Citation: Rui-Xue ZHUGE, Peng-Chao SHI, Teng ZHANG. MOF-Conductive Polymer Composite Film as Electrocatalyst for Oxygen Reduction in Acidic Media[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220306. doi: 10.14102/j.cnki.0254-5861.2011-3350 shu

MOF-Conductive Polymer Composite Film as Electrocatalyst for Oxygen Reduction in Acidic Media

Rui-Xue ZHUGE ^{a, b} ,
Peng-Chao SHI ^{b, c} ,
Teng ZHANG ^{b, c,,}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of the Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Teng ZHANG, zhangteng@fjirsm.ac.cn
Received Date: 1 September 2021
Accepted Date: 18 November 2021

Fund Project:

Figures(4)

A metal-organic framework (MOF)-conductive polymer composite film was constructed from PCN-222(Fe) nanoparticles and PEDOT: PSS solution by simple drop-casting approach. The composite film was tested as an electrocatalytic device for oxygen reduction reaction (ORR). The combination of PCN-222(Fe) MOF particles and conductive PEDOT matrix facilitates electron transfer in the composite material and improves the ORR performance of PCN-222(Fe). Levich plot and H₂O₂ quantification experiment show that PCN-222(Fe)/PEDOT: PSS film mainly catalyzes two-electron oxygen reduction and produces H₂O₂.
- metal-organic frameworks (MOFs),
- conductive polymer,
- porphyrin,
- oxygen reduction reaction (ORR),
- electrocatalysis
1. [1]
  Furukawa, H.; Cordova, K. E.; O'Keeffe, M.; Yaghi, O. M. The chemistry and applications of metal-organic frameworks. Science 2013, 341, 1230444−12. doi: 10.1126/science.1230444
2. [2]
  Wang, Z.; Cohen, S. M. Postsynthetic modification of metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1315−1329. doi: 10.1039/b802258p
3. [3]
  Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Hupp, J. T. Metal-organic framework materials as chemical sensors. Chem. Rev. 2012, 112, 1105−1125. doi: 10.1021/cr200324t
4. [4]
  Stock, N.; Biswas, S. Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chem. Rev. 2012, 112, 933−969. doi: 10.1021/cr200304e
5. [5]
  Jiao, L.; Wang, Y.; Jiang, H. L.; Qiang, X. Metal-organic frameworks as platforms for catalytic applications. Adv. Mater. 2018, 30, 1703663−23. doi: 10.1002/adma.201703663
6. [6]
  Yuan, S.; Feng, L.; Wang, K.; Pang, J.; Bosch, M.; Lollar, C.; Sun, Y.; Qin, J.; Yang, X.; Zhang, P. Stable metal-organic frameworks: design, synthesis, and applications. Adv. Mater. 2018, 30, 1704303−35. doi: 10.1002/adma.201704303
7. [7]
  Wu, Z.; Guo, S.; Kong, L. H. Doping [Ru(bpy)₃]²⁺ into metal-organic framework to facilitate the separation and reuse of noble-metal photosensitizer during CO₂ photoreduction. Chin. J. Catal. 2021, 42, 1790−1797. doi: 10.1016/S1872-2067(21)63820-2
8. [8]
  Li, J. R.; Kuppler, R. J.; Zhou, H. C. Selective gas adsorption and separation in metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1477−1504. doi: 10.1039/b802426j
9. [9]
  Woellner, M.; Hausdorf, S.; Klein, N.; Mueller, P.; Martin, W. S.; Kaskel, S. Adsorption and detection of hazardous trace gases by metal-organic frameworks. Adv. Mater. 2018, 30, 1704679. doi: 10.1002/adma.201704679
10. [10]
  Lin, R. B.; Xiang, S. C.; Zhou, W.; Chen, B. Microporous metal-organic framework materials for gas separation. Chem. 2020, 6, 337−363. doi: 10.1016/j.chempr.2019.10.012
11. [11]
  Shah, M.; McCarthy, M. C.; Sachdeva, S.; Lee, A. K.; Jeong, H. K. Current status of metal-organic framework membranes for gas separations: promises and challenges. Ind. Eng. Chem. Res. 2012, 51, 2179−2199. doi: 10.1021/ie202038m
