Citation: Yanmei Gan, Jiajie Zhu, Qixin Zhang, Chaoying Wang, Lunhui Guan, Yi Zhao. Boosting Stable and Fast Potassium Storage of Iron Sulfide through Rational Yolk-Shell Design and Ni Doping[J]. Chinese Journal of Structural Chemistry, ;2022, 41(5): 220503. doi: 10.14102/j.cnki.0254-5861.2022-0044 shu

Boosting Stable and Fast Potassium Storage of Iron Sulfide through Rational Yolk-Shell Design and Ni Doping

Yanmei Gan ^{1, 2, 3} ,
Jiajie Zhu ⁴ ,
Qixin Zhang ^{2, 3} ,
Chaoying Wang ² ,
Lunhui Guan ³ ,
Yi Zhao ^2,,

1.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
2.
Straits Institute of Flexible Electronics (SIFE, Future Technologies), Fujian Normal University, Fuzhou 350117, China
3.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350108, China
4.
School of Physics Science and Engineering, Tongji University, Shanghai 200092, China

Corresponding author: Yi Zhao, ifeyzhao@fjnu.edu.cn
Received Date: 28 February 2022
Accepted Date: 4 April 2022

Figures(5)

Metal sulfides have been regarded as promising anodes for potassium-ion batteries (PIBs) due to their high theoretical capacities, while the performance is limited by their intrinsic poor conductivity and large volume fluctuation during the insertion/extraction of large potassium ion. Herein, the battery performance of iron sulfide anode is significantly enhanced through yolk-shell (Y-S) structure design and nickel doping, aiming to realize good structure stability and superior electron/ion transportation. For potassium storage, as-prepared Y-S Ni-FeS₂@C shows excellent cyclic performance and sustains high capacities of 328 mA h g^-1 after 100 cycles at 0.2 A g^-1 and 226 mA h g^-1 after 1000 cycles at 1 A g^-1. Especially, it displays a superior rate capacity of 200 mA h g^-1 at 20 A g^-1, higher than that of Y-S FeS₂@C and most as-reported metal sulfide anodes for PIBs. The experimental analysis and theoretical calculation illuminate the effect of Ni-doping on decreasing the particle size of iron sulfide and enhancing the ion/electron transport ability, thus accounting for the exceptional rate capability of Y-S Ni-FeS₂@C composite.
- FeS₂,
- Ni-doping,
- yolk-shell structure,
- anode,
- potassium-ion batteries
1. [1]
  Armand, M.; Tarascon, J. M. Building better batteries. Nature 2008, 451, 652-657. doi: 10.1038/451652a
2. [2]
  Zeng, X. Q.; Li, M.; Abd El-Hady, D.; Alshitari, W.; Al-Bogami, A. S.; Lu, J.; Amine, K. Commercialization of lithium battery technologies for electric vehicles. Adv. Energy Mater. 2019, 9, 1900161.
3. [3]
  Li, M.; Lu, J.; Chen, Z. W.; Amine, K. 30 years of lithium-ion batteries. Adv. Mater. 2018, 30, 1800561. doi: 10.1002/adma.201800561
4. [4]
  Chen, M.; Wang, E.; Liu, Q.; Guo, X.; Chen, W.; Chou, S. L.; Dou, S. X. Recent progress on iron- and manganese-based anodes for sodiumion and potassium-ion batteries. Energy Storage Mater. 2019, 19, 163-179. doi: 10.1016/j.ensm.2019.03.030
5. [5]
  Liu, Y.; Yang, C.; Zhang, Q.; Liu, M. Recent progress in the design of metal sulfides as anode materials for sodium ion batteries. Energy Storage Mater. 2019, 22, 66-96. doi: 10.1016/j.ensm.2019.01.001
6. [6]
  Hosaka, T.; Kubota, K.; Hameed, A. S.; Komaba, S. Research development on K-ion batteries. Chem. Rev. 2020, 120, 6358-6466.
