Citation: Sha Li, Xin Wang, Min Cao, Jingjun Lu, Li Qiu, Xiaoliang Yan. Engineering the Interface and Interaction Structure on Highly Coke-Resistant Ni/CeO₂-Al₂O₃ Catalyst for Dry Reforming of Methane[J]. Chinese Journal of Structural Chemistry, ;2022, 41(12): 221200. doi: 10.14102/j.cnki.0254-5861.2022-0113 shu

Engineering the Interface and Interaction Structure on Highly Coke-Resistant Ni/CeO₂-Al₂O₃ Catalyst for Dry Reforming of Methane

Sha Li ¹ ,
Xin Wang ¹ ,
Min Cao ¹ ,
Jingjun Lu ¹ ,
Li Qiu ¹ ,
Xiaoliang Yan ^{1, 2,,}

1.
College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China
2.
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: Xiaoliang Yan, yanxiaoliang@tyut.edu.cn
Received Date: 7 May 2022
Accepted Date: 1 August 2022
Available Online: 6 August 2022

Figures(9)

Designing and tailoring metal-support interaction in Ni-based catalysts with plentiful interfacial sites is of significant interest for achieving a targeted catalytic performance in dry reforming of methane (DRM), but remains as a challenging task. In this work, Ni/Al₂O₃ and Ni/CeO₂-Al₂O₃ catalysts with the same strong metal-support interaction (SMSI) but distinct interface structure are developed by an improved evaporation-induced self-assembly method using pseudobohemite gel as aluminum source. Ni/CeO₂-Al₂O₃ exhibits superior catalytic activity and stability in DRM in comparison with Ni/Al₂O₃. The highest CH₄ and CO₂ conversion reaches at 71.4% and 82.1% for Ni/CeO₂-Al₂O₃, which are higher than that of 64.3% and 75.6% for Ni/Al₂O₃ at 700 ℃. The SMSI effect in Ni/CeO₂-Al₂O₃ provides more active interfacial sites with less coke deposition, and promotes the generation of active formate species which are the key intermediates for DRM. The findings of the present work could possibly pave the way for fabricating catalysts with SMSI strategy for efficient heterogeneous catalysis.
- metal-support interaction,
- interface,
- Ni catalysts,
- CeO₂,
- dry reforming of methane
1. [1]
  Diao, Y. N.; Zhang, X.; Liu, Y.; Chen, B. B.; Wu, G. H.; Shi, C. Plasma-assisted dry reforming of methane over Mo₂C-Ni/Al₂O₃ catalysts: effects of β-Mo₂C promoter. Appl. Catal. B Environ. 2022, 301, 120779. doi: 10.1016/j.apcatb.2021.120779
2. [2]
  Guo, Y.; Li, Y. F.; Ning, Y. X.; Liu, Q. K.; Tian, L.; Zhang, R. D.; Fu, Q.; Wang, Z. J. CO₂ reforming of methane over a highly dispersed Ni/Mg-Al-O catalyst prepared by a facile and green method. Ind. Chem. Eng. Res. 2020, 59, 15506-15514. doi: 10.1021/acs.iecr.0c02444
3. [3]
  Zhang, T. T.; Liu, Z. X.; Zhu, Y. A.; Liu, Z. C.; Sui, Z. J.; Zhu, K. K.; Zhou, X. G. Dry reforming of methane on Ni-Fe-MgO catalysts: influence of Fe on carbon-resistant property and kinetics. Appl. Catal. B Environ. 2020, 264, 118497. doi: 10.1016/j.apcatb.2019.118497
4. [4]
  Song, Y.; Ozdemir, E.; Ramesh, S.; Adishev, A.; Subramanian, S.; Harale, A.; Albuali, M.; Fadhel, B. A.; Jamal, A.; Moon, D.; Choi, S. H.; Yavuz, C. T. Dry reforming of methane by stable Ni-Mo nanocatalysts on single-crystalline MgO. Science 2020, 367, 777-781. doi: 10.1126/science.aav2412
5. [5]
  Liu, C. J.; Ye, J. Y.; Jiang, J. J.; Pan, Y. X. Progresses in the preparation of coke resistant Ni-based catalyst for steam and CO₂ reforming of methane. ChemCatChem 2011, 3, 529-541. doi: 10.1002/cctc.201000358
