Advanced Search

Citation: Shanren Tao, Sijie Wan, Qinyang Huang, Chengming Li, Jiaguo Yu, Shaowen Cao. Molecular Engineering of g-C3N4 with Dibenzothiophene Groups as Electron Donor for Enhanced Photocatalytic H2-Production[J]. Chinese Journal of Structural Chemistry, ;2022, 41(6): 220604. doi: 10.14102/j.cnki.0254-5861.2022-0068 shu

Molecular Engineering of g-C3N4 with Dibenzothiophene Groups as Electron Donor for Enhanced Photocatalytic H2-Production

  • 1.

    State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

  • Corresponding author: Shaowen Cao, swcao@whut.edu.cn
  • Received Date: 24 March 2022
    Accepted Date: 8 April 2022

Figures(8)

  • The construction of donor-acceptor (D-A) molecular structure is an attractive strategy to enhance the photocatalytic performance of polymeric semiconductors. Herein, dibenzothiophene (DBT)-4-carbaldehyde as the precursor is introduced into g-C3N4 (TCN) prepared by two-step thermal polymerization to construct an intramolecular D-A type copolymer (TCN-DBTx). DFT calculation and experimental results reveal that DBT plays the role of electron donor unit to modify g-C3N4. The incorporation of DBT not only adjusts the band gap to improve reduction ability, but also induces an internal electric field with extending π-conjugated system for effective charge transfer. As a result, TCN-DBTx exhibits much better photocatalytic performance with an optimal hydrogen production rate of 3334 μmol h-1 g-1, which is 2.5 times that of TCN. This work provides a protocol for preparing high-performance g-C3N4-based photocatalysts toward various applications.
  • 加载中
    1. [1]

      Zhao, W.; Chen, Z.; Yang, X. R.; Qian, X. X.; Liu, C. X.; Zhou, D. T.; Sun, T.; Zhang, M.; Wei, G. Y.; Dissanayake, P. D.; Ok, Y. S. Recent advances in photocatalytic hydrogen evolution with high-performance catalysts without precious metals. Renew. Sust. Energ. Rev. 2020, 132, 110040.  doi: 10.1016/j.rser.2020.110040

    2. [2]

      Cheng, C.; He, B. W.; Fan, J. J.; Cheng, B.; Cao, S. W.; Yu, J. G. An inorganic/organic S-scheme heterojunction H2-production photocatalyst and its charge transfer mechanism. Adv. Mater. 2021, 33, 2100317.  doi: 10.1002/adma.202100317

    3. [3]

      Lin, J. D.; Yan, S.; Huang, Q. D.; Fan, M. T.; Yuan, Y. Z.; Tan, T. T. Y.; Liao, D. W. TiO2 promoted by two different non-noble metal cocatalysts for enhanced photocatalytic H2 evolution. Appl. Surf. Sci. 2014, 309, 188-193.  doi: 10.1016/j.apsusc.2014.05.008

    4. [4]

      Xiang, X. L.; Zhu, B. C.; Cheng, B.; Yu, J. G.; Lv, H. J. Enhanced photocatalytic H2-production activity of CdS quantum dots using Sn2+ as cocatalyst under visible light irradiation. Small 2020, 16, 2001024.  doi: 10.1002/smll.202001024

    5. [5]

      Yang, Y.; Zhou, C. Y.; Wang, W. J.; Xiong, W. P.; Zeng, G. M.; Huang, D. L.; Zhang, C.; Song, B.; Xue, W. J.; Li, X. P.; Wang, Z. W.; He, D. H.; Luo, H. Z.; Ouyang, Z. L. Recent advances in application of transition metal phosphides for photocatalytic hydrogen production. Chem. Eng. J. 2021, 405, 126547.  doi: 10.1016/j.cej.2020.126547

    6. [6]

      Maeda, K.; Wang, X. C.; Nishihara, Y.; Lu, D. L.; Antonietti, M.; Domen, K. Photocatalytic activities of graphitic carbon nitride powder for water reduction and oxidation under visible light. J. Phys. Chem. C 2009, 113, 4940-4947.

