Citation: Yaoyao Chen, Changhao Gao, Tian Yang, Wenjing Li, Haojie Xu, Zhihua Sun. Research Advances of Ferroelectric Semiconductors of 2D Hybrid Perovskites toward Photoelectronic Applications[J]. Chinese Journal of Structural Chemistry, ;2022, 41(4): 220400. doi: 10.14102/j.cnki.0254-5861.2022-0013 shu

Research Advances of Ferroelectric Semiconductors of 2D Hybrid Perovskites toward Photoelectronic Applications

Yaoyao Chen ^{1, 2, †} ,
Changhao Gao ^{1, 2, †} ,
Tian Yang ^{1, 2} ,
Wenjing Li ^{1, 3} ,
Haojie Xu ^{1, 3} ,
Zhihua Sun ^{1, 2, 3,,}

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
2.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Zhihua Sun, sunzhihua@fjirsm.ac.cn
Received Date: 19 January 2022
Accepted Date: 11 February 2022

Figures(12)

Ferroelectric materials, characterized by the switchable spontaneous polarization (P_s) through reversing the directions of external electric field, exhibit versatile physical attributes that have been extensively used for practical device applications. Two-dimensional (2D) organic-inorganic hybrid perovskites are recently emerging as a robust family of candidate ferroelectrics, termed ferroelectric semiconductors. In particular, the coexistence and/or coupling of ferroelectric polarization with their semiconducting properties enables new physical concepts, thus providing a potential platform for the development of new multifunctional optoelectronic devices. This review primarily describes the structural origin of symmetry breaking for generating ferroelectric orders in 2D hybrid perovskites, and then presents the combination of ferroelectric P_s with other semiconducting optoelectronic activities. Regarding the emergence of new photoelectric behaviors, the prospects for this 2D family of ferroelectric semiconductors are further discussed, along with their development tendency for the future photoelectronic device applications.
- ferroelectric materials,
- hybrid perovskites,
- semiconductor properties,
- two-dimensional
1. [1]
  Sun, Z. H.; Yi, X. F.; Tao, K. W.; Ji, C. M.; Liu, X. T.; Li, L. N.; Han, S. G.; Zheng, A. M.; Hong, M. C.; Luo, J. H. A molecular ferroelectric showing room-temperature record-fast switching of spontaneous polarization. Angew. Chem. Int. Ed. 2018, 57, 9833–9837. doi: 10.1002/anie.201805776
2. [2]
  Pandey, R.; Vats, G.; Yun, J.; Bowen, C. R.; Ho-Baillie, A. W. Y.; Seidel, J.; Butler, K. T.; Seok, S. I. Mutual insight on ferroelectrics and hybrid halide perovskites: a platform for future multifunctional energy conversion. Adv. Mater. 2019, 31, 1807376. doi: 10.1002/adma.201807376
3. [3]
  You, Y. M.; Liao, W. Q.; Zhao, D. W.; Ye, H. Y.; Zhang, Y.; Zhou, Q. H.; Niu, X. H.; Wang, J. L.; Li, P. F.; Fu, D. W.; Wang, Z. M.; Gao, S.; Yang, K. L.; Liu, J. M.; Li, J. Y.; Yan, Y. F.; Xiong, R. G. An organic-inorganic perovskite ferroelectric with large piezoelectric response. Science 2017, 357, 306–309. doi: 10.1126/science.aai8535
4. [4]
  Scott, J. F. Applications of modern ferroelectrics. Science 2007, 315, 954–959. doi: 10.1126/science.1129564
5. [5]
  Scott, J. F. Ferroelectric Memories Springer-Verlag. Berlin 2000.
6. [6]
  Ye, Z. G. Handbook of Advanced Dielectric, Piezoelectric and Ferroelectric Materials: Synthesis, Properties and Applications. Elsevier 2008.
