Citation: Deqing Zhang, Junfeng Ren, Caixia Li, Bin Luo, Lei Wang, Yanyan Li. An Advanced Design Concept of Mansion-like Freestanding Silicon Anodes with Improved Lithium Storage Performances[J]. Chinese Journal of Structural Chemistry, ;2022, 41(5): 220505. doi: 10.14102/j.cnki.0254-5861.2022-0070 shu

An Advanced Design Concept of Mansion-like Freestanding Silicon Anodes with Improved Lithium Storage Performances

Deqing Zhang ^{1, 2} ,
Junfeng Ren ^{1, 2} ,
Caixia Li ^{1, 3,,} ,
Bin Luo ^4,, ,
Lei Wang ^{1, 3,,} ,
Yanyan Li ¹

1.
State Key Laboratory Base of Eco-chemical Engineering, Taishan Scholar Advantage and Characteristic Discipline Team of Eco-chemical Process and Technology, Qingdao University of Science and Technology, Qingdao 266042, China
2.
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
3.
College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
4.
Nanomaterials Centre, School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, St Lucia, QLD 4072, Australia

Corresponding author: Caixia Li, licaixia91@126.com Bin Luo, b.luo1@uq.edu.au Lei Wang, inorchemwl@126.com
Received Date: 24 March 2022
Accepted Date: 27 April 2022

Figures(6)

To conquer inherently low conductivity, volume swelling, and labile solid electrolyte interphase (SEI) films of Si anode in lithium ion battery (LIBs), it is widely accepted that appropriate structure design of Si-C hybrids performs effectively, especially for nanosize Si particles. Herein, inspired by the sturdy construction of high-rise buildings, a mansion-like 3D structured Si@SiO₂/PBC/RGO (SSPBG) with separated rooms is developed based on 0D core-shell Si@SiO₂, 1D pyrolytic bacterial cellulose (PBC) and 2D reduced graphene oxide (RGO). Therefore, these hierarchical protectors operate synergistically to inhibit the inevitable volume changes during electrochemical process. Specifically, tightly coated SiO₂ shell as the first protective layer could buffer the volume expansion and reduce detrimental pulverization of Si NPs. Furthermore, flexible spring-like PBC and ultra-fine RGO sheets perform as securer barriers and skeleton which will counteract the microstructure strain and accelerate electron transfer at the same time. Remarkably, the self-supporting electrode realizes a distinguished performance of 901 mAh g^-1 at 2 A g^-1 for 500 cycles. When matched with LiFePO₄ cathodes, high stability of more than 100 cycles has been realized for the full batteries.
- Si anode,
- bacterial cellulose,
- graphene,
- 3D conductive network,
- binder-free,
- lithium-ion battery
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