6. [6]
  Chen, S. Y.; Zaffran, J.; Yang, B. Descriptor design in the computational screening of Ni-based catalysts with balanced activity and stability for dry reforming of methane reaction. ACS Catal. 2020, 10, 3074-3083. doi: 10.1021/acscatal.9b04429
7. [7]
  Huang, Y. L.; Li, X. D. Zhang, Q.; Vinokurov, V. A.; Huang, W. Carbon deposition behaviors in dry reforming of CH₄ at elevated pressures over Ni/MoCeZr/MgAl₂O₄-MgO catalysts. Fuel 2022, 310, 122449. doi: 10.1016/j.fuel.2021.122449
8. [8]
  Azancot, L.; Bobadilla, L. F.; Centeno, M. A.; Odriozola, J. A. IR spectroscopic insights into the coking-resistance effect of potassium on nickel-based catalyst during dry reforming of methane. Appl. Catal. B Environ. 2021, 285, 119822. doi: 10.1016/j.apcatb.2020.119822
9. [9]
  Liu, Z. Y.; Grinter, D. C.; Lustemberg, P. G.; Nguyen-Phan, T. D.; Zhou, Y. H.; Luo, S.; Waluyo, I.; Crumlin, E. J.; Stacchiola, D. J.; Zhou, J.; Carrasco, J.; Busnengo, H. F.; Ganduglia-Pirovano, M. V.; Senanayake, S. D.; Rodriguez, J. A. Dry reforming of methane on a highly-active Ni-CeO₂ catalyst: effects of metal-support interactions on C-H bond breaking. Angew. Chem. Int. Ed. 2016, 55, 7455-7459. doi: 10.1002/anie.201602489
10. [10]
  Akri, M.; Zhao, S.; Li, X. Y.; Zang, K. T.; Lee, A. F.; Isaacs, M. A.; Xi, W.; Gangarajula, Y.; Luo, J.; Ren, Y. J.; Cui, Y. T.; Li, L.; Su, Y.; Pan, X. L.; Wen, W.; Pan, Y.; Wilson, K.; Li, L.; Qiao, B. T.; Ishii, H.; Liao, Y. F.; Wang, A. Q.; Wang, X. D.; Zhang, T. Atomically dispersed nickel as coke-resistant active sites for methane dry reforming. Nat. Commun. 2019, 10, 5181. doi: 10.1038/s41467-019-12843-w
11. [11]
  Ewbank, J. L.; Kovarik, L.; Diallo, F. Z.; Sivers, C. Effect of metal-support interactions in Ni/Al₂O₃ catalysts with low metal loading for methane dry reforming. Appl. Catal. A Gen. 2015, 494, 57-67. doi: 10.1016/j.apcata.2015.01.029
12. [12]
  Yang, B.; Deng, J.; Li, H. R.; Yan, T. T.; Zhang, J. P.; Zhang, D. S. Coking-resistant dry reforming of methane over Ni/gamma-Al₂O₃ catalysts by rationally steering metal-support interaction. iScience 2021, 24, 102747. doi: 10.1016/j.isci.2021.102747
13. [13]
  Zhou, L.; Li, L. D.; Wei, N. N.; Li, J.; Basset, J. M. Effect of NiAl₂O₄ formation on Ni/Al₂O₃ stability during dry reforming of methane. ChemCatChem 2015, 7, 2508-2516. doi: 10.1002/cctc.201500379
14. [14]
  Zhang, S. S.; Ying, M.; Yu, J.; Zhan, W. C.; Wang, L.; Guo, Y.; Guo, Y. L. Ni_xAl₁O₂-delta mesoporous catalysts for dry reforming of methane: the special role of NiAl₂O₄ spinel phase and its reaction mechanism. Appl. Catal. B Environ. 2021, 291, 120074. doi: 10.1016/j.apcatb.2021.120074
15. [15]
  Li, K.; Pei, C. L.; Li, X. Y.; Chen, S.; Zhang, X. H.; Liu, R.; Gong, J. L. Dry reforming of methane over La₂O₂CO₃-modified Ni/Al₂O₃ catalysts with moderate metal support interaction. Appl. Catal. B Environ. 2020, 264, 118448. doi: 10.1016/j.apcatb.2019.118448
16. [16]
  Stroud, T.; Smith, T. J.; Le, S. E.; Santos, J. L.; Centeno, M. A.; Arellano-Garcia, H.; Odriozola, J. A.; Reina, T. R. Chemical CO₂ recycling via dry and bi reforming of methane using Ni-Sn/Al₂O₃ and Ni-Sn/CeO₂-Al₂O₃ catalysts. Appl. Catal. B Environ. 2018, 224, 125-135. doi: 10.1016/j.apcatb.2017.10.047
