Citation: Shi-Hao SUN, Qian-Chong ZHANG, Xiao-Liang YE, Chivanje evulu KASHI, Wen-Hua LI, Guan-E WANG, Gang XU. High-humidity Sensor of a New Trinuclear Ti₃-Oxo Cluster[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220307. doi: 10.14102/j.cnki.0254-5861.2011-3351 shu

High-humidity Sensor of a New Trinuclear Ti₃-Oxo Cluster

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Guan-E WANG, gewang@fjirsm.ac.cn
Received Date: 2 September 2021
Accepted Date: 8 August 2021

Fund Project: the National Natural Science Foundation of China 21975254the National Natural Science Foundation of China 21905280the National Natural Science Foundation of China 21950410532the National Natural Science Foundation of China 2019M662254Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Open Research Fund ES202080085the Youth Innovation Promotion Association CAS 2018342

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Crystalline polyoxo-titanium clusters (PTCs), as a molecular model of TiO₂ nanomaterials, have attracted unprecedented attention due to their designable structure, tunable band gap, catalysis, and photochromic properties. A new trinuclear Ti₃-oxo cluster, [Ti₃(μ₂-O)(μ₃-O)(abz)₆(OⁱPr)₂]·CH₃CN·H₂O (Ti3), was synthesized by solvothermal method with a yield of 60% by using 4-aminobenzoic acid as ligand. Single-crystal X-ray diffraction shows that it has a [Ti₃(μ₂-O)(μ₃-O)(abz)₆(OⁱPr)₂] trinuclear cluster structure. Ti3 crystallizes in monoclinic space group P2₁/c with a = 11.091(1), b = 22.837(2), c = 22.754(1) Å, β = 90.580(6)°, V = 5763.0(6) Å³, Z = 4, D_c = 1.345 g·cm^-3, F(000) = 2412, μ = 2.743 mm⁻¹, R = 0.0796, and wR = 0.2260 (I > 2σ(I)). Ti3 shows typical semiconductive behavior determined by temperature-dependent conductivity test. The chemiresistive humidity sensor fabricated by Ti3 showed good performance, including high response (four orders of magnitude current change from 0 to 100% RH) and fast response time (160 s) and recovery time (26 s).
- polyoxo-titanium clusters,
- semiconductor,
- chemiresistive sensor,
- humidity sensor
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

High-humidity Sensor of a New Trinuclear Ti3-Oxo Cluster

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通讯作者: 陈斌, bchen63@163.com

High-humidity Sensor of a New Trinuclear Ti₃-Oxo Cluster