. Energy Mater. 2021, 11, 2100624. doi: 10.1002/aenm.202100624
150. [150]
  Sun, S.; Zhai, T.; Liang, C. L.; Savilov, S. V.; Xia, H. Boosted crystalline/amorphous Fe₂O_3-δ core/shell heterostructure for flexible solid-state pseudocapacitors in large scale. Nano Energy 2018, 45, 390-397. doi: 10.1016/j.nanoen.2018.01.015
151. [151]
  Wu, L. B.; Yu, L.; Zhu, Q. C.; McElhenny, B.; Zhang, F. H.; Wu, C. Z.; Xing, X. X.; Bao, J. M.; Chen, S.; Ren, Z. F. Boron-modified cobalt iron layered double hydroxides for high efficiency seawater oxidation. Nano Energy 2021, 83, 105838. doi: 10.1016/j.nanoen.2021.105838
152. [152]
  Zhang, K.; Zhang, G.; Qu, J. H.; Liu, H. J. Disordering the atomic structure of Co(II) oxide via B-doping: an efficient oxygen vacancy introduction approach for high oxygen evolution reaction electrocatalysts. Small 2018, 14, 1802760. doi: 10.1002/smll.201802760
153. [153]
  Cheng, Z. F.; Pi, Y. C.; Shao, Q.; Huang, X. Q. Boron-doped amorphous iridium oxide with ultrahigh mass activity for acidic oxygen evolution reaction. Sci. China Mater. 2021, 64, 2958-2966. doi: 10.1007/s40843-021-1687-5
154. [154]
  Zuo, Y. P.; Rao, D. W.; Ma, S. N.; Li, T. T.; Tsang, Y. H.; Kment, S.; Chai, Y. Valence engineering via dual-cation and boron doping in pyrite selenide for highly efficient oxygen evolution. ACS Nano. 2019, 13, 11469-11476. doi: 10.1021/acsnano.9b04956
155. [155]
  Jiang, Z. Q.; Jiang, Z. J.; Maiyalagan, T.; Manthiram, A. Cobalt oxide-coated N- and B-doped graphene hollow spheres as bifunctional electrocatalysts for oxygen reduction and oxygen evolution reactions. J. Mater. Chem. A 2016, 4, 5877-5889. doi: 10.1039/C6TA01349J
156. [156]
  Glavin, N.; Muratore, C.; Jespersen, M.; Hu, J.; Hagerty, P.; Hilton, A. M.; Blake, A. T.; Grabowski, C. A.; Durstock, M.; McConney, M.; Hilgefort, D.; Fisher, T. S.; Voevodin, A. Amorphous boron nitride: a universal, ultrathin dielectric for 2D nanoelectronics. Adv. Funct. Mater. 2016, 26, 2640-2647. doi: 10.1002/adfm.201505455
157. [157]
  Liu, H.; Zhang, X. H.; Li, Y. X.; Li, X.; Dong, C. K.; Wu, D. Y.; Tang, C. C.; Chou, S. L.; Fang, F.; Du, X. W. Conductive boron nitride as promising catalyst support for the oxygen evolution reaction. Adv. Energy Mater. 2020, 10, 1902521. doi: 10.1002/aenm.201902521
158. [158]
  Liu, X. X.; Wang, Y. H.; Chen, L. B.; Chen, P. P.; Jia, S. P.; Zhang, Y.; Zhou, S. Y.; Zang, J. B. Co₂B and Co nanoparticles immobilized on the N-B-doped carbon derived from nano-B₄C for efficient catalysis of oxygen evolution, hydrogen evolution, and oxygen reduction reactions. ACS Appl. Mater. Interfaces 2018, 10, 37067-37078. doi: 10.1021/acsami.8b13359
159. [159]
  Zhao, W. N.; Xu, T.; Li, T.; Wang, Y. K.; Liu, H.; Feng, J. Z.; Ding, S. J.; Li, Z. T.; Wu, M. B. Amorphous iron(III)-borate nanolattices as multifunctional electrodes for self-driven overall water splitting and rechargeable zinc-air battery. Small 2018, 14, 1802829. doi: 10.1002/smll.201802829
160. [160]
  Tian, R. F.; Zhao, S. J.; Li, J. K.; Chen, Z. B.; Peng, W. F.; He, Y.; Zhang, L. L.; Yan, S.; Wu, L. L.; Ahuja, R.; Gou, H. Y. Pressure-promoted highly-ordered Fe-doped-Ni₂B for effective oxygen evolution reaction and overall water splitting. J. Mater. Chem. A 2021, 9, 6469-6475. doi: 10.1039/D0TA10010B
161. [161]
  Saad, A.; Gao, Y.; Owusu, K. A.; Liu, W.; Wu, Y. Y.; Ramiere, A.; Guo, H. C.; Tsiakaras, P.; Cai, X. K. Ternary Mo₂NiB₂ as a superior bifunctional electrocatalyst for overall water splitting. Small 2022, 18, 2104303. doi: 10.1002/smll.202104303
162. [162]
  Xu, Y. L.; Wang, C.; Huang, Y. H.; Fu, J. Recent advances in electrocatalysts for neutral and large-current-density water electrolysis. Nano Energy 2021, 80, 105545. doi: 10.1016/j.nanoen.2020.105545
163. [163]
  Liu, H. X.; Li, X. Y.; Chen, L. L.; Zhu, X. D.; Dong, P.; Chee, M. O. L.; Ye, M. X.; Guo, Y. H.; Shen, J. F. Monolithic Ni-Mo-B bifunctional electrode for large current water splitting. Adv. Funct. Mater. 2021, 32, 2107308.