17. [17]
  Wang, S. B.; Lu, M. Role of CeO₂ in Ni/CeO₂-Al₂O₃ catalysts for carbon dioxide reforming of methane. Appl. Catal. B Environ. 1998, 19, 267-277. doi: 10.1016/S0926-3373(98)00081-2
18. [18]
  Peng, W. X.; Wang, L. S.; Mirzaee, M.; Ahmadi, H.; Esfahani, M. J.; Fremaux, S. Hydrogen and syngas production by catalytic biomass gasification. Energy Convers. Manage. 2017, 135, 270-273. doi: 10.1016/j.enconman.2016.12.056
19. [19]
  Biset-Peiró, M.; Guilera, J.; Zhang, T.; Arbiol, J.; Andreu, T. On the role of ceria in Ni-Al₂O₃ catalyst for CO₂ plasma methanation. Appl. Catal. A Gen. 2019, 575, 223-229. doi: 10.1016/j.apcata.2019.02.028
20. [20]
  Luisetto, I.; Tuti, S.; Battocchio, C.; Lo Mastro, S.; Sodo, A. Ni/CeO₂-Al₂O₃ catalysts for the dry reforming of methane: the effect of CeAlO₃ content and nickel crystallite size on catalytic activity and coke resistance. Appl. Catal. A Gen. 2015, 500, 12-22. doi: 10.1016/j.apcata.2015.05.004
21. [21]
  Ahmed, W.; Awadallah, A. E.; Aboul-Enein, A. A. Ni/CeO₂-Al₂O₃ catalysts for methane thermo-catalytic decomposition to CO_x-free H₂ production. Int. J. Hydrogen Energy 2016, 41, 18484-18493. doi: 10.1016/j.ijhydene.2016.08.177
22. [22]
  Anita, H.; Miklós, N.; Andrea, B.; Boglárka, M.; György, S.; Giuseppe, P.; Leonarda, F. L.; Anna, M. V.; ValeriaLa, P. Strong impact of indium promoter on Ni/Al₂O₃ and Ni/CeO₂-Al₂O₃ catalysts used in dry reforming of methane. Appl. Catal. A Gen. 2021, 621, 118174. doi: 10.1016/j.apcata.2021.118174
23. [23]
  Song, Z. W.; Wang, Q. Q.; Guo, C.; Li, S.; Yan, W. J.; Jiao, W. Y.; Qiu, L.; Yan, X. L.; Li, R. F. Improved effect of Fe on the stable NiFe/Al₂O₃ catalyst in low-temperature dry reforming of methane. Ind. Eng. Chem. Res. 2020, 59, 17250-17258. doi: 10.1021/acs.iecr.0c01204
24. [24]
  Meng, F. H.; Li, X.; Li, M. H.; Cui, X. X.; Li, Z. Catalytic performance of CO methanation over La-promoted Ni/Al₂O₃ catalyst in a slurry-bed reactor. Chem. Eng. J. 2016, 313, 1548-1555.
25. [25]
  Rynkowski, J. M.; Paryjczak, T.; Lenik, M. On the nature of oxidic nickel phases in NiO/γ-AI₂O₃ catalysts. Appl. Catal. A Gen. 1993, 106, 73-82. doi: 10.1016/0926-860X(93)80156-K
26. [26]
  Ai, H. M.; Yang, H. Y.; Liu, Q.; Zhao, G. M.; Yang, J.; Gu, F. N. ZrO₂-modified Ni/LaAl₁₁O₁₈ catalyst for CO methanation: effects of catalyst structure on catalytic performance. Chin. J. Catal. 2018, 39, 297-308. doi: 10.1016/S1872-2067(17)62995-4
27. [27]
  Tan, M.; Wang, X.; Wang, X.; Zou, X.; Ding, W.; Lu, X. Influence of calcination temperature on textural and structural properties, reducibility, and catalytic behavior of mesoporous γ-alumina-supported Ni-Mg oxides by one-pot template-free route. J. Catal. 2015, 329, 151-166. doi: 10.1016/j.jcat.2015.05.011
28. [28]
  Yan, X. L.; Zhao, B. R.; Liu, Y.; Li, Y. N. Dielectric barrier discharge plasma for preparation of Ni-based catalysts with enhanced coke resistance: current status and perspective. Catal. Today 2015, 256, 29-40. doi: 10.1016/j.cattod.2015.04.045
29. [29]
