Citation: Yi-Feng WANG, Mou-Hai SHU. Synthesis and Crystal Structure of a Copper(II) Complex with Funnel-like Ligand Based on Calix[6]arene[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220318. doi: 10.14102/j.cnki.0254-5861.2011-3312 shu

Synthesis and Crystal Structure of a Copper(II) Complex with Funnel-like Ligand Based on Calix[6]arene

Yi-Feng WANG ,
Mou-Hai SHU ^,

School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Mou-Hai SHU, mhshu@sjtu.edu.cn
Received Date: 20 July 2021
Accepted Date: 8 November 2021

Fund Project: the Natural Science Foundation of Shanghai 19ZR1424900

Figures(5)

The preparation method of a funnel like ligand derived from calix[6]arene and tris(2-pyridyl-methyl)anime has been improved. The Cu(II) complex was obtained and characterized by ESI-MS, EPR, UV-Vis spectra and crystallographic analysis. In the complex, a guest acetonitrile molecule is introduced into the cavity of the ligand host via the coordination with Cu(II) center.
- Cu(II) complex,
- crystal structure,
- calix[6]arene,
- host-guest interaction
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