Citation: Rui Zhai, Yindi Zhu, Limei Chang, Zhigang Gu, Jian Zhang. Layer-by-Layer Grafting Dye on Chiral MOF Thin Films for Circularly Polarized Luminescence[J]. Chinese Journal of Structural Chemistry, ;2022, 41(9): 220907. doi: 10.14102/j.cnki.0254-5861.2022-0023 shu

Layer-by-Layer Grafting Dye on Chiral MOF Thin Films for Circularly Polarized Luminescence

Rui Zhai ^{1, 2} ,
Yindi Zhu ¹ ,
Limei Chang ¹ ,
Zhigang Gu ^{1, 3,,} ,
Jian Zhang ^{1, 3,,}

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
2.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
3.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

Corresponding author: Zhigang Gu, zggu@fjirsm.ac.cn Jian Zhang, zhj@fjirsm.ac.cn
Received Date: 5 February 2022
Accepted Date: 4 April 2022
Available Online: 15 April 2022

Figures(4)

Metal-organic frameworks with chiral feature (chirMOFs) are attracting great attention on circularly polarized luminescence (CPL). However, developing new efficient strategy to achieve or improve CPL properties is an urgent task. Herein, new chiral MOF thin films prepared by liquid-phase epitaxial layer by layer (lbl) growth method (SURchirMOF) are composed of D- or L-camphorate (D/Lcam) and aminopyrazine (Pr-NH₂) by using liquid phase epitaxial layer by layer (lbl) method. The resulted Zn₂(D/Lcam)₂Pr-NH₂ SURchirMOF shows strong chirality and luminescence but weak CPL emission at 390 nm. After lbl modifying a dye molecule FluoresceinIsothiocyanate (FITC), the chiroptical Zn₂(D/Lcam)₂Pr-NH-FITC SURchirMOFs with ~7 times CPL signal improvement and ~3 times g_lum value amplification are obtained. This work provides a new strategy to develop chiral MOF thin films for CPL improvement using lbl grafting approach.
- metal-organic frameworks,
- liquid-phase epitaxy,
- thin film,
- circularly polarized luminescence
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