  Al-Fatesh, A. S.; Naeem, M. A.; Fakeeha, A. H.; Abasaeed, A. E. Role of La₂O₃ as promoter and support in Ni/γ-Al₂O₃ catalysts for dry reforming of methane. Chin. J. Chem. Eng. 2014, 22, 28-37. doi: 10.1016/S1004-9541(14)60029-X
30. [30]
  McCarty, J. G.; Wise, H. Hydrogenation of surface carbon on alumina-supported nickel. J. Catal. 1979, 57, 406-416. doi: 10.1016/0021-9517(79)90007-1
31. [31]
  Vogt, C.; Groeneveld, E.; Kamsma, G.; Nachtegaal, M.; Lu, L.; Kiely, C. J.; Berben, P. H.; Meirer, F.; Weckhuysen, B. M. Unravelling structure sensitivity in CO₂ hydrogenation over nickel. Nat. Catal. 2018, 1, 127-134. doi: 10.1038/s41929-017-0016-y
32. [32]
  Pan, Y.; Liu C. J.; Ge, Q. Adsorption and protonation of CO₂ on partially hydroxylated γ-Al₂O₃ surfaces: a density functional theory study. Langmuir 2008, 24, 12410-12419. doi: 10.1021/la802295x
33. [33]
  Busca, G.; Lorenzelli, V. Infrared spectroscopic identification of species arising from reactive adsorption of carbon oxides on metal oxide surfaces. Mater. Chem. 1982, 7, 89-126. doi: 10.1016/0390-6035(82)90059-1
34. [34]
  Wang, X.; Hong, Y. C.; Shi, H.; Szanyi, J. Kinetic modeling and transient DRIFTS-MS studies of CO₂ methanation over Ru/Al₂O₃ catalysts. J. Catal. 2016, 343, 185-195. doi: 10.1016/j.jcat.2016.02.001
35. [35]
  Alarcon, A.; Guilera, J.; Soto, R.; Andreu, T. Higher tolerance to sulfur poisoning in CO₂ methanation by the presence of CeO₂. Appl. Catal. B Environ. 2020, 263, 118346. doi: 10.1016/j.apcatb.2019.118346
36. [36]
  Zhang, X. Y.; Deng, J.; Pupucevski, M.; Impeng, S.; Yang, B.; Chen, G. R.; Kuboon, S.; Zhong, Q. D.; Faungnawakij, K.; Zheng, L. R.; Wu, G.; Zhang, D. S. High-performance binary Mo-Ni catalysts for efficient carbon removal during carbon dioxide reforming of methane. ACS Catal. 2021, 11, 12087-12095. doi: 10.1021/acscatal.1c02124
37. [37]
  Shi, L.; Yang, G. H.; Tao, K.; Yoneyama, Y.; Tan, Y. S.; Tsubaki, N. An introduction of CO₂ conversion by dry reforming with methane and new route of low-temperature methanol synthesis. Acc. Chem. Res. 2013, 46, 1838-1847. doi: 10.1021/ar300217j
38. [38]
  Szanyi, J.; Kwak, J. H. Dissecting the steps of CO₂ reduction: 2. The interaction of CO and CO₂ with Pd/gamma-Al₂O₃: an in situ FTIR study. Phys. Chem. Chem. Phys. 2014, 16, 15126-15138. doi: 10.1039/C4CP00617H
39. [39]
  Ni, J.; Chen, L. W.; Lin, J. Y.; Kawi, S. Carbon deposition on borated alumina supported nano-sized Ni catalysts for dry reforming of CH₄. Nano Energy 2012, 1, 674-686. doi: 10.1016/j.nanoen.2012.07.011
40. [40]
  Ferreira-Aparicio, P.; Fernandez-Garcia, M.; Guerrero-Ruiz, A.; Rodríguez-Ramos, I. Evaluation of the role of the metal-support interfacial centers in the dry reforming of methane on alumina-supported rhodium catalysts. J. Catal. 2000, 190, 296-308. doi: 10.1006/jcat.1999.2752
41. [41]
  Luo, J. Z.; Yu, Z. L.; Ng, C. F.; Au, C. T. CO₂/CH₄ reforming over Ni-La₂O₃/5A: an investigation on carbon deposition and reaction steps. J. Catal. 2000, 194, 198-210. doi: 10.1006/jcat.2000.2941
42. [42]
  Yan, X. L.; Hu, T.; Liu, P.; Li, S.; Zhao, B. R.; Zhang, Q.; Jiao, W. Y.; Chen, S.; Wang, P. F.; Lu, J. J. Highly efficient and stable Ni/CeO₂-SiO₂ catalyst for dry reforming of methane: effect of interfacial structure of Ni/CeO₂ on SiO₂. Appl. Catal. B Environ. 2019, 246, 221-231. doi: 10.1016/j.apcatb.2019.01.070