7. [7]
  Cao, J.; Xie, Y.; Yang, Y.; Wang, X.; Li, W.; Zhang, Q.; Ma, S.; Cheng, S.; Lu, B. Achieving uniform Li plating/stripping at ultrahigh currents and capacities by optimizing 3D nucleation sites and Li₂Se-enriched SEI. Adv. Sci. 2022, 202104689.
8. [8]
  Dhir, S.; Wheeler, S.; Capone, I.; Pasta, M. Outlook on K-ion batteries. Chem. 2020, 6, 2442-2460. doi: 10.1016/j.chempr.2020.08.012
9. [9]
  Zhang, W. C.; Yiu, L.; Guo, Z. P. Approaching high-performance potassium-ion batteries via advanced design strategies and engineering. Sci. Adv. 2019, 5, 7412. doi: 10.1126/sciadv.aav7412
10. [10]
  Kim, H.; Kim, J. C.; Bianchini, M.; Seo, D. H.; Rodriguez-Garcia, J.; Ceder, G. Recent progress and perspective in electrode materials for Kion batteries. Adv. Energy Mater. 2017, 8, 1702384.
11. [11]
  Chen, M.; Zhao, J. M.; Sun, C. F. High-volumetric-capacity WSe₂ anode for potassium-ion batteries. Chin. J. Struct. Chem. 2021, 40, 926-932.
12. [12]
  Pan, Q.; Tong, Z.; Su, Y.; Qin, S.; Tang, Y. Energy storage mechanism, challenge and design strategies of metal sulfides for rechargeable sodium/potassium-ion batteries. Adv. Funct. Mater. 2021, 31, 2103912. doi: 10.1002/adfm.202103912
13. [13]
  Wu, Y. H.; Zhang, C. L.; Zhao, H. P.; Lei, Y. Recent advances in ferromagnetic metal sulfides and selenides as anodes for sodium- and potassium-ion batteries. J. Mater. Chem. A 2021, 15, 9506-9534.
14. [14]
  Chen, J. W.; Chua, D. H. C.; Lee, P. S. The advances of metal sulfides and in situ characterization methods beyond Li ion batteries: sodium, potassium, and aluminum ion batteries. Small Methods 2020, 4, 1900648. doi: 10.1002/smtd.201900648
15. [15]
  Zhao, Y.; Wang, L. P.; Sougrati, M. T.; Feng, Z.; Leconte, Y.; Fisher, A.; Srinivasan, M.; Xu, Z. A review on design strategies for carbon based metal oxides and sulfides nanocomposites for high performance Li and Na ion battery anodes. Adv. Energy Mater. 2017, 7, 1601424. doi: 10.1002/aenm.201601424
16. [16]
  Xie, Y.; Cao, J.; Wang, X.; Li, W.; Deng, L.; Ma, S.; Zhang, H.; Guan, C.; Huang, W. MOF-derived bifunctional Co_{0. 85}Se nanoparticles embedded in N-doped carbon nanosheet arrays as efficient sulfur hosts for lithium-sulfur batteries. Nano Lett. 2021, 21, 8579-8586. doi: 10.1021/acs.nanolett.1c02037
17. [17]
  Geng, H. Y.; Peng, Y.; Qu, L. T.; Zhang, H. J.; Wu, M. H. Structure design and composition engineering of carbon-based nanomaterials for lithium energy storage. Adv. Energy Mater. 2020, 10, 1903030. doi: 10.1002/aenm.201903030
18. [18]
  Yang, X.; Wang, Z. D.; Fu, Y. R.; Liu, Q.; Xiao, G. Ca₂Nb₂O₇ as a novel open-framework anode material for potassium-ion batteries. Chin. J. Struct. Chem. 2021, 40, 233-238.
19. [19]
  Wang, C. Y.; Yao, Q. Q.; Gan, Y. M.; Zhang, Q. X.; Guan, L. H.; Zhao, Y. Monodispersed SWNTs assembled coating layer as an alternative to graphene with enhanced alkali-ion storage performance. Chin. J. Struct. Chem. 2022, 41, 2201040-2201046.