    7. [7]

      Cao, S. W.; Low, J. X.; Yu, J. G.; Jaroniec, M. Polymeric photocatalysts based on graphitic carbon nitride. Adv. Mater. 2015, 27, 2150-2176.  doi: 10.1002/adma.201500033

    8. [8]

      Malik, R.; Tomer, V. K. State-of-the-art review of morphological advancements in graphitic carbon nitride (g-CN) for sustainable hydrogen production. Renew. Sust. Energ. Rev. 2021, 135, 110235.  doi: 10.1016/j.rser.2020.110235

    9. [9]

      Hou, Y. T.; Guan, H. H.; Yu, J. G.; Cao, S. W. Potassium/oxygen co-doped polymeric carbon nitride for enhanced photocatalytic CO2 reduction. Appl. Surf. Sci. 2021, 563, 150310.  doi: 10.1016/j.apsusc.2021.150310

    10. [10]

      Jiang, R. R.; Lu, G. H.; Liu, J. C.; Wu, D. H.; Yan, Z. H.; Wang, Y. H. Incorporation of π-conjugated molecules as electron donors in g-C3N4 enhances photocatalytic H2-production. Renew. Energy 2021, 164, 531-540.  doi: 10.1016/j.renene.2020.09.040

    11. [11]

      Wang, Y. J.; Li, Y.; Cao, S. W.; Yu, J. G. Ni-P cluster modified carbon nitride toward efficient photocatalytic hydrogen production. Chin. J. Catal. 2019, 40, 867-874.  doi: 10.1016/S1872-2067(19)63343-7

    12. [12]

      Zong, X. P.; Niu, L. J.; Jiang, W. S.; Yu, Y. M.; An, L.; Qu, D.; Wang, X. Y.; Sun, Z. C. Constructing creatinine-derived moiety as donor block for carbon nitride photocatalyst with extended absorption and spatial charge separation. Appl. Catal. B: Environ. 2021, 291, 120099.  doi: 10.1016/j.apcatb.2021.120099

    13. [13]

      Fu, J. W.; Xu, Q. L.; Low, J. X.; Jiang, C. J.; Yu, J. G. Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst. Appl. Catal. B: Environ. 2019, 243, 556-565.  doi: 10.1016/j.apcatb.2018.11.011

    14. [14]

      Chen, L.; Xu, Y. M.; Chen, B. In situ photochemical fabrication of CdS/g-C3N4 nanocomposites with high performance for hydrogen evolution under visible light. Appl. Catal. B: Environ. 2019, 256, 117848.  doi: 10.1016/j.apcatb.2019.117848

    15. [15]

      Lin, B.; Li, H.; An, H.; Hao, W. B.; Wei, J. J.; Dai, Y. Z.; Ma, C. S.; Yang, G. D. Preparation of 2D/2D g-C3N4 nanosheet@ZnIn2S4 nanoleaf heterojunctions with well-designed high-speed charge transfer nano-channels towards high efficiency photocatalytic hydrogen evolution. Appl. Catal. B: Environ. 2018, 220, 542-552.  doi: 10.1016/j.apcatb.2017.08.071

    16. [16]

      Jiang, L. S.; Wang, K.; Wu, X. Y.; Zhang, G. K.; Yin, S. Amorphous bimetallic cobalt nickel sulfide cocatalysts for significantly boosting photo-catalytic hydrogen evolution performance of graphitic carbon nitride: efficient interfacial charge transfer. ACS Appl. Mater. Interfaces 2019, 11, 26898-26908.  doi: 10.1021/acsami.9b07311

    17. [17]

      Chen, Z.; Gao, Y. T.; Chen, F.; Shi, H. F. Metallic NiSe cocatalyst decorated g-C3N4 with enhanced photocatalytic activity. Chem. Eng. J. 2021, 413.