1. [1]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
2. [2]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
3. [3]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Peng Zhang , Yitao Yang , Tian Qin , Xueqiu Wu , Yuechang Wei , Jing Xiong , Xi Liu , Yu Wang , Zhen Zhao , Jinqing Jiao , Liwei Chen . Interface engineering of Pt/CeO₂-{100} catalysts for enhancing catalytic activity in auto-exhaust carbon particles oxidation. Chinese Chemical Letters, 2025, 36(2): 110396-. doi: 10.1016/j.cclet.2024.110396
6. [6]
  Yunxia Liu , Guandong Wu , Lin Li , Yiming Niu , Bingsen Zhang , Botao Qiao , Junhu Wang . Construction of sintering-resistant gold catalysts via ascorbic-acid inducing strong metal-support interactions. Chinese Chemical Letters, 2025, 36(4): 110608-. doi: 10.1016/j.cclet.2024.110608
7. [7]
  Junchuan Sun , Lu Wang . Carbon exchange enabled supra-photothermal methane dry reforming. Chinese Journal of Structural Chemistry, 2024, 43(10): 100330-100330. doi: 10.1016/j.cjsc.2024.100330
8. [8]
  Tinghui Yang , Min Kuang , Jianping Yang . Mesoporous CuCe dual-metal catalysts for efficient electrochemical reduction of CO2 to methane. Chinese Journal of Structural Chemistry, 2024, 43(8): 100350-100350. doi: 10.1016/j.cjsc.2024.100350
9. [9]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
10. [10]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
11. [11]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
12. [12]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
13. [13]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
14. [14]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
15. [15]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
16. [16]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
17. [17]
  Yuchen Wang , Zhenhao Xu , Kai Yan . Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules. Chinese Journal of Structural Chemistry, 2025, 44(1): 100418-100418. doi: 10.1016/j.cjsc.2024.100418
18. [18]
  Linlu Bai , Wensen Li , Xiaoyu Chu , Haochun Yin , Yang Qu , Ekaterina Kozlova , Zhao-Di Yang , Liqiang Jing . Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction. Chinese Chemical Letters, 2025, 36(2): 109931-. doi: 10.1016/j.cclet.2024.109931
19. [19]
  Changyuan Bao , Yunpeng Jiang , Haoyin Zhong , Huaizheng Ren , Junhui Wang , Binbin Liu , Qi Zhao , Fan Jin , Yan Meng Chong , Jianguo Sun , Fei Wang , Bo Wang , Ximeng Liu , Dianlong Wang , John Wang . Synergizing 3D-printed structure and sodiophilic interface enables highly efficient sodium metal anodes. Chinese Chemical Letters, 2024, 35(11): 109353-. doi: 10.1016/j.cclet.2023.109353
20. [20]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011

Get Citation

PDF

XML

Metrics

PDF Downloads(20)
Abstract views(1252)
HTML views(107)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Engineering the Interface and Interaction Structure on Highly Coke-Resistant Ni/CeO2-Al2O3 Catalyst for Dry Reforming of Methane

Metrics

通讯作者: 陈斌, bchen63@163.com

Engineering the Interface and Interaction Structure on Highly Coke-Resistant Ni/CeO₂-Al₂O₃ Catalyst for Dry Reforming of Methane