Citation: Na YANG, Hua YANG, Hai-Quan TIAN, Da-Cheng LI, Jian-Min DOU. Two Polynuclear Fe Complexes with Boat-like Core: Syntheses, Structures and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220304. doi: 10.14102/j.cnki.0254-5861.2011-3311 shu

Two Polynuclear Fe Complexes with Boat-like Core: Syntheses, Structures and Magnetic Properties

Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China

Corresponding author: Hua YANG, Jian-Min DOU, dougroup@163.com
Received Date: 19 July 2021
Accepted Date: 15 September 2021

Fund Project: the National Natural Science Foundation of China 21671093the National Natural Science Foundation of China 21701078

Figures(8)

Two novel polynuclear complexes {NaFe₄(μ₄-O)(L)₄(μ₂-Cl)[Fe(CN)₅NO](H₂O)(DMF)₂} (1) and {NaFe₄(μ₄-O)(L)₄(μ₂-OEt)[Fe(CN)₅NO](H₂O)(DMF)₂} (2) have been prepared using the tetradentate N-(2-hydroxyethyl)-3-methoxysalicylaldimine Schiff-base ligand (H₂L) with the help of [Fe(CN)₅NO]^2- linkers, where the ligand was in situ synthesized through the condensation of o-vanillin and ethanolamine in the formation process of complexes. The resulting complexes possess "boat-like" structure constructed through three Fe ions and one Na ion with the fourth Fe ion acting as the "paddle". The "hull bottom" contains an eight-membered metallamacrocycle with metallacrown-like motif and [-M-O-] repeat unit. Both complexes display three-dimensional frameworks through C–H∙∙∙N hydrogen bonds, C–H∙∙∙Cl hydrogen bonds, and π-π stacking interactions with the introduction of solvent molecules and coordination anions. Variable-temperature magnetic susceptibility measurements reveal strong antiferromagnetic couplings between the metal centers in complexes 1 and 2.
- crystal structures,
- magnetic properties,
- Schiff-base,
- metallamacrocycle
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