7. [7]
  Spaldin, N. A.; Fiebig, M.; Mostovoy, M. The toroidal moment in condensed-matter physics and its relation to the magnetoelectric effect. J. Phys. : Condens. Matter. 2008, 20, 434203. doi: 10.1088/0953-8984/20/43/434203
8. [8]
  Litvin, D. B. Ferroic classifications extended to ferrotoroidic crystals. Acta Crystallogr. Sect. A: Found. Crystallogr. 2008, 64, 316–320. doi: 10.1107/S0108767307068262
9. [9]
  Lee, J. H.; Fang, L.; Vlahos, E.; Ke, X.; Jung, Y. W.; Kourkoutis, L. F.; Kim, J. W.; Ryan, P. J.; Heeg, T.; Roeckerath, M.; Goian, V.; Bernhagen, M.; Uecker, R.; Hammel, P. C.; Rabe, K. M.; Kamba, S.; Schubert, J.; Freeland, J. W.; Muller, D. A.; Fennie, C. J.; Schiffer, P.; Gopalan, V.; Johnston-Halperin, E.; Schlom, D. G. A strong ferroelectric ferromagnet created by means of spin-lattice coupling. Nature 2010, 466, 954–958. doi: 10.1038/nature09331
10. [10]
  Horiuchi, S.; Tokura, Y. Organic ferroelectrics. Nat. Mater. 2008, 7, 357–366. doi: 10.1038/nmat2137
11. [11]
  Hu, P. F.; Hu, S. B.; Huang, Y. D.; Reimers, J. R.; Rappe, A. M.; Li, Y. L.; Stroppa, A.; Ren, W. Bioferroelectric properties of glycine crystals. J. Phys. Chem. Lett. 2019, 10, 1319–1324. doi: 10.1021/acs.jpclett.8b03837
12. [12]
  Fu, D. W.; Zhang, W.; Cai, H. L.; Ge, J. Z.; Zhang, Y.; Xiong, R. G. Diisopropylammonium chloride: a ferroelectric organic salt with a high phase transition temperature and practical utilization level of spontaneous polarization. Adv. Mater. 2011, 23, 201102938.
13. [13]
  Valasek, J. Piezo-electric and allied phenomena in Rochelle salt. Phys. Rev. 1921, 17, 475–481. doi: 10.1103/PhysRev.17.475
14. [14]
  Han, S. G.; Li, M. F.; Liu, Y.; Guo, W. Q.; Hong, M. C.; Sun, Z. H.; Luo, J. H. Tailoring of a visible-light-absorbing biaxial ferroelectric towards broadband self-driven photodetection. Nat. Commun. 2021, 12, 284. doi: 10.1038/s41467-020-20530-4
15. [15]
  Fu, D. W.; Cai, H. L.; Liu, Y. M.; Ye, Q.; Zhang, W.; Zhang, Y.; Chen, X. Y.; Giovannetti, G.; Capone, M.; Li, J. Y.; Xiong, R. G. Diisopropyl-ammonium bromide is a high-temperature molecular ferroelectric crystal. Science 2013, 339, 425–428. doi: 10.1126/science.1229675
16. [16]
  Ye, H. Y.; Tang, Y. Y.; Li, P. F.; Liao, W. Q.; Gao, J. X.; Hua, X. N.; Cai, H.; Shi, P. P.; You, Y. M.; Xiong, R. G. Metal-free three-dimensional perovskite ferroelectrics. Science 2018, 361, 151–155. doi: 10.1126/science.aas9330
17. [17]
  Xu, H. J.; Guo, W. Q.; Wang, J. Q.; Ma, Y.; Han, S. G.; Liu, Y.; Lu, L.; Pan, X.; Luo, J. H.; Sun, Z. H. A metal-free molecular antiferroelectric material showing high phase transition temperatures and large electrocaloric effects. J. Am. Chem. Soc. 2021, 143, 14379–14385. doi: 10.1021/jacs.1c07521
18. [18]
  Kundys, B.; Lappas, A.; Viret, M.; Kapustianyk, V.; Rudyk, V.; Semak, S.; Simon, C.; Bakaimi, I. Multiferroicity and hydrogen-bond ordering in (C₂H₅NH₃)₂CuCl₄ featuring dominant ferromagnetic interactions. Phys. Rev. B 2010, 81, 224434. doi: 10.1103/PhysRevB.81.224434