    18. [18]

      Li, X. G.; Bi, W. T.; Zhang, L.; Tao, S.; Chu, W. S.; Zhang, Q.; Luo, Y.; Wu, C. Z.; Xie, Y. Single-atom Pt as co-catalyst for enhanced photocatalytic H2 evolution. Adv. Mater. 2016, 28, 2427-2431.  doi: 10.1002/adma.201505281

    19. [19]

      Cao, S. W.; Li, H.; Tong, T.; Chen, H. C.; Yu, A. C.; Yu, J. G.; Chen, H. M. Single-atom engineering of directional charge transfer channels and active sites for photocatalytic hydrogen evolution. Adv. Funct. Mater. 2018, 28, 1802169.  doi: 10.1002/adfm.201802169

    20. [20]

      Yin, J. T.; Li, Z.; Cai, Y.; Zhang, Q. F.; Chen, W. Ultrathin graphitic carbon nitride nanosheets with remarkable photocatalytic hydrogen production under visible LED irradiation. Chem. Commun. 2017, 53, 9430-9433.  doi: 10.1039/C7CC04204C

    21. [21]

      Cui, Y. J.; Wang, Y. X.; Wang, H.; Cao, F.; Chen, F. Y. Polycondensation of ammonium thiocyanate into novel porous g-C3N4 nanosheets as photocatalysts for enhanced hydrogen evolution under visible light irradiation. Chin. J. Catal. 2016, 37, 1899-1906.  doi: 10.1016/S1872-2067(16)62509-3

    22. [22]

      Wu, M.; Gong, Y. S.; Nie, T.; Zhang, J.; Wang, R.; Wang, H. W.; He, B. B. Template-free synthesis of nanocage-like g-C3N4 with high surface area and nitrogen defects for enhanced photocatalytic H2 activity. J. Mater. Chem. A 2019, 7, 5324-5332.  doi: 10.1039/C8TA12076E

    23. [23]

      Guo, S. E.; Tang, Y. Q.; Xie, Y.; Tian, C. G.; Feng, Q. M.; Zhou, W.; Jiang, B. J. P-doped tubular g-C3N4 with surface carbon defects: universal synthesis and enhanced visible-light photocatalytic hydrogen production. Appl. Catal. B: Environ. 2017, 218, 664-671.  doi: 10.1016/j.apcatb.2017.07.022

    24. [24]

      Guo, H.; Shu, Z.; Chen, D. H.; Tan, Y. G.; Zhou, J.; Meng, F. Y.; Li, T. T. One-step synthesis of S-doped g-C3N4 nanosheets for improved visible-light photocatalytic hydrogen evolution. Chem. Phys. 2020, 533, 110714.  doi: 10.1016/j.chemphys.2020.110714

    25. [25]

      Liao, Y. W.; Wang, G. H.; Wang, J.; Wang, K.; Yan, S. D.; Su, Y. R. Nitrogen vacancy induced in situ g-C3N4 p-n homojunction for boosting visible light-driven hydrogen evolution. J. Colloid Interface Sci. 2021, 587, 110-120.  doi: 10.1016/j.jcis.2020.12.009

    26. [26]

      Wang, L. Y.; Hong, Y. Z.; Liu, E. L.; Wang, Z. G.; Chen, J. H.; Yang, S.; Wang, J. B.; Lin, X.; Shi, J. Y. Rapid polymerization synthesizing high-crystalline g-C3N4 towards boosting solar photocatalytic H2 generation. Int. J. Hydrogen Energy 2020, 45, 6425-6436.  doi: 10.1016/j.ijhydene.2019.12.168

    27. [27]

      Che, H. N.; Liu, C. B.; Che, G. B.; Liao, G. F.; Dong, H. J.; Li, C. X.; Song, N.; Li, C. M. Facile construction of porous intramolecular g-C3N4-based donor-acceptor conjugated copolymers as highly efficient photocatalysts for superior H2 evolution. Nano Energy 2020, 67, 104273.  doi: 10.1016/j.nanoen.2019.104273

    28. [28]

      Lai, J. Y.; Zhang, W. D.; Yu, Y. X. Building sp carbon-bridged g-C3N4-based electron donor-π-acceptor unit for efficient photocatalytic water splitting. Mol. Catal. 2021, 505, 111518.  doi: 10.1016/j.mcat.2021.111518

    29. [29]

      Sun, D. W.; Chen, K. L.; Huang, J. H. Benzenesulfonyl chloride-incorporated g-C3N4 for photocatalytic hydrogen generation by using the hydrolysate of poly(lactic acid) as sacrificial reagent. Appl. Catal. A-Gen. 2021, 628, 118397.  doi: 10.1016/j.apcata.2021.118397

