Citation: Ruiyan Chen, Guanghui Chen, Yanping He, Jian Zhang. Coordination Assembly of Tetrahedral Ti₄(embonate)₆ Cages with Alkaline-Earth Metal Ions[J]. Chinese Journal of Structural Chemistry, ;2022, 41(1): 220100. doi: 10.14102/j.cnki.0254-5861.2021-0016 shu

Coordination Assembly of Tetrahedral Ti₄(embonate)₆ Cages with Alkaline-Earth Metal Ions

Ruiyan Chen ^{1, 2} ,
Guanghui Chen ² ,
Yanping He ^2,, ,
Jian Zhang ^2,,

1.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Yanping He, hyp041@163.com Jian Zhang, zhj@fjirsm.ac.cn
Received Date: 28 October 2021
Accepted Date: 19 November 2021

Figures(6)

Recently, the tetrahedral Ti₄L₆ cage (L = embonate) has been applied as the starting material to realize coordination assembly with transition and rare-earth ornoble metal ions through a two-step reaction. In this work, by employing the Ti₄L₆ cages to assemble with alkaline-earth metal ions (such as Mg²⁺, Ca²⁺ and Ba²⁺) under different solvothermal conditions, a series of Ti₄L₆-based structures from simple cages to 1D chain, 2D layer and 3D framework have been synthesized and structurally characterized. In addition, thermal stability, phase purity, UV-vis absorption spectrum, the fluorescent and third-order nonlinear-optical properties are also investigated.
- metal-organic cages,
- stepwise-assembly,
- alkaline-earth,
- structures,
- nonlinear optics
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沈阳化工大学材料科学与工程学院沈阳 110142

Coordination Assembly of Tetrahedral Ti4(embonate)6 Cages with Alkaline-Earth Metal Ions

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Coordination Assembly of Tetrahedral Ti₄(embonate)₆ Cages with Alkaline-Earth Metal Ions