Citation: Shi-Hao SUN, Qian-Chong ZHANG, Xiao-Liang YE, Chivanje evulu KASHI, Wen-Hua LI, Guan-E WANG, Gang XU. High-humidity Sensor of a New Trinuclear Ti₃-Oxo Cluster[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220307. doi: 10.14102/j.cnki.0254-5861.2011-3351 shu

High-humidity Sensor of a New Trinuclear Ti₃-Oxo Cluster

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Guan-E WANG, gewang@fjirsm.ac.cn
Received Date: 2 September 2021
Accepted Date: 8 August 2021

Fund Project: the National Natural Science Foundation of China 21975254the National Natural Science Foundation of China 21905280the National Natural Science Foundation of China 21950410532the National Natural Science Foundation of China 2019M662254Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Open Research Fund ES202080085the Youth Innovation Promotion Association CAS 2018342

Figures(5)

Crystalline polyoxo-titanium clusters (PTCs), as a molecular model of TiO₂ nanomaterials, have attracted unprecedented attention due to their designable structure, tunable band gap, catalysis, and photochromic properties. A new trinuclear Ti₃-oxo cluster, [Ti₃(μ₂-O)(μ₃-O)(abz)₆(OⁱPr)₂]·CH₃CN·H₂O (Ti3), was synthesized by solvothermal method with a yield of 60% by using 4-aminobenzoic acid as ligand. Single-crystal X-ray diffraction shows that it has a [Ti₃(μ₂-O)(μ₃-O)(abz)₆(OⁱPr)₂] trinuclear cluster structure. Ti3 crystallizes in monoclinic space group P2₁/c with a = 11.091(1), b = 22.837(2), c = 22.754(1) Å, β = 90.580(6)°, V = 5763.0(6) Å³, Z = 4, D_c = 1.345 g·cm^-3, F(000) = 2412, μ = 2.743 mm⁻¹, R = 0.0796, and wR = 0.2260 (I > 2σ(I)). Ti3 shows typical semiconductive behavior determined by temperature-dependent conductivity test. The chemiresistive humidity sensor fabricated by Ti3 showed good performance, including high response (four orders of magnitude current change from 0 to 100% RH) and fast response time (160 s) and recovery time (26 s).
- polyoxo-titanium clusters,
- semiconductor,
- chemiresistive sensor,
- humidity sensor
1. [1]
  Fang, W. H.; Zhang, L.; Zhang, J. Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters. Chem. Soc. Rev. 2018, 47, 404–421. doi: 10.1039/C7CS00511C
2. [2]
  Fan, X.; Wang, J. H.; Wu, K. F.; Zhang, L.; Zhang, J. Isomerism in titanium-oxo clusters: molecular anatase model with atomic structure and improved photocatalytic activity. Angew. Chem. Int. Ed. 2019, 58, 1320–1323. doi: 10.1002/anie.201809961
3. [3]
  Fan, X.; Fu, H.; Zhang, L.; Zhang, J. Pyrazole-thermal synthesis: a new approach towards N-rich titanium-oxo clusters with photochromic behaviors. Dalton Trans. 2019, 48, 8049–8052. doi: 10.1039/C9DT01628G
4. [4]
  Fang, W. H.; Zhang, L.; Zhang, J. A 3.6 nm Ti52-oxo nanocluster with precise atomic structure. J. Am. Chem. Soc. 2016, 138, 7480–7483. doi: 10.1021/jacs.6b03489
5. [5]
  Gao, M. Y.; Wang, F.; Gu, Z. G.; Zhang, D. X.; Zhang, L.; Zhang, J. Fullerene-like polyoxotitanium cage with high solution stability. J. Am. Chem. Soc. 2016, 138, 2556–2559. doi: 10.1021/jacs.6b00613
6. [6]
  Liu, J. X.; Gao, M. Y.; Fang, W. H.; Zhang, L.; Zhang, J. Bandgap engineering of titanium-oxo clusters: labile surface sites used for ligand substitution and metal incorporation. Angew. Chem. Int. Ed. 2016, 128, 5246–5251. doi: 10.1002/ange.201510455
7. [7]
  Chen, S.; Fang, W. H.; Zhang, L.; Zhang, J. Synthesis, structures, and photocurrent responses of polyoxo-titanium clusters with oxime ligands: from Ti₄ to Ti₁₈. Inorg. Chem. 2018, 57, 8850–8856. doi: 10.1021/acs.inorgchem.8b00751
8. [8]
  Gao, M. Y.; Fan, X.; Zhang, L.; Zhang, J. Dicarboxylate ligands oriented assembly of {Ti₃(μ₃-O)} units: from dimer to coordination triangles and rectangles. Inorg. Chem. 2018, 57, 5642–5647. doi: 10.1021/acs.inorgchem.8b00586
9. [9]
  Hong, Z. F.; Xu, S. H.; Yan, Z. H.; Lu, D. F.; Kong, X. J.; Long, L. S.; Zheng, L. S. A large titanium oxo cluster featuring a well-defined structural unit of rutile. Cryst. Growth Des. 2018, 18, 4864–4868. doi: 10.1021/acs.cgd.8b00904
10. [10]
  Yang, Y. M.; Lun, H. J.; Long, L. S.; Kong, X. J.; Zheng, L. S. Controlled synthesis of lanthanide-titanium oxo clusters EuTi₆, EuTi₇ and La₂Ti₁₄. Acta Phys. Chim. Sin. 2020, 36, 1912007–6.