19. [19]
  Li, L. N.; Liu, X. T.; Li, Y. B.; Xu, Z.; Wu, Z. Y.; Han, S. G.; Tao, K. W.; Hong, M. C.; Luo, J. H.; Sun, Z. H. Two-dimensional hybrid perovskite-type ferroelectric for highly polarization-sensitive shortwave photodetection. J. Am. Chem. Soc. 2019, 141, 2623–2629. doi: 10.1021/jacs.8b12948
20. [20]
  Ma, Y.; Wang, J. Q.; Guo, W. Q.; Han, S. G.; Xu, J. L.; Liu, Y.; Lu, L.; Xie, Z. D.; Luo, J. H.; Sun, Z. H. The first improper ferroelectric of 2D multilayered hybrid perovskite enabling strong tunable polarization-directed second harmonic generation effect. Adv. Fun. Mater. 2021, 31, 2103012. doi: 10.1002/adfm.202103012
21. [21]
  Liu, H. Y.; Zhang, H. Y.; Chen, X. G.; Xiong, R. G. Molecular design principles for ferroelectrics: ferroelectrochemistry. J. Am. Chem. Soc. 2020, 142, 15205–15218. doi: 10.1021/jacs.0c07055
22. [22]
  Cohen, R. E. Origin of ferroelectricity in perovskite oxides. Nature 1992, 358, 136–138. doi: 10.1038/358136a0
23. [23]
  Fu, H. X.; Cohen, R. E. Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics. Nature 2000, 403, 281–283. doi: 10.1038/35002022
24. [24]
  Saha, S.; Sinha, T. P.; Mookerjee, A. Electronic structure, chemical bonding, and optical properties of paraelectric BaTiO₃. Phys. Rev. B 2000, 62, 8828–8834. doi: 10.1103/PhysRevB.62.8828
25. [25]
  Levin, I.; Tucker, M. C.; Wu, H.; Provenzano, V.; Dennis, C. L.; Karimi, S.; Comyn, T.; Stevenson, T.; Smith, R. I.; Reaney, I. M. Displacive phase transitions and magnetic structures in Nd-substituted BiFeO₃. Chem. Mater. 2011, 23, 2166–2175. doi: 10.1021/cm1036925
26. [26]
  Shi, P. P.; Tang, Y. Y.; Li, P. F.; Liao, W. Q.; Wang, Z. X.; Ye, Q.; Xiong, R. G. Symmetry breaking in molecular ferroelectrics. Chem. Soc. Rev. 2016, 45, 3811–3827. doi: 10.1039/C5CS00308C
27. [27]
  Zhang, W.; Xiong, R. G. Ferroelectric metal-organic frameworks. Chem. Rev. 2012, 112, 1163–1195. doi: 10.1021/cr200174w
28. [28]
  Xu, G. C.; Ma, X. M.; Zhang, L.; Wang, Z. M.; Gao, S. Disorder-order ferroelectric transition in the metal formate framework of [NH₄][Zn(HCOO)₃]. J. Am. Chem. Soc. 2010, 132, 9588–9590. doi: 10.1021/ja104263m
29. [29]
  Xu, G. C.; Zhang, W.; Ma, X. M.; Chen, Y. H.; Zhang, L.; Cai, H. L.; Wang, Z. M.; Xiong, R. G.; Gao, S. Coexistence of magnetic and electric orderings in the metal-formate frameworks of [NH₄][M(HCOO)₃]. J. Am. Chem. Soc. 2011, 133, 14948–14951. doi: 10.1021/ja206891q
30. [30]
  Xu, H. J.; Han, S. G.; Sun, Z. H.; Luo, J. H. Recent advances of two-dimensional organic-inorganic hybrid perovskite ferroelectric materials. Acta Chim. Sin. 2021, 79, 23–35. doi: 10.6023/A20080375
31. [31]
  Wang, Y. N.; Huang, J. W.; Wang, L.; She, H. D.; Wang, Q. Z. Research progress of ferrite materials for photoelectrochemical water splitting. Chin. J. Struct. Chem. 2022, 41, 2201054–2201068.