20. [20]
  Wu, C.; Tong, X.; Ai, Y. F.; Liu, D. S.; Yu, P.; Wu, J.; Wang, Z. M. M. A review: enhanced anodes of Li/Na-ion batteries based on yolk-shell structured nanomaterials. Nano-Micro Lett. 2018, 10, 40.
21. [21]
  Shi, X. L.; Gan, Y. M.; Zhang, Q. X.; Wang, C. Y.; Zhao, Y.; Guan, L. H.; Huang, W. A partial sulfuration strategy derived multi-yolk-shell structure for ultra-stable K/Na/Li-ion storage. Adv. Mater. 2021, 33, 2100837.
22. [22]
  Zhao, Y.; Shi, X. L.; Ong, S. J. H.; Yao, Q. Q.; Chen, B.; Hou, K.; Liu, C.; Xu, Z. J.; Guan, L. H. Enhancing the charge transportation ability of yolk-shell structure for high-rate sodium and potassium storage. ACS Nano 2020, 14, 4463-4474.
23. [23]
  Liu, S.; Li, X. Z.; Huang, B.; Yang, J. W.; Chen, Q. Q.; Li, Y. W.; Xiao, S. H. Controllable construction of yolk-shell Sn-Co@void@C and its advantages in Na-ion storage. Rare Metals 2021, 40, 2392.
24. [24]
  Lin, L. S.; Song, J.; Yang, H. H.; Chen, X. Yolk-shell nanostructures: design, synthesis, and biomedical applications. Adv. Mater. 2018, 30, 1704639.
25. [25]
  Yao, Q. Q.; Zhang, J. S.; Li, J. X.; Huang, W. J.; Hou, K.; Zhao, Y.; Guan, L. H. Yolk-shell NiS_x@C nanosheets as K-ion battery anodes with high rate capability and ultralong cycle life. J. Mater. Chem. A 2019, 32, 18932.
26. [26]
  Yang, F. H.; Gao, H.; Hao, J. N.; Zhang, S. L.; Li, P.; Liu, Y. Q.; Chen, J.; Guo, Z. P. Yolk-shell structured FeP@C nanoboxes as advanced anode materials for rechargeable lithium‐/potassium-ion batteries. Adv. Funct. Mater. 2019, 29, 1808291.
27. [27]
  Li, Y.; Chen, M. H.; Liu, B.; Zhang, Y.; Liang, X. Q.; Xia, X. H. Heteroatom doping: an effective way to boost sodium ion storage. Adv. Energy Mater. 2020, 10, 2000927.
28. [28]
  Chen, B.; Chao, D. L.; Liu, E. Z.; Jaroniec, M.; Zhao, N. Q.; Qiao, S. Z. Transition metal dichalcogenides for alkali metal ion batteries: engineering strategies at the atomic level. Energy Environ. Sci. 2020, 13, 1096-1131.
29. [29]
  Tan, Z.; Sharma, L.; Kakkar, R.; Meng, T.; Jiang, Y.; Cao, M. H. Arousing the reactive Fe sites in pyrite (FeS₂) via integration of electronic structure reconfiguration and in situ electrochemical topotactic transformation for highly efficient oxygen evolution reaction. Inorg. Chem. 2019, 58, 7615-7627.
30. [30]
  Li, J.; Liu, Q.; Zhang, Y.; Jiang, J.; Wu, H. B.; Yu, X. Y. Copper and carbon-incorporated yolk-shelled FeP spheres with enhanced sodium storage properties. Chem. Eng. J. 2021, 421, 127776.
31. [31]
  Fang, Y.; Yu, X. Y.; Lou, X. W. D. Formation of hierarchical Cu-doped CoSe₂ microboxes via sequential ion exchange for high-performance sodium-ion batteries. Adv. Mater. 2018, 21, 1706668.
32. [32]
  Xuan, S. H.; Wang, F.; Wang, Y. X. J.; Yu, J. C.; Leung, K. C. F. Facile synthesis of size-controllable monodispersed ferrite nanospheres. J. Mater. Chem. 2010, 20, 5086-5094.