164. [164]
  Wu, Z. X.; Nie, D. Z.; Song, M.; Jiao, T. T.; Fu, G. T.; Liu, X. E. Facile synthesis of Co-Fe-B-P nanochains as an efficient bifunctional electrocatalyst for overall water-splitting. Nanoscale 2019, 11, 7506-7512. doi: 10.1039/C9NR01794A
165. [165]
  Qiang, C. C.; Zhang, L.; He, H. L.; Liu, Y. Y.; Zhao, Y. Y.; Sheng, T.; Liu, S. J.; Wu, X. L.; Fang, Z. Efficient electrocatalytic water splitting by bimetallic cobalt iron boride nanoparticles with controlled electronic structure. J. Colloid Interface Sci. 2021, 604, 650-659. doi: 10.1016/j.jcis.2021.07.024
166. [166]
  Li, Y. J.; Huang, B. L.; Sun, Y. J.; Luo, M. C.; Yang, Y.; Qin, Y. N.; Wang, L.; Li, C. J.; Lv, F.; Zhang, W. Y.; Guo, S. J. Multimetal borides nanochains as efficient electrocatalysts for overall water splitting. Small 2019, 15, 1804212. doi: 10.1002/smll.201804212
167. [167]
  Hu, Q.; Li, G. M.; Han, Z.; Wang, Z. Y.; Huang, X. W.; Chai, X. Y.; Zhang, Q. L.; Liu, J. H.; He, C. X. General synthesis of ultrathin metal borate nanomeshes enabled by 3D bark-like N-doped carbon for electrocatalysis. Adv. Energy Mater. 2019, 9, 1901130. doi: 10.1002/aenm.201901130
168. [168]
  Cheng, Y.; Pang, K. L.; Xu, X. H.; Yuan, P. F.; Zhang, Z. G.; Wu, X.; Zheng, L. R.; Zhang, J. N.; Song, R. Borate crosslinking synthesis of structure tailored carbon-based bifunctional electrocatalysts directly from guar gum hydrogels for efficient overall water splitting. Carbon 2020, 157, 153-163. doi: 10.1016/j.carbon.2019.10.024
169. [169]
  Anjum, M. A. R.; Lee, M. H.; Lee, J. S. Boron- and nitrogen-codoped molybdenum carbide nanoparticles imbedded in a BCN network as a bifunctional electrocatalyst for hydrogen and oxygen evolution reactions. ACS Catal. 2018, 8, 8296-8305. doi: 10.1021/acscatal.8b01794
170. [170]
  Xu, H. B.; Fei, B.; Cai, G. H.; Ha, Y.; Liu, J.; Jia, H. X.; Zhang, J. C.; Liu, M.; Wu, R. B. Boronization‐induced ultrathin 2D nanosheets with abundant crystalline-amorphous phase boundary supported on nickel foam toward efficient water splitting. Adv. Energy Mater. 2019, 10, 1902714.
171. [171]
  Yuan, H. F.; Wang, S. M.; Ma, Z. Z.; Kundu, M.; Tang, B.; Li, J. P.; Wang, X. G. Oxygen vacancies engineered self-supported B doped Co₃O₄ nanowires as an efficient multifunctional catalyst for electrochemical water splitting and hydrolysis of sodium borohydride. Chem. Eng J. 2021, 404, 126474. doi: 10.1016/j.cej.2020.126474
172. [172]
  Shi, D.; Chang, B.; Ai, Z. Z.; Jiang, H. H.; Chen, F. Z.; Shao, Y. G.; Shen, J. X.; Wu, Y. Z.; Hao, X. P. Boron carbonitride with tunable B/N Lewis acid/base sites for enhanced electrocatalytic overall water splitting. Nanoscale 2021, 13, 2849-2854. doi: 10.1039/D0NR06857H
173. [173]
  Chodvadiya, D.; Som, N. N.; Jha, P. K.; Chakraborty, B. Enhancement in the catalytic activity of two-dimensional α-CN by B, Si and P doping for hydrogen evolution and oxygen evolution reactions. Int. J. Hydrogen Energy 2021, 46, 22478-22498. doi: 10.1016/j.ijhydene.2021.04.080
174. [174]
  Zhang, H. X.; Liu, M.; Bu, X. H.; Zhang, J. Zeolitic BIF crystal directly producing noble-metal nanoparticles in its pores for catalysis. Sci. Rep. 2014, 4, 3923.
175. [175]
  Liu, M. R.; Hong, Q. L.; Li, Q. H.; Du, Y. H.; Zhang, H. X.; Chen, S. M.; Zhou, T. H.; Zhang, J. Cobalt boron imidazolate framework derived cobalt nanoparticles encapsulated in B/N codoped nanocarbon as efficient bifunctional electrocatalysts for overall water splitting. Adv. Funct. Mater. 2018, 28, 1801136. doi: 10.1002/adfm.201801136
176. [176]
  Zheng, Y.; Jiao Y.; Zhu, Y. H.; Cai, Q. R.; Vasileff, A.; Li, L. H.; Han, Y.; Chen, Y.; Qiao, S. Z. Molecule-level g-C₃N₄ coordinated transition metals as a new class of electrocatalysts for oxygen electrode reactions. J. Am. Chem. Soc. 2017, 139, 3336-3339. doi: 10.1021/jacs.6b13100
177. [177]
  Tang, S. B.; Zhou, X. H.; Liu, T. Y.; Zhang, S. Y.; Yang, T. T.; Luo, Y.; Sharman, E.; Jiang, J. Single nickel atom supported on hybridized graphene-boron nitride nanosheet as a highly active bi-functional electrocatalyst for hydrogen and oxygen evolution reactions. J. Mater. Chem. A 2019, 7, 26261-26265. doi: 10.1039/C9TA10500J
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