    30. [30]

      Fan, X. Q.; Zhang, L. X.; Cheng, R. L.; Wang, M.; Li, M. L.; Zhou, Y. J.; Shi, J. L. Construction of graphitic C3N4-based intramolecular donor-acceptor conjugated copolymers for photocatalytic hydrogen evolution. ACS Catal. 2015, 5, 5008-5015.  doi: 10.1021/acscatal.5b01155

    31. [31]

      Li, K.; Zhang, W. D. Creating graphitic carbon nitride based donor-π-acceptor-π-donor structured catalysts for highly photocatalytic hydrogen evolution. Small 2018, 14, 1703599.  doi: 10.1002/smll.201703599

    32. [32]

      Cao, S. W.; Jiang, J.; Zhu, B. C.; Yu, J. G. Shape-dependent photo-catalytic hydrogen evolution activity over a Pt nanoparticle coupled g-C3N4 photocatalyst. Phys. Chem. Chem. Phys. 2016, 18, 19457-19463.  doi: 10.1039/C6CP02832B

    33. [33]

      Jin, Z. L.; Li, Y. B.; Hao, X. Q. Ni, Co-based selenide anchored g-C3N4 for boosting photocatalytic hydrogen evolution. Acta Phys. -Chim. Sin. 2021, 37, 1912033.

    34. [34]

      Wang, J.; Zhao, H.; Zhu, B. C.; Larter, S.; Cao, S. W.; Yu, J. G.; Kibria, M. G.; Hu, J. G. Solar-driven glucose isomerization into fructose via transient Lewis acid-base active sites. ACS Catal. 2021, 11, 12170-12178.  doi: 10.1021/acscatal.1c03252

    35. [35]

      Xia, P. F.; Cao, S. W.; Zhu, B. C.; Liu, M. J.; Shi, M. S.; Yu, J. G.; Zhang, Y. F. Designing a 0D/2D S-scheme heterojunction over polymeric carbon nitride for visible-light photocatalytic inactivation of bacteria. Angew. Chem. Int. Ed. 2020, 59, 5218-5225.  doi: 10.1002/anie.201916012

    36. [36]

      Gong, J. Y.; Xie, Z. B.; Wang, B.; Li, Z. Q.; Zhu, Y.; Xue, J. M.; Le, Z. G. Fabrication of g-C3N4-based conjugated copolymers for efficient photo-catalytic reduction of U(VI). J. Environ. Chem. Eng. 2021, 9, 104638.  doi: 10.1016/j.jece.2020.104638

    37. [37]

      Li, H. F.; Ding, M. N.; Luo, L. L.; Yang, G. X.; Shi, F. Y.; Huo, Y. N. Nanomesh-structured graphitic carbon nitride polymer for effective capture and photocatalytic elimination of bacteria. ChemCatChem. 2020, 12, 1334-1340.  doi: 10.1002/cctc.201901699

    38. [38]

      Ye, H. N.; Wang, Z. Q.; Yu, F. T.; Zhang, S. C.; Kong, K. Y.; Gong, X. Q.; Hua, J. L.; Tian, H. Fluorinated conjugated poly(benzotriazole)/g-C3N4 heterojunctions for significantly enhancing photocatalytic H2 evolution. Appl. Catal. B: Environ. 2020, 267, 118577.  doi: 10.1016/j.apcatb.2019.118577

    39. [39]

      Li, H.; Li, F.; Yu, J. G.; Cao, S. W. 2D/2D FeNi-LDH/g-C3N4 hybrid photocatalyst for enhanced CO2 photoreduction. Acta Phys. -Chim. Sin. 2021, 37, 2010073.