12. [12]
  Kang, Z. X.; Fan, L. L.; Sun, D. F. Recent advances and challenges of metal-organic framework membranes for gas separation. J. Mater. Chem. A 2017, 5, 10073−10091. doi: 10.1039/C7TA01142C
13. [13]
  Hu, Z.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815−5840. doi: 10.1039/C4CS00010B
14. [14]
  Yao, M. S.; Li, W. H.; Xu, G. Metal-organic frameworks and their derivatives for electrically-transduced gas sensors. Coord. Chem. Rev. 2021, 426, 213479−34. doi: 10.1016/j.ccr.2020.213479
15. [15]
  Chen, L.; Xu, Q. Metal-organic framework composites for catalysis. Matter 2019, 1, 57−89. doi: 10.1016/j.matt.2019.05.018
16. [16]
  Bavykina, A.; Kolobov, N.; Khan, I. S.; Bau, J. A.; Gascon, J. Metal-organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives. Chem. Rev. 2020, 120, 8468−8535. doi: 10.1021/acs.chemrev.9b00685
17. [17]
  Huang, Y. B.; Liang, J.; Wang, X. S.; Cao, R. Multifunctional metal-organic framework catalysts: synergistic catalysis and tandem reactions. Chem. Soc. Rev. 2017, 46, 126−157. doi: 10.1039/C6CS00250A
18. [18]
  Zhuo, T. C.; Song, Y.; Zhuang, G. L.; Chang, L. P.; Zhang, Z. M. H-bond-mediated selectivity control of formate versus CO during CO₂ photoreduction with two cooperative Cu/X sites. J. Am. Chem. Soc. 2021, 143, 6114−6122. doi: 10.1021/jacs.0c13048
19. [19]
  Wang, L.; Zheng, M.; Xie, Z. Nanoscale metal-organic frameworks for drug delivery: a conventional platform with new promise. J. Mater. Chem. B 2018, 6, 707−717. doi: 10.1039/C7TB02970E
20. [20]
  Wang, Y.; Yan, J.; Wen, N. Metal-organic frameworks for stimuli-responsive drug delivery. Biomaterials 2020, 230, 119619−26. doi: 10.1016/j.biomaterials.2019.119619
21. [21]
  Della Rocca, J.; Liu, D.; Lin, W. Nanoscale metal-organic frameworks for biomedical imaging and drug delivery. Acc. Chem. Res. 2011, 44, 957−968. doi: 10.1021/ar200028a
22. [22]
  He, C.; Liu, D.; Lin, W. Nanomedicine applications of hybrid nanomaterials built from metal-ligand coordination bonds: nanoscale metal-organic frameworks and nanoscale coordination polymers. Chem. Rev. 2015, 115, 11079−11108. doi: 10.1021/acs.chemrev.5b00125
23. [23]
  Yoon, M.; Suh, K.; Natarajan, S. Proton conduction in metal-organic frameworks and related modularly built porous solids. Angew. Chem. Int. Ed. 2013, 52, 2688−2700. doi: 10.1002/anie.201206410
24. [24]
  Li, A. L.; Gao, Q.; Xu, J. Proton-conductive metal-organic frameworks: recent advances and perspectives. Coord. Chem. Rev. 2017, 344, 54−82. doi: 10.1016/j.ccr.2017.03.027
25. [25]
  Li, J. H.; Wang, Y. S.; Chen, Y. C.; Kun, C. W. Metal-organic frameworks toward electrocatalytic applications. Appl. Sci. 2019, 9, 2427−19. doi: 10.3390/app9122427
26. [26]
  Lu, X. F.; Xia, B. Y.; Zang, S. Q. Metal-organic frameworks based electrocatalysts for the oxygen reduction reaction. Angew. Chem. Int. Ed. 2020, 59, 4634−4650. doi: 10.1002/anie.201910309
27. [27]
  Liao, P. Q.; Shen, J. Q.; Zhang, J. P. Metal-organic frameworks for electrocatalysis. Coord. Chem. Rev. 2018, 373, 22−48. doi: 10.1016/j.ccr.2017.09.001
28. [28]
  Ko, M.; Mendecki, L.; Eagleton, A. M.; Durbin, C. G.; Mirica, K. A. Employing conductive metal-organic frameworks for voltammetric detection of neurochemicals. J. Am. Chem. Soc. 2020, 142, 11717−11733. doi: 10.1021/jacs.9b13402
29. [29]
