Citation: Chang-Pu Wan, Jun-Dong Yi, Rong Cao, Yuan-Biao Huang. Conductive Metal/Covalent Organic Frameworks for CO₂ Electroreduction[J]. Chinese Journal of Structural Chemistry, ;2022, 41(5): 220500. doi: 10.14102/j.cnki.0254-5861.2022-0075 shu

Conductive Metal/Covalent Organic Frameworks for CO₂ Electroreduction

Chang-Pu Wan ^{1, 2} ,
Jun-Dong Yi ^{1, 3} ,
Rong Cao ^{1, 2, 4,,} ,
Yuan-Biao Huang ^{1, 2,,}

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), University of Science and Technology of China, Hefei 230026, China
4.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

Author Bio: Chang-Pu Wan obtained his BE degree from the Qingdao University in 2020. Currently, he studies as a master student in Prof. Rong Cao's group in the Fujian Institute of Research on the Structure of Matter (FJIRSM), CAS. His research focuses on porous frameworks materials (MOFs, COFs) for CO₂ heterogeneous catalysis
Jun-Dong Yi received his bachelor's degree from the School of Materials Science and Engineering, Central South University in 2013. Then he received his PhD degree in Fujian Institute of Research on the Structure of Matter (FJIRSM), Chinese Academy of Sciences in 2018. His current research interest focuses on carbon dioxide cycle system, including carbon dioxide enrichment, carbon dioxide electrolysis, and the improvement of carbon dioxide electrolysis device
Rong Cao received his bachelor's degree from University of Science and Technology of China in 1986 and obtained his PhD (1993) in FJIRSM (Fujian Institute of Research on the Structure of Matter), Chinese Academy of Sciences. Following post-doctoral experience in the Hong Kong Polytechnic University and JSPS Fellowship in Nagoya University, he became a professor at FJIRSM in 1998. Now, he is the director of FJIRSM. His main research interests include inorganic-organic hybrid materials, nanomaterials and supramolecular chemistry
Yuan-Biao Huang obtained his PhD (2009) under the supervision of Prof. Guo-Xin Jin from Fudan University. In the same year, he joined Prof. Rong Cao's group at FJIRSM, CAS. In 2014, he joined Prof. Qiang Xu's group at AIST (National Institute of Advanced Industrial Science and Technology) as a JSPS (Japan Society for the Promotion of Science) invited fellow. In 2015, he moved back to FJIRSM, CAS and since 2017, he has been a professor at FJIRSM. His research interests include porous ionic frameworks and conducting materials (MOFs, COFs) for CO₂-involved heterogeneous catalysis
Corresponding author: Rong Cao, rcao@fjirsm.ac.cn Yuan-Biao Huang, ybhuang@fjirsm.ac.cn
Received Date: 3 April 2022
Accepted Date: 29 April 2022

Figures(14)

Porous crystalline metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are promising platforms for electrocatalytic reduction of CO₂ (CO₂RR) due to their large CO₂ adsorption uptakes and periodically arranged single active sites. However, the applications in CO₂RR of the traditional MOFs and COFs are greatly limited by their low electron conductivity. In recent years, numerous types of MOFs and COFs with high intrinsic conductivity have been rationally designed and successfully constructed, and some of them have been applied in CO₂RR. In this review, the applications of conductive MOFs and COFs in CO₂RR have been summarized. The conductive MOFs and COFs can be categorized according to the methods, in which the conductivity is enhanced, such as constructing fully π-conjugated backbones, donor-acceptor heterojunction, enhancing the π-π stacking interactions between organic moieties and/or the introduction of guest molecules.
- metal-organic frameworks,
- covalent organic frameworks,
- CO₂ electroreduction reaction,
- conductive frameworks
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沈阳化工大学材料科学与工程学院沈阳 110142

Conductive Metal/Covalent Organic Frameworks for CO2 Electroreduction

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通讯作者: 陈斌, bchen63@163.com

Conductive Metal/Covalent Organic Frameworks for CO₂ Electroreduction