    40. [40]

      Kumar, A.; Prajapati, P. K.; Aathira, M. S.; Bansiwal, A.; Boukherroub, R.; Jain, S. L. Highly improved photoreduction of carbon dioxide to methanol using cobalt phthalocyanine grafted to graphitic carbon nitride as photocatalyst under visible light irradiation. J. Colloid Interface Sci. 2019, 543, 201-213.  doi: 10.1016/j.jcis.2019.02.061

    41. [41]

      Song, X. H.; Li, X.; Zhang, X. Y.; Wu, Y. F.; Ma, C. C.; Huo, P. W.; Yan, Y. S. Fabricating C and O co-doped carbon nitride with intramolecular donor-acceptor systems for efficient photoreduction of CO2 to CO. Appl. Catal. B: Environ. 2020, 268, 118736.  doi: 10.1016/j.apcatb.2020.118736

    42. [42]

      Zou, J.; Liao, G.; Jiang, J.; Xiong, Z.; Bai, S.; Wang, H.; Wu, P.; Zhang, P.; Li, X. In-situ construction of sulfur-doped g-C3N4/defective g-C3N4 isotype step-scheme heterojunction for boosting photocatalytic H2 evolution. Chin. J. Struct. Chem. 2022, 41, 2201025-2201033.

    43. [43]

      Hayat, A.; Shaishta, N.; Mane, S. K. B.; Hayat, A.; Khan, J.; Rehman, A. U.; Li, T. H. Molecular engineering of polymeric carbon nitride based donor-acceptor conjugated copolymers for enhanced photocatalytic full water splitting. J. Colloid Interface Sci. 2020, 560, 743-754.  doi: 10.1016/j.jcis.2019.10.088

    44. [44]

      Wang, W. R.; Li, J.; Li, Q.; Xu, Z. W.; Liu, L. N.; Chen, X. Q.; Xiao, W. J.; Yao, J. H.; Zhang, F.; Li, W. S. Side-chain-extended conjugation: a strategy for improving the photocatalytic hydrogen production performance of a linear conjugated polymer. J. Mater. Chem. A 2021, 9, 8782-8791.  doi: 10.1039/D0TA12425G

    45. [45]

      Zhang, Y. Z.; Shi, J. W.; Huang, Z. X.; Guan, X. J.; Zong, S. C.; Cheng, C.; Zheng, B. T.; Guo, L. J. Synchronous construction of CoS2 in-situ loading and s doping for g-C3N4: enhanced photocatalytic H2-evolution activity and mechanism insight. Chem. Eng. J. 2020, 401, 126135.  doi: 10.1016/j.cej.2020.126135

    46. [46]

      Xue, F.; Liu, M. C.; Cheng, C.; Deng, J. K.; Shi, J. W. Localized NiS2 quantum dots on g-C3N4 nanosheets for efficient photocatalytic hydrogen production from water. ChemCatChem. 2018, 10, 5441-5448.  doi: 10.1002/cctc.201801510

    47. [47]

      Lin, B.; An, H.; Yan, X. Q.; Zhang, T. X.; Wei, J. J.; Yang, G. D. Fish-scale structured g-C3N4 nanosheet with unusual spatial electron transfer property for high-efficiency photocatalytic hydrogen evolution. Appl. Catal. B: Environ. 2017, 210, 173-183.  doi: 10.1016/j.apcatb.2017.03.066

    48. [48]

      Thommes, M.; Kaneko, K.; Neimark, A. V.; Olivier, J. P.; Rodriguez-Reinoso, F.; Rouquerol, J.; Sing, K. S. W. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC technical report). Pure Appl. Chem. 2015, 87, 1051-1069.  doi: 10.1515/pac-2014-1117

    49. [49]

      Li, H.; Zhang, J.; Yu, J.; Cao, S. Ultra-thin carbon-doped Bi2WO6 nanosheets for enhanced photocatalytic CO2 reduction. Trans. Tianjin Univ. 2021, 27, 338-347.  doi: 10.1007/s12209-021-00289-5

    50. [50]

      Li, H.; Zhu, B. C.; Cao, S. W.; Yu, J. G. Controlling defects in crystalline carbon nitride to optimize photocatalytic CO2 reduction. Chem. Commun. 2020, 56, 5641-5644.  doi: 10.1039/D0CC01338B

    51. [51]

      Zhang, W. D.; Zhao, Z. W.; Dong, F.; Zhang, Y. X. Solvent-assisted synthesis of porous g-C3N4 with efficient visible-light photocatalytic performance for NO removal. Chin. J. Catal. 2017, 38, 372-378.  doi: 10.1016/S1872-2067(16)62585-8

    52. [52]

      Zhang, Y. Z.; Huang, Z. X.; Dong, C. L.; Shi, J. W.; Cheng, C.; Guan, X. J.; Zong, S. C.; Luo, B.; Cheng, Z. N.; Wei, D. X.; Huang, Y. C.; Shen, S. H.; Guo, L. J. Synergistic effect of nitrogen vacancy on ultrathin graphitic carbon nitride porous nanosheets for highly efficient photocatalytic H2 evolution. Chem. Eng. J. 2022, 431.