32. [32]
  Ji, C. M.; Li, Y. Z.; Liu, X. T.; Wang, Y. X.; Zhu, T. T.; Chen, Q.; Li, L. N.; Wang, S. A.; Luo, J. H. Monolayer-to-multilayer dimensionality reconstruction in a hybrid perovskite for exploring the bulk photovoltaic effect enables passive X-ray detection. Angew. Chem. Int. Ed. 2021, 60, 20970–20976. doi: 10.1002/anie.202108145
33. [33]
  Li, M. F.; Han, S. G.; Liu, Y.; Luo, J. H.; Hong, M. C.; Sun, Z. H. Soft perovskite-type antiferroelectric with giant electrocaloric strength near room temperature. J. Am. Chem. Soc. 2020, 142, 20744–20751. doi: 10.1021/jacs.0c09601
34. [34]
  Han, S. G.; Wang, G. E.; Xu, G.; Luo, J. H.; Sun, Z. H. Ferroelectric perovskite-type films with robust in-plane polarization toward efficient room-temperature chemiresistive sensing. Fundam. Res. 2022, doi: 10.1016/j.fmre.2022.01.015. doi: 10.1016/j.fmre.2022.01.015
35. [35]
  Zhang, H.; Chen, X.; Tang, Y.; Liao, W.; Di, F.; Mu, X.; Peng, H.; Xiong, R. PFM (piezoresponse force microscopy)-aided design for molecular ferroelectrics. Chem. Soc. Rev. 2021, 50, 8248–8278. doi: 10.1039/C9CS00504H
36. [36]
  You, Y. M.; Tang, Y. Y.; Li, P. F.; Zhang, H. Y.; Zhang, W. Y.; Zhang, Y.; Ye, H. Y.; Nakamura, T.; Xiong, R. G. Quinuclidinium salt ferroelectric thin-film with duodecuple-rotational polarization-directions. Nat. Commun. 2017, 8, 14934. doi: 10.1038/ncomms14934
37. [37]
  Tang, Y. Y.; Xie, Y. F.; Zeng, Y. L.; Liu, J. C.; He, W. H.; Huang, X. Q.; Xiong, R. G. Record enhancement of phase transition temperature realized by H/F substitution. Adv. Mater. 2020, 32, 2003530.
38. [38]
  Ji, C. M.; Wang, S.; Li, L. N.; Sun, Z. H.; Hong, M. C.; Luo, J. H. The first 2D hybrid perovskite ferroelectric showing broadband white-light emission with high color rendering index. Adv. Fun. Mater. 2018, 29, 1805038.
39. [39]
  Cortecchia, D.; Yin, J.; Bruno, A.; Lo, S. A.; Gurzadyan, G. G.; Mhaisalkar, S.; Brédas, J.; Soci, C. Polaron self-localization in white-light emitting hybrid perovskites. J. Mater. Chem. C 2017, 5, 2771–2780. doi: 10.1039/C7TC00366H
40. [40]
  Sha, T. T.; Xiong, Y. A.; Pan, Q.; Chen, X. G.; Song, X. J.; Yao, J.; Miao, S. R.; Jing, Z. Y.; Feng, Z. J.; You, Y. M.; Xiong, R. G. Fluorinated 2D lead iodide perovskite ferroelectrics. Adv. Mater. 2019.
