Citation: Zhao-Di Zhou, Zi-Long Xu, Dan Wang, Lin-Fang Jia, Han-Qing Zhao, Bao-Yi Yu, Chong-Chen Wang. Two Bisligand-Coordinated Luminescent Zn(II)-Coordination Polymers for Sensing of Ions and Pesticides in Aqueous Solutions[J]. Chinese Journal of Structural Chemistry, ;2022, 41(9): 220908. doi: 10.14102/j.cnki.0254-5861.2022-0077 shu

Two Bisligand-Coordinated Luminescent Zn(II)-Coordination Polymers for Sensing of Ions and Pesticides in Aqueous Solutions

1.
Key Laboratory of Urban Agriculture (North China), Ministry of Agriculture, College of Bioscience and Resources Environment, Beijing University of Agriculture, Beijing 102206, China
2.
Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Beijing University of Civil Engineering and Architecture, Beijing 100044, China

Corresponding author: Bao-Yi Yu, yubaoyi123@hotmail.com Chong-Chen Wang, chongchenwang@126.com
Received Date: 9 April 2022
Accepted Date: 4 August 2022
Available Online: 11 August 2022

Figures(5)

Two coordination polymers (CPs) [Zn(PTA)(DTP)(H₂O)₂]·(DMF) (CP-1) and [Zn(BTC)(DTP)]·(CH₃CN)_1.5·(H₂O)₄ (CP-2) with one- and two-dimensional architectures were synthesized from Zn(II) ion and different organic linkers like terephthalic acid (H₂PTA), benzene-1, 3, 5-tricarboxylic acid (H₃BTC), and 3, 5-di(1, 2, 4-triazol-1-yl) pyridine (DTP). The fluorescent sensing experiments showed that the two CPs displayed effective, sensitive, and selective abilities towards Fe³⁺ and Cr₂O₇^2-. For sensing the pesticides, CP-1 outperforms in sensing of metamitron (MMT) and CP-2 is ultrasensitive towards imidacloprid (IMI). The possible mechanisms involved in the quenching of the fluorescence intensity include the inner filter effect (IFE) and the fluorescence resonance energy transfer (FRET) effect.
- coordination polymer,
- fluorescence sensing,
- heavy metal ions,
- pesticides,
- X-ray crystallography
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