Citation: Li-Jun ZHAI, Ru TONG, Ci-Bin WANG, Meng-Jie SHI, Ya-Nan MO, Wen-Kai CHE, Yu-Lan NIU, Tuo-Ping HU. Structural Diversity and Magnetic Properties of Two Coordination Polymers Based on 6-(3, 5-Dicarboxylphenyl)nicotinic Acid[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1687-1695. doi: 10.14102/j.cnki.0254-5861.2011-3354 shu

Structural Diversity and Magnetic Properties of Two Coordination Polymers Based on 6-(3, 5-Dicarboxylphenyl)nicotinic Acid

Li-Jun ZHAI ^{a, c} ,
Ru TONG ^a ,
Ci-Bin WANG ^a ,
Meng-Jie SHI ^a ,
Ya-Nan MO ^a ,
Wen-Kai CHE ^a ,
Yu-Lan NIU ^a,, ,
Tuo-Ping HU ^b,,

a.
Taiyuan Institute of Technology, Department of Chemistry and Chemical Engineering, Taiyuan 030008, China
b.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China
c.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Yu-Lan NIU, niuyl@tit.edu.cn Tuo-Ping HU, hutuoping@nuc.edu.cn
Received Date: 6 September 2021
Accepted Date: 8 November 2021

Fund Project: the NSF of China 21676258the Scientific and Technologial Innovation Project of Shanxi Province 2020L0647Innovation and Entrepreneurship Project of Taiyuan Institute of Technology S202114101015

Figures(5)

Two new coordination polymers (Co-CPs), namely {[Co₈(DCPN)₄(1, 2-bimb)₄(μ₃-OH)₄]· (CH₃CN)_0.5(H₂O)₂}_n (1) and {[Co₂(DCPN)(1, 3-bimb)(μ₃-OH)]·H₂O}_n (2), where H₃DCPN = 6-(3, 5-dicarboxyl-phenyl)nicotinic acid, 1, 2-bimb = 1, 2-bis(imidazole-1-methyl)benzene and 1, 3-bimb = 1, 3-bis(imidazole-1-methyl)benzene, have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction analysis, elemental analysis (EA), infrared (IR) analysis, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). The structural analysis indicated that 1 is a 2D structure based on two different [Co₄(DCPN)₂(μ₃-OH)₂]_n SBUs, and 2 is a 3D framework based on [Co₄(DCPN)₂(μ₃-OH)₂] SBUs. In addition, the magnetic measurements showed that 1 and 2 have antiferromagnetic interactions between adjacent Co(II) ions. The slight difference of magnetic properties between 1 and 2 may be attributed to their different structures formed during the assembly process.
- coordination polymers,
- solvothermal synthesis,
- magnetic properties
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