  Liu, L. T.; Zhou, Y. L.; Liu, S.; Mao, T. The applications of metal organic frameworks in electrochemical sensors. ChemElectroChem. 2018, 5, 6−19. doi: 10.1002/celc.201700931
30. [30]
  Morozan, A.; Jaouen, F. Metal organic frameworks for electrochemical applications. Energy Environ. Sci. 2012, 5, 9269−9290. doi: 10.1039/c2ee22989g
31. [31]
  Wang, H. F.; Chen, L.; Pang, H.; Kaskel, S.; Xu, Q. MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions. Chem. Soc. Rev. 2020, 49, 1414−1448. doi: 10.1039/C9CS00906J
32. [32]
  Xia, W.; Mahmood, A.; Zou, R. Q. Metal-organic frameworks and their derived nanostructures for electrochemical energy storage and conversion. Energy Environ. Sci. 2015, 8, 1837−1866. doi: 10.1039/C5EE00762C
33. [33]
  Zhao, S.; Wang, Y.; Dong, J.; He, C. T.; Tang, Z. Y. Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution. Nat. Energy 2016, 1, 1−10.
34. [34]
  Jia, G.; Gao, Y. F.; Zhang, W.; Cao, Z.; Li, C.; Liu, J. Metal-organic frameworks as heterogeneous catalysts for electrocatalytic oxidative carbonylation of methanol to dimethyl carbonate. Electrochem. Commun. 2013, 34, 211−214. doi: 10.1016/j.elecom.2013.06.013
35. [35]
  Lions, M.; Tommasino, J. B.; Chattot, R.; Abeykoon, B.; Fateeva, A. Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework. Chem. Commun. 2017, 53, 6496−6499. doi: 10.1039/C7CC02113E
36. [36]
  Zhang, C. Y.; Wang, M. Y.; Liu, L.; Xu, X. Electrochemical investigation of a new Cu-MOF and its electrocatalytic activity towards H₂O₂ oxidation in alkaline solution. Electrochem. Commun. 2013, 33, 131−134. doi: 10.1016/j.elecom.2013.04.026
37. [37]
  Sun, L.; Campbell, M. G.; Dinca, M. Electrically conductive porous metal-organic frameworks. Angew. Chem. Int. Ed. Engl. 2016, 55, 3566−3579. doi: 10.1002/anie.201506219
38. [38]
  Wang, T. C.; Hod, I.; Audu, C. O.; Vermeulen, N. A.; Nguyen, S. T.; Farha, O. K.; Hupp, J. T. Rendering high surface area, mesoporous metal-organic frameworks electronically conductive. ACS Appl. Mater. Interfaces 2017, 9, 12584−12591. doi: 10.1021/acsami.6b16834
39. [39]
  Huang, T. Y.; Kung, C. W.; Liao, Y. T.; Wu, K. C. Enhanced charge collection in MOF-525-PEDOT nanotube composites enable highly sensitive biosensing. Adv. Sci. 2017, 4, 1700261−8. doi: 10.1002/advs.201700261
40. [40]
  Kung, C. W.; Li, Y. S.; Lee, M. H.; Wang, S. Y.; Chang, W. H. In situ growth of porphyrinic metal-organic framework nanocrystals on graphene nanoribbons for the electrocatalytic oxidation of nitrite. J. Mater. Chem. A 2016, 4, 10673−10682. doi: 10.1039/C6TA02563C
41. [41]
  Wang, Y.; Wang, L.; Chen, H.; Ma, S. Fabrication of highly sensitive and stable hydroxylamine electrochemical sensor based on gold nanoparticles and metal-metalloporphyrin framework modified electrode. ACS Appl. Mater. Interfaces 2016, 8, 18173−18181. doi: 10.1021/acsami.6b04819
42. [42]
  Chen, J.; Xu, Q.; Shu, Y.; Hu, X. Y. Synthesis of a novel Au nanoparticles decorated Ni-MOF/Ni/NiO nanocomposite and electrocatalytic performance for the detection of glucose in human serum. Talanta 2018, 184, 136−142. doi: 10.1016/j.talanta.2018.02.057
43. [43]
  Ma, S.; Goenaga, G. A.; Call, A. V.; Liu, D. J. Cobalt imidazolate framework as precursor for oxygen reduction reaction electrocatalysts. Chem. Eur. J. 2011, 17, 2063−2067. doi: 10.1002/chem.201003080
44. [44]
  Jahan, M.; Bao, Q.; Loh, K. P. Electrocatalytically active graphene-porphyrin MOF composite for oxygen reduction reaction. J. Am. Chem. Soc. 2012, 134, 6707−6713. doi: 10.1021/ja211433h
45. [45]