41. [41]
  Aizu, K. Possible species of "ferroelastic" crystals and of simultaneously ferroelectric and ferroelastic crystals. J. Phys. Soc. Jpn. 1969, 27, 387–396. doi: 10.1143/JPSJ.27.387
42. [42]
  Aizu, K. Possible species of ferromagnetic, ferroelectric, and ferroelastic crystals. Phys. Rev. B 1970, 2, 754–772. doi: 10.1103/PhysRevB.2.754
43. [43]
  Ji, C. M.; Dey, D.; Peng, Y.; Liu, X. T.; Li, L. N.; Luo, J. H. Ferroelectricity-driven self-powered ultraviolet photodetection with strong polarization sensitivity in a two-dimensional halide hybrid perovskite. Angew. Chem. Int. Ed. 2020, 59, 18933–18937. doi: 10.1002/anie.202005092
44. [44]
  Huang, P. J.; Taniguchi, K.; Miyasaka, H. Bulk photovoltaic effect in a pair of chiral-polar layered perovskite-type lead iodides altered by chirality of organic cations. J. Am. Chem. Soc. 2019, 141, 14520–14523. doi: 10.1021/jacs.9b06815
45. [45]
  Ji, W.; Yao, K.; Liang, Y. C. Bulk photovoltaic effect at visible wavelength in epitaxial ferroelectric BiFeO₃ thin films. Adv. Mater. 2010, 22, 1763–1766. doi: 10.1002/adma.200902985
46. [46]
  Yang, S. Y.; Seidel, J.; Byrnes, S. J.; Shafer, P.; Yang, C. H.; Rossell, M. D.; Yu, P.; Chu, Y. H.; Scott, J. F.; Ager, J. W., 3rd; Martin, L. W.; Ramesh, R. Above-bandgap voltages from ferroelectric photovoltaic devices. Nat. Nanotechnol. 2010, 5, 143–147. doi: 10.1038/nnano.2009.451
47. [47]
  Li, L. N.; Sun, Z. H.; Wang, P.; Hu, W. D.; Wang, S. S.; Ji, C. M.; Hong, M. C.; Luo, J. H. Tailored engineering of an unusual (C₄H₉NH₃)₂(CH₃NH₃)₂Pb₃Br₁₀ two-dimensional multilayered perovskite ferroelectric for a high-performance photodetector. Angew. Chem. Int. Ed. 2017, 56, 12150–12154. doi: 10.1002/anie.201705836
48. [48]
  Li, L. N.; Shang, X. Y.; Wang, S. S.; Dong, N. N.; Ji, C. M.; Chen, X. Y.; Zhao, S. G.; Wang, J.; Sun, Z. H.; Hong, M. C.; Luo, J. H. Bilayered hybrid perovskite ferroelectric with giant two-photon absorption. J. Am. Chem. Soc. 2018, 140, 6806–6809. doi: 10.1021/jacs.8b04014
49. [49]
  Zhang, R.; Fan, J. D.; Zhang, X.; Yu, H. H.; Zhang, H. J.; Mai, Y. H.; Xu, T. X.; Wang, J. Y.; Snaith, H. J. Nonlinear optical response of organic-inorganic halide perovskites. ACS Photonics 2016, 3, 371–377. doi: 10.1021/acsphotonics.5b00563
50. [50]
  Wang, J. Q.; Liu, Y.; Han, S. G.; Ma, Y.; Li, Y. B.; Xu, Z. Y.; Luo, J. H.; Hong, M. C.; Sun, Z. H. Ultrasensitive polarized-light photodetectors based on 2D hybrid perovskite ferroelectric crystals with a low detection limit. Sci. Bull. 2021, 66, 158–163. doi: 10.1016/j.scib.2020.06.018
51. [51]
  Wu, Z. Y.; Ji, C. M.; Li, L. N.; Kong, J. T.; Sun, Z. H.; Zhao, S. G.; Wang, S. S.; Hong, M. C.; Luo, J. H. Alloying n-butylamine into CsPbBr₃ to give a two-dimensional bilayered perovskite ferroelectric material. Angew. Chem. Int. Ed. 2018, 57, 8140–8143. doi: 10.1002/anie.201803716
52. [52]
  Liu, Y.; Pan, X.; Liu, X. T.; Han, S. G.; Wang, J. Q.; Lu, L.; Xu, H. J.; Sun, Z. H.; Luo, J. H. Tailoring interlayered spacers of 2D cesium-based perovskite ferroelectrics toward exceptional ferro-pyro-phototronic effects. Small 2021, 2106888.