    53. [53]

      Hu, S. W.; Shi, J. W.; Luo, B.; Ai, C. Q.; Jing, D. W. Significantly enhanced photothermal catalytic hydrogen evolution over Cu2O-rGO/TiO2 composite with full spectrum solar light. J. Colloid Interface Sci. 2022, 608, 2058-2065.  doi: 10.1016/j.jcis.2021.10.136

    54. [54]

      Lan, X. W.; Li, Q.; Zhang, Y. Z.; Li, Q.; Ricardez-Sandoval, L.; Bai, G. Y. Engineering donor-acceptor conjugated organic polymers with boron nitride to enhance photocatalytic performance towards visible-light-driven metal-free selective oxidation of sulfides. Appl. Catal. B: Environ. 2020, 277, 119274.  doi: 10.1016/j.apcatb.2020.119274

    55. [55]

      Li, H. P.; Lee, H. Y.; Park, G. S.; Lee, B. J.; Park, J. D.; Shin, C. H.; Hou, W. G.; Yu, J. S. Conjugated polyene-functionalized graphitic carbon nitride with enhanced photocatalytic water-splitting efficiency. Carbon 2018, 129, 637-645.  doi: 10.1016/j.carbon.2017.12.048

    56. [56]

      Zhang, Q. H.; Xia, Y.; Cao, S. W. "Environmental phosphorylation" boosting photocatalytic CO2 reduction over polymeric carbon nitride grown on carbon paper at air-liquid-solid joint interfaces. Chin. J. Catal. 2021, 42, 1667-1676.  doi: 10.1016/S1872-2067(21)63824-X

    57. [57]

      Yu, H. G.; Xu, J. C.; Gao, D. D.; Fan, J. J.; Yu, J. G. Triethanolamine-mediated photodeposition formation of amorphous Ni-P alloy for improved H2-evolution activity of g-C3N4. Sci. China Mater. 2020, 63, 2215-2227.  doi: 10.1007/s40843-020-1298-x

    58. [58]

      Wang, Z. L.; Chen, Y. F.; Zhang, L. Y.; Cheng, B.; Yu, J. G.; Fan, J. J. Step-scheme CdS/TiO2 nanocomposite hollow microsphere with enhanced photocatalytic CO2 reduction activity. J. Mater. Sci. Technol. 2020, 56, 143-150.  doi: 10.1016/j.jmst.2020.02.062

    59. [59]

      Chen, B.; Yu, J.; Wang, R.; Zhang, X. G.; He, B. B.; Jin, J.; Wang, H. W.; Gong, Y. S. Three-dimensional ordered macroporous g-C3N4-Cu2O-TiO2 heterojunction for enhanced hydrogen production. Sci. China Mater. 2022, 65, 139-146.  doi: 10.1007/s40843-021-1714-9

    60. [60]

      Han, S.; Li, B.; Huang, L.; Xi, H.; Ding, Z.; Long, J. Construction of ZnIn2S4-CdIn2S4 microspheres for efficient photo-catalytic reduction of CO2 with visible light. Chin. J. Struct. Chem. 2022, 41, 2201007-2201013.