  Zhang, Y.; Bo, X.; Luhana, C.; Wang, H.; Li, M.; Guo, L. Facile synthesis of a Cu-based MOF confined in macroporous carbon hybrid material with enhanced electrocatalytic ability. Chem. Commun. 2013, 49, 6885−6887. doi: 10.1039/c3cc43292k
46. [46]
  Hu, X. Y.; Wang, Y.; Ge, H.; Ye, G.; Chen, H. H. Carbon functionalized metal organic framework/nafion composites as novel electrode materials for ultrasensitive determination of dopamine. J. Mater. Chem. B 2015, 3, 3747−3753. doi: 10.1039/C4TB01869A
47. [47]
  Xu, G. D.; Zuo, Y. X.; Huang, B. Metal-organic framework-74-Ni/carbon nanotube composite as sulfur host for high performance lithium-sulfur batteries. J. Electroanal. Chem. 2018, 830, 43−49.
48. [48]
  Xiong, W.; Li, H.; You, H.; Cao, M. N.; Cao, R. Encapsulating metal organic framework into hollow mesoporous carbon sphere as efficient oxygen bifunctional electrocatalyst. Natl. Sci. Rev. 2020, 7, 609−619. doi: 10.1093/nsr/nwz166
49. [49]
  Xu, Z.; Yang, L.; Xu, C. Pt@UiO-66 heterostructures for highly selective detection of hydrogen peroxide with an extended linear range. Anal. Chem. 2015, 87, 3438−3444. doi: 10.1021/ac5047278
50. [50]
  Chen, Y.; Sun, X.; Biswas, S.; Xie, Y.; Wang, Y.; Hu, X. Integrating polythiophene derivates to PCN-222(Fe) for electrocatalytic sensing of L-dopa. Biosens. Bioelectron. 2019, 141, 111470−8. doi: 10.1016/j.bios.2019.111470
51. [51]
  Wang, Y.; Wang, L.; Huang, W. A metal-organic framework and conducting polymer based electrochemical sensor for high performance cadmium ion detection. J. Mater. Chem. A 2017, 5, 8385−8393. doi: 10.1039/C7TA01066D
52. [52]
  Liang, X. Q.; Zhang, F.; Feng, W.; Zou, X. Q.; Zhao, C. J.; Na, H.; Liu, C.; Sun, F. X.; Zhu, G. S. From metal-organic framework (MOF) to MOF-polymer composite membrane: enhancement of low-humidity proton conductivity. Chem. Sci. 2013, 4, 983−992. doi: 10.1039/C2SC21927A
53. [53]
  Jiang, H.; Liu, X. C.; Wu, Y. Metal-organic frameworks for high charge-discharge rates in lithium-sulfur batteries. Angew. Chem. Int. Ed. 2018, 57, 3916−3921. doi: 10.1002/anie.201712872
54. [54]
  Xia, Y.; Sun, K.; Ouyang, J. Solution-processed metallic conducting polymer films as transparent electrode of optoelectronic devices. Adv. Mater. 2012, 24, 2436−2440. doi: 10.1002/adma.201104795
55. [55]
  Kim, N.; Kee, S.; Lee, S. H. Highly conductive PEDOT: PSS nanofibrils induced by solution-processed crystallization. Adv. Mater. 2014, 26, 2268−2272. doi: 10.1002/adma.201304611
56. [56]
  Feng, D. W.; Gu, Z. Y.; Li, J. R.; Jiang, H. L.; Wei, Z. W. Zirconium-metalloporphyrin PCN-222: mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts. Angew. Chem. Int. Ed. 2012, 51, 10307−10310. doi: 10.1002/anie.201204475
57. [57]
  He, T.; Xu, X.; Ni, B.; Wang, H.; Yong, L.; Hu, W.; Xun, W. Fast and scalable synthesis of uniform zirconium-, hafnium-based metal-organic framework nanocrystals. Nanoscale 2017, 9, 19209−19215. doi: 10.1039/C7NR06274E
58. [58]
  Sohrabi, S.; Dehghanpour, S.; Ghalkhani, M. Three-dimensional metal-organic framework graphene nanocomposite as a highly efficient and stable electrocatalyst for the oxygen reduction reaction in acidic media. ChemCatChem. 2016, 8, 2356−2366. doi: 10.1002/cctc.201600298
59. [59]
  Shi, L.; Yang, L. Q.; Zhang, H. B.; Chang, K.; Zhao, G.; Kako, T.; Ye, J. Implantation of iron(III) in porphyrinic metal organic frameworks for highly improved photocatalytic performance. Appl. Catal. B 2018, 224, 60−68. doi: 10.1016/j.apcatb.2017.10.033