53. [53]
  Liu, Y.; Han, S. G.; Wang, J. Q.; Ma, Y.; Guo, W. Q.; Huang, X. Y.; Luo, J. H.; Hong, M. C.; Sun, Z. H. Spacer cation alloying of a homoconformational carboxylate trans isomer to boost in-plane ferroelectricity in a 2D hybrid perovskite. J. Am. Chem. Soc. 2021, 143, 2130–2137. doi: 10.1021/jacs.0c12513
54. [54]
  Wang, J.; Gudiksen, M. S.; Duan, X.; Cui, Y.; Lieber, C. M. Highly polarized photoluminescence and photodetection from single indium phosphide nanowires. Science 2001, 293, 1455–1457. doi: 10.1126/science.1062340
55. [55]
  Peng, Y.; Liu, X. T.; Sun, Z. H.; Ji, C. M.; Li, L. N.; Wu, Z. Y.; Wang, S. S.; Yao, Y. P.; Hong, M. C.; Luo, J. H. Exploiting the bulk photovoltaic effect in a 2D trilayered hybrid ferroelectric for highly sensitive polarized light detection. Angew. Chem. Int. Ed. 2020, 59, 3933–3937. doi: 10.1002/anie.201915094
56. [56]
  Xu, Z. Y.; Weng, W.; Li, Y. B.; Liu, X. T.; Yang, T.; Li, M. F.; Huang, X. Y.; Luo, J. H.; Sun, Z. H. 3D-to-2D dimensional reduction for exploiting a multilayered perovskite ferroelectric toward polarized-light detection in the solar-blind ultraviolet region. Angew. Chem. Int. Ed. 2020, 59, 21693–21697. doi: 10.1002/anie.202009329
57. [57]
  Chen, H. Y.; Liu, K. W.; Hu, L. F.; Al-Ghamdi, A. A.; Fang, X. S. New concept ultraviolet photodetectors. Mater. Today 2015, 18, 493–502. doi: 10.1016/j.mattod.2015.06.001
58. [58]
  Xie, C.; Lu, X. T.; Tong, X. W.; Zhang, Z. X.; Liang, F. X.; Liang, L.; Luo, L. B.; Wu, Y. C. Recent progress in solar-blind deep-ultraviolet photodetectors based on inorganic ultrawide bandgap semiconductors. Adv. Fun. Mater. 2019, 29, 1806006. doi: 10.1002/adfm.201806006
59. [59]
  Sutherland, R. L. Handbook of Nonlinear Optics. CRC Press 2003.
60. [60]
  Li, M. F.; Xu, Y. M.; Han, S. G.; Xu, J. L.; Xie, Z. D.; Liu, Y.; Xu, Z. Y.; Hong, M. C.; Luo, J. H.; Sun, Z. H. Giant and broadband multiphoton absorption nonlinearities of a 2D organometallic perovskite ferroelectric. Adv. Mater. 2020, 32, 2002972.