    61. [61]

      He, F.; Meng, A. Y.; Cheng, B.; Ho, W. K.; Yu, J. G. Enhanced photo-catalytic H2-production activity of WO3/TiO2 step-scheme heterojunction by graphene modification. Chin. J. Catal. 2020, 41, 9-20.  doi: 10.1016/S1872-2067(19)63382-6

    62. [62]

      Yang, C.; Wang, Y. J.; Yu, J. G.; Cao, S. W. Ultrathin 2D/2D graphdiyne/Bi2WO6 heterojunction for gas-phase CO2 photoreduction. ACS Appl. Energy Mater. 2021, 4, 8734-8738.  doi: 10.1021/acsaem.1c02122

    63. [63]

      Chen, R.; Chen, J.; Che, H.; Zhou, G.; Ao, Y.; Liu, B. Atomically dispersed main group magnesium on cadmium sulfide as the active site for promoting photocatalytic hydrogen evolution catalysis. Chin. J. Struct. Chem. 2022, 41, 2201014-2201018.

    64. [64]

      Sun, Z. Z.; Jiang, Y. B.; Zeng, L.; Huang, L. M. Intramolecular charge transfer and extended conjugate effects in donor-π-acceptor-type mesoporous carbon nitride for photocatalytic hydrogen evolution. ChemSusChem. 2019, 12, 1325-1333.  doi: 10.1002/cssc.201802890

    65. [65]

      Liu, G. G.; Zhao, G. X.; Zhou, W.; Liu, Y. Y.; Pang, H.; Zhang, H. B.; Hao, D.; Meng, X. G.; Li, P.; Kako, T.; Ye, J. H. In situ bond modulation of graphitic carbon nitride to construct p-n homojunctions for enhanced photocatalytic hydrogen production. Adv. Funct. Mater. 2016, 26, 6822-6829.  doi: 10.1002/adfm.201602779

    66. [66]

      Che, H. N.; Li, C. M.; Li, C. X.; Liu, C. B.; Dong, H. J.; Song, X. H. Benzoyl isothiocyanate as a precursor to design of ultrathin and high-crystalline g-C3N4-based donor-acceptor conjugated copolymers for superior photocatalytic H2 production. Chem. Eng. J. 2021, 410, 127791.  doi: 10.1016/j.cej.2020.127791

  • 加载中
    1. [1]

      Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353

    2. [2]

      Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433

    3. [3]

      Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401

    4. [4]

      Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066

    5. [5]

      Fei ZHOU , Xiaolin JIA . Co3O4/TiO2 composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236

    6. [6]

      Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877

    7. [7]

      Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632

    8. [8]

      Guixu Pan ,  Zhiling Xia ,  Ning Wang ,  Hejia Sun ,  Zhaoqi Guo ,  Yunfeng Li ,  Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463

    9. [9]

      Rong-Nan Yi , Wei-Min He . Electron donor-acceptor complex enabled arylation of dithiocarbamate anions with thianthrenium salts under aqueous micellar conditions. Chinese Chemical Letters, 2024, 35(11): 110194-. doi: 10.1016/j.cclet.2024.110194

    10. [10]

      Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi2Sn2O7 quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131

    11. [11]

      Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs3Bi2Br9/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430

    12. [12]

      Qiang Zhang ,  Weiran Gong ,  Huinan Che ,  Bin Liu ,  Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205

    13. [13]

      Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

    14. [14]

      Yan Fan , Jiao Tan , Cuijuan Zou , Xuliang Hu , Xing Feng , Xin-Long Ni . Unprecedented stepwise electron transfer and photocatalysis in supramolecular assembly derived hybrid single-layer two-dimensional nanosheets in water. Chinese Chemical Letters, 2025, 36(4): 110101-. doi: 10.1016/j.cclet.2024.110101

    15. [15]

      Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO2 cycloaddition over W18O49/NH2-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

    16. [16]

      Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

    17. [17]

      Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    18. [18]

      Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO3/g-C3N4 heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259

    19. [19]

      Hang Meng ,  Bicheng Zhu ,  Ruolun Sun ,  Zixuan Liu ,  Shaowen Cao ,  Kan Zhang ,  Jiaguo Yu ,  Jingsan Xu . Dynamic photoluminescence switching of carbon nitride thin films for anticounterfeiting and encryption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100410-100410. doi: 10.1016/j.cjsc.2024.100410

    20. [20]

      Yihu Ke ,  Shuai Wang ,  Fei Jin ,  Guangbo Liu ,  Zhiliang Jin ,  Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458

Get Citation
PDF
XML
Metrics
  • PDF Downloads(10)
  • Abstract views(421)
  • HTML views(35)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return