60. [60]
  Usov, P. M.; Huffman, B.; Epley, C. C.; Matthew, C. Study of electrocatalytic properties of metal-organic framework PCN-223 for the oxygen reduction reaction. ACS Appl. Mater. Interfaces 2017, 9, 33539−33543. doi: 10.1021/acsami.7b01547
61. [61]
  Kadish, K. M.; Morrison, M. M.; Constant, L. A.; Dickens, L.; Davis, D. G. A study of solvent and substituent effects on the redox potentials and electron-transfer rate constants of substituted iron meso-tetraphenylporphyrins. J. Am. Chem. Soc. 1976, 98, 8387−8390. doi: 10.1021/ja00442a013
62. [62]
  Hod, I.; Sampson, M. D.; Deria, P. Fe-porphyrin-based metal-organic framework films as high-surface concentration, heterogeneous catalysts for electrochemical reduction of CO₂. ACS Catal. 2015, 5, 6302−6309. doi: 10.1021/acscatal.5b01767
1. [1]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
2. [2]
  Kang Wang , Qinglin Zhou , Weijin Li . Conductive metal-organic frameworks for electromagnetic wave absorption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100325-100325. doi: 10.1016/j.cjsc.2024.100325
3. [3]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
4. [4]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
5. [5]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
6. [6]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
7. [7]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
8. [8]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
9. [9]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
10. [10]
  Xingyan Liu , Chaogang Jia , Guangmei Jiang , Chenghua Zhang , Mingzuo Chen , Xiaofei Zhao , Xiaocheng Zhang , Min Fu , Siqi Li , Jie Wu , Yiming Jia , Youzhou He . Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal. Chinese Chemical Letters, 2024, 35(9): 109455-. doi: 10.1016/j.cclet.2023.109455
11. [11]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
12. [12]
  Jian Yang , Guang Yang , Zhijie Chen . Capturing carbon dioxide from air by using amine-functionalized metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(5): 100267-100267. doi: 10.1016/j.cjsc.2024.100267
13. [13]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
14. [14]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
15. [15]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
16. [16]
  Xue-Zhi Wang , Yi-Tong Liu , Chuang-Wei Zhou , Bei Wang , Dong Luo , Mo Xie , Meng-Ying Sun , Yong-Liang Huang , Jie Luo , Yan Wu , Shuixing Zhang , Xiao-Ping Zhou , Dan Li . Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars. Chinese Chemical Letters, 2024, 35(10): 109380-. doi: 10.1016/j.cclet.2023.109380
17. [17]
  Kunsong Hu , Yulong Zhang , Jiayi Zhu , Jinhua Mai , Gang Liu , Manoj Krishna Sugumar , Xinhua Liu , Feng Zhan , Rui Tan . Nano-engineered catalysts for high-performance oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(10): 109423-. doi: 10.1016/j.cclet.2023.109423
18. [18]
  Pingfan Zhang , Shihuan Hong , Ning Song , Zhonghui Han , Fei Ge , Gang Dai , Hongjun Dong , Chunmei Li . Alloy as advanced catalysts for electrocatalysis: From materials design to applications. Chinese Chemical Letters, 2024, 35(6): 109073-. doi: 10.1016/j.cclet.2023.109073
19. [19]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
20. [20]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094

Get Citation

PDF

XML

Metrics

PDF Downloads(26)
Abstract views(738)
HTML views(135)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142