11. [11]
  Li, G. J.; Long, L. S.; Kong, X. J.; Zheng, L. S. Chem. J. Chin. Univ. Chin. 2020, 41, 2577–2586.
12. [12]
  Farahani, H.; Wagiran, R.; Hamidon, M. N. Humidity sensors principle, mechanism, and fabrication technologies: a comprehensive review. Sensors 2014, 14, 7781–7939.
13. [13]
  Mogera, U.; Sagade, A. A.; George, S. J.; Kulkarni, G. U. Ultrafast response humidity sensor using supramolecular nanofibre and its application in monitoring breath humidity and flow. Sci. Rep. 2014, 4, 4103–9. doi: 10.1038/srep04103
14. [14]
  Sikarwar, S.; Yadav, B. C. Opto-electronic humidity sensor: a review. Sens. Actuator. A. Phys. 2015, 233, 54–70. doi: 10.1016/j.sna.2015.05.007
15. [15]
  Zhao, J.; Li, N.; Yu, H.; Wei, Z.; Liao, M. Z.; Chen, P.; Wang, S. P.; Shi, D. X.; Sun, Q. J.; Zhang, G. Y. Highly sensitive MoS₂ humidity sensors array for noncontact sensation. Adv. Mater. 2017, 29, 1702076–7. doi: 10.1002/adma.201702076
16. [16]
  Duan, Z. H.; Jiang, Y. D.; Zhao, Q. N.; Wang, S.; Yuan, Z.; Zhang, Y. J.; Liu, B. H.; Tai, H. L. Facile and low-cost fabrication of a humidity sensor using naturally available sepiolite nanofibers. Nanotechnology 2020, 31, 355501–8. doi: 10.1088/1361-6528/ab932c
17. [17]
  Atalay, S.; Erdemoglu, S.; Kolat, V. S.; Izgi, T.; Akgeyik, E.; Yilmaz, H. C.; Kaya, H.; Atalay, F. E. J. Electro. Mater. 2020, 5, 3209–3215.
18. [18]
  Zhang, Y. Y.; Fu, W. Y.; Yang, H. B.; Qi, Q.; Zeng, Y.; Zhang, T.; Ge, R. X.; Zou, G. G. Synthesis and characterization of TiO₂ nanotubes for humidity sensing. Appl. Surf. Sci. 2008, 254, 5545–5547. doi: 10.1016/j.apsusc.2008.02.106
19. [19]
  Farzaneh, A.; Esrafili, M. D.; Mermer, O. Development of TiO₂ nanofibers based semiconducting humidity sensor: adsorption kinetics and DFT computations. Mater. Chem. Phys. 2020, 239, 121981–9. doi: 10.1016/j.matchemphys.2019.121981
20. [20]
  Jyothilal, H.; Shukla, G.; Walia, S.; Kundu, S.; Angappane, S. Humidity sensing and breath analyzing applications of TiO₂ slanted nanorod arrays. Sens. Actuator A Phys. 2020, 301, 111758–10. doi: 10.1016/j.sna.2019.111758
21. [21]
  Hong, K.; Chun, H. Nonporous titanium-oxo molecular clusters that reversibly and selectively adsorb carbon dioxide. Inorg. Chem. 2013, 52, 17, 9705–9707.
22. [22]
  Cai, M. L.; Wang, G. E.; Yao, M. S.; Wu, G. D.; Li, Y.; Xu, G. Semiconductive 1D nanobelt iodoplumbate hybrid with high humidity response. Inorg. Chem. Commun. 2018, 93, 42–46. doi: 10.1016/j.inoche.2018.05.002
23. [23]
  Lv, X. J.; Yao, M. S.; Wang, G. E.; Li, Y. Z.; Xu, G. A new 3D cupric coordination polymer as chemiresistor humidity sensor: narrow hysteresis, high sensitivity, fast response and recovery. Sci. China Chem. 2017, 60, 1197–1204.
24. [24]
  Huang, J. H.; He, Y. H.; Yao, M. S.; He, J.; Xu, G.; Zeller, M.; Xu, Z. T. A semiconducting gyroidal metal-sulfur framework for chemiresistive sensing. J. Mater. Chem. A 2017, 5, 16139–16143. doi: 10.1039/C7TA02069D
25. [25]
  Tian, M.; Fu, Z. H.; Nath, B.; Yao, M. S. Synthesis of large and uniform Cu₃TCPP truncated quadrilateral nano-flake and its humidity sensing properties. Rsc. Adv. 2016, 6, 88991–88995. doi: 10.1039/C6RA19403F
26. [26]
  Xie, W. Y.; Liu, B.; Xiao, S. H.; Li, H.; Wang, Y. R.; Cai, D. P.; Wang, D. D.; Wang, L. L.; Liu, Y.; Li, Q. H.; Wang, T. H. High performance humidity sensors based on CeO₂ nanoparticles. Sens. Actuators B Chem. 2015, 215, 125–132. doi: 10.1016/j.snb.2015.03.051
27. [27]
  Wang, L. J.; He, Y.; Hu, J. H.; Qi, Q.; Zhang, T. DC humidity sensing properties of BaTiO₃ nanofiber sensors with different electrode materials. Sens. Actuators B. Chem. 2011, 153, 460–464. doi: 10.1016/j.snb.2010.11.016
28. [28]
  Jiang, K.; Fei, T.; Jiang, F.; Wang, G.; Zhang, T. A dew sensor based on modified carbon black and polyvinyl alcoholcomposites. Sens. Actuators B. Chem. 2014, 192, 658–663. doi: 10.1016/j.snb.2013.11.004
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

High-humidity Sensor of a New Trinuclear Ti3-Oxo Cluster

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通讯作者: 陈斌, bchen63@163.com

High-humidity Sensor of a New Trinuclear Ti₃-Oxo Cluster