33. [33]
  Yao, Q. Q.; Gan, Y. M.; Ma, Z. J.; Qian, X. Y.; Cai, S. Z.; Zhao, Y.; Guan, L. H.; Huang, W. Approaching superior potassium storage of carbonaceous anode through a combined strategy of carbon hybridization and sulfur doping. Energy Environ. Mater. 2021, DOI:10.1002/eem2.12217. doi: 10.1002/eem2.12217
34. [34]
  Han, K.; Zhao, W.; Yu, Q.; Liu, Z.; Li, P.; Wang, W.; Song, L.; An, F.; Cao, P.; Qu, X. Marcasite-FeS₂@carbon nanodots anchored on 3D celllike graphenic matrix for high-rate and ultrastable potassium ion storage. J. Power Sources 2020, 469, 228429.
35. [35]
  Luo, Y.; Tao, M.; Deng, J.; Zhan, R.; Guo, B.; Ma, Q.; Aslam, M. K.; Qi, Y.; Xu, M. Nanocubes composed of FeS₂@C nanoparticles as advanced anode materials for K-ion storage. Inorg. Chem. Front. 2020, 7, 394-401.
36. [36]
  Salvati, L.; Makovsky, L. E.; Stencel, J. M.; Brown, F. R.; Hercules, D. M. Surface spectroscopic study of tungsten-alumina catalysts using X-ray photoelectron, ion scattering, and Raman spectroscopies. J. Phys. Chem. 1982, 85, 3700-3707.
37. [37]
  Wu, H. F.; Gan, Y. M.; Yao, Q. Q.; Wang, L. P.; Wang, C. Y.; Zhang, Q. X.; Hou, K.; Zhao, Y.; Guan, L. H. Boosting the lithium and sodium storage performance of graphene-based composite via pore engineering and surface protection. Nanotechnology 2021, 32, 105402.
38. [38]
  Zhao, Y.; Zhu, J.; Ong, S. J. H.; Yao, Q.; Shi, X.; Hou, K.; Xu, Z. J.; Guan, L. H. High-rate and ultralong cycle-life potassium ion batteries enabled by in situ engineering of yolk-shell FeS₂@C structure on graphene matrix. Adv. Energy Mater. 2018, 8, 1802565.
39. [39]
  Yang, S. H.; Park, S. K.; Park, G. D.; Kim, J. H.; Kang, Y. C. Rational synthesis of uniform yolk-shell Ni-Fe bimetallic sulfide nanoflakes@porous carbon nanospheres as advanced anodes for high-performance potassium-/sodium-ion batteries. Chem. Eng. J. 2021, 417, 127963.
40. [40]
  Augustyn, V.; Come, J.; Lowe, M. A.; Kim, J. W.; Taberna, P. L.; Tolbert, S. H.; Abruna, H. D.; Simon, P.; Dunn, B. High-rate electrochemical energy storage through Li⁺ intercalation pseudocapacitance. Nat. Mater. 2013, 12, 518-522.
41. [41]
  Kim, H. S.; Cook, J. B.; Lin, H.; Ko, J. S.; Tolbert, S. H.; Ozolins, V.; Dunn, B. Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO_3-x. Nat. Mater. 2017, 16, 454.
42. [42]
  Li, D.; Dai, L.; Ren, X.; Ji, F.; Sun, Q.; Zhang, Y.; Ci, L. Foldable potassium-ion batteries enabled by free-standing and flexible SnS₂@C nanofibers. Energy Environ. Sci. 2021, 14, 424-436.
43. [43]
  Shen, Z.; Cao, L.; Rahn, C. D.; Wang, C. Y. Least squares galvanostatic intermittent titration technique (LS-GITT) for accurate solid phase diffusivity measurement. J. Electrochem. Soc. 2013, 160, A1842-A1846.
44. [44]
  Li, W. D.; Wang, D. Z.; Gong, Z. J.; Yin, Z. M.; Guo, X. S.; Liu, J.; Mao, C. M.; Zhang, Z. H.; Li, G. C. A robust strategy for engineering Fe₇S₈/C hybrid nanocages reinforced by defect-rich MoS₂ nanosheets for superior potassium-ion storage. ACS Nano 2020, 14, 16046-16056.
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