Citation: Wei Qiao, Xingyu Huang, Ligang Feng. Advances of PtRu-Based Electrocatalysts for Methanol Oxidation[J]. Chinese Journal of Structural Chemistry, ;2022, 41(7): 220701. doi: 10.14102/j.cnki.0254-5861.2022-0098 shu

Advances of PtRu-Based Electrocatalysts for Methanol Oxidation

1.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Author Bio: Wei Qiao received his B.S. degree at the Inner Mongolia University of Technology in 2015. He is currently an M.S. candidate in the School of Chemistry and Chemical Engineering, Yangzhou University, supervised by Prof. Ligang Feng. His current research interests include the synthesis of platinum-based catalysts and electrochemistry for water splitting reactions and small molecule oxidation
Xingyu Huang received her B.S. degree in pharmaceutical engineering from Xiangnan University in 2021. Now she is pursuing a master's degree supervised by Prof. Ligang Feng, at the School of Chemistry and Chemical Engineering, Yangzhou University. Her current research interests are focusing on non-noble metal-based catalysts for electrochemical applications
Ligang Feng, Professor, obtained his Ph.D. degree from Changchun Institute of Applied Chemistry, Chinese Academy of Sciences in 2011. After performing postdoctoral research at Ecole Polytechnique Fédérale de Lausanne (EPFL) and the Chalmers University of Technology from 2012 to 2016, he started a professorship in April 2016 at Yangzhou University. His research interests focus on energy conversion and storage, particularly novel and cost-effective catalyst material from earth-abundant materials and their applications in fuel cells and water splitting
Corresponding author: Ligang Feng, ligang.feng@yzu.edu.cn, fenglg11@gmail.com
Received Date: 29 April 2022
Accepted Date: 10 May 2022
Available Online: 24 May 2022

Figures(9)

Platinum-Ruthenium (PtRu)-based materials are considered the "holy grail" of electrocatalysts for methanol oxidation reaction (MOR) in the fuel cells technique. However, to the best of our knowledge, the exhaustive review report on the advance of PtRu materials for methanol oxidation is rarely summarized for the recent novel achievements. Herein, we summarize and discuss the latest progress of PtRu-based catalysts in MOR. The reaction mechanism of MOR is firstly introduced, and the promotion mechanism is revealed by the relevant activity descriptor, the in-situ spectroscopic analysis and the theoretical calculation. Subsequently, some advanced regulation strategies of PtRu-based catalysts are concluded, including support engineering, morphology design and surface interface regulation. Finally, the challenges and opportunities to improve the MOR performance of PtRu-based electrocatalysts are prospected to further promote the widespread application of PtRu-based catalysts in electrocatalytic systems. It is concluded that many efforts are still required to decipher the atomic scale structure-activity relationship and the structural changes of atoms and electrons in the reaction process by advanced strategies and characterization methods. Hopefully, this review can be helpful for novel PtRu-based catalyst development and understanding their correlation to the structure and performance of energy-relevant electrocatalysis.
- Pt-Ru based catalysts,
- electrocatalysis,
- methanol oxidation reaction,
- regulation strategies
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