Citation: LUO Ya, FU Lu-Lu, XIANG Jing. Three New Zn(Ⅱ) Coordination Compounds Based on the in-situ Formed Tetrazolate Ligand: Syntheses, Crystal Structures and Luminescence Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(1): 95-102. doi: 10.14102/j.cnki.0254-5861.2011-404 shu

Three New Zn(Ⅱ) Coordination Compounds Based on the in-situ Formed Tetrazolate Ligand: Syntheses, Crystal Structures and Luminescence Properties

1.
College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou, Hubei 434023, China

Received Date: 5 June 2014
Available Online: 1 December 2014
Fund Project: The project was supported by the National Natural Science Foundation of China (21201023) (21201023)the scientific research fund of Hubei Provincial Education Department (D20131202) (D20131202)

Reactions of 2-(2-benzoimidazolyl) acetonitrile and NaN₃ with ZnSO₄ or ZnCl₂ in the presence of nicotinic acid in the mixture of EtOH/H₂O afforded a mononuclear compound [Zn(L¹)₂] (1) and a 1-D polymer [Zn(L¹)Cl]_n (2), respectively (L¹=5-[(benzoimidazolyl) methyl]-1H-tetrazolate). However, in the similar condition except that imidazole was added instead of nicotinic acid, the reaction afforded a 1-D compound [Zn(L¹)₂]_n (3) featuring triply helical chains via the π-π stacking of ligands. They are characterized by elemental analysis and IR, and their structures have been determined by X-ray crystallography. Thermal stability of these compounds was measured by TGA and their luminescent properties were investigated at room temperature.
- tetrazole,
- Zn(Ⅱ),
- helical structure,
- photoluminescence
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