61. [61]
  Nicolo, F.; Plancherel, D.; Chapuis, G.; Buenzli, J. C. G. Complexes of lanthanoid salts with macrocyclic ligands. 34. Glasslike structure in crystalline macrocyclic complexes: synthesis, X-ray diffraction, and laser-spectroscopic investigation of neodymium(III) and europium(III) complexes with 4, 13-dimethyl-1, 7, 10, 16-tetraoxa-4, 13-diazacyclooctadecane. Inorg. Chem. 1988, 27, 3518–3526. doi: 10.1021/ic00293a018
62. [62]
  Shi, C.; Ye, L.; Gong, Z. X.; Ma, J. J.; Wang, Q. W.; Jiang, J. Y.; Hua, M. M.; Wang, C. F.; Yu, H.; Zhang, Y.; Ye, H. Y. Two-dimensional organic-inorganic hybrid rare-earth double perovskite ferroelectrics. J. Am. Chem. Soc. 2020, 142, 545–551. doi: 10.1021/jacs.9b11697
63. [63]
  Guo, W. Q.; Liu, X. T.; Han, S. G.; Liu, Y.; Xu, Z. Y.; Hong, M. C.; Luo, J. H.; Sun, Z. H. Room-temperature ferroelectric material composed of a two-dimensional metal halide double perovskite for X-ray detection. Angew. Chem. Int. Ed. 2020, 59, 13879–13884. doi: 10.1002/anie.202004235
64. [64]
  Tsai, H.; Nie, W.; Blancon, J. C.; Stoumpos, C. C.; Asadpour, R.; Harutyunyan, B.; Neukirch, A. J.; Verduzco, R.; Crochet, J. J.; Tretiak, S.; Pedesseau, L.; Even, J.; Alam, M. A.; Gupta, G.; Lou, J.; Ajayan, P. M.; Bedzyk, M. J.; Kanatzidis, M. G. High-efficiency two-dimensional Ruddlesden-Popper perovskite solar cells. Nature 2016, 536, 312–316. doi: 10.1038/nature18306
65. [65]
  Blancon, J. C.; Tsai, H.; Nie, W.; Stoumpos, C. C.; Pedesseau, L.; Katan, C.; Kepenekian, M.; Soe, C. M. M.; Appavoo, K.; Sfeir, M. Y.; Tretiak, S.; Ajayan, P. M.; Kanatzidis, M. G.; Even, J.; Crochet, J. J.; Mohite, A. D. Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites. Science 2017, 355, 1288–1292. doi: 10.1126/science.aal4211
1. [1]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
2. [2]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
3. [3]
  Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235
4. [4]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
5. [5]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
6. [6]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
7. [7]
  Yan Cheng , Hai-Quan Yao , Ya-Di Zhang , Chao Shi , Heng-Yun Ye , Na Wang . Nitrate-bridged hybrid organic-inorganic perovskites. Chinese Journal of Structural Chemistry, 2024, 43(9): 100358-100358. doi: 10.1016/j.cjsc.2024.100358
8. [8]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
9. [9]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
10. [10]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
11. [11]
  Yuting Wu , Haifeng Lv , Xiaojun Wu . Design of two-dimensional porous covalent organic framework semiconductors for visible-light-driven overall water splitting: A theoretical perspective. Chinese Journal of Structural Chemistry, 2024, 43(11): 100375-100375. doi: 10.1016/j.cjsc.2024.100375
12. [12]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
13. [13]
  Changhui Yu , Peng Shang , Huihui Hu , Yuening Zhang , Xujin Qin , Linyu Han , Caihe Liu , Xiaohan Liu , Minghua Liu , Yuan Guo , Zhen Zhang . Evolution of template-assisted two-dimensional porphyrin chiral grating structure by directed self-assembly using chiral second harmonic generation microscopy. Chinese Chemical Letters, 2024, 35(10): 109805-. doi: 10.1016/j.cclet.2024.109805
14. [14]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
15. [15]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
16. [16]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
17. [17]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
18. [18]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
19. [19]
  Xingwen Cheng , Haoran Ren , Jiangshan Luo . Boosting the self-trapped exciton emission in vacancy-ordered double perovskites via supramolecular assembly. Chinese Journal of Structural Chemistry, 2024, 43(6): 100306-100306. doi: 10.1016/j.cjsc.2024.100306
20. [20]
  Haiyang Gu , Xiang Xu . Multicolor hybrid metal halides and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(9): 100352-100352. doi: 10.1016/j.cjsc.2024.100352

Get Citation

PDF

XML

Metrics

PDF Downloads(24)
Abstract views(645)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142