Citation: E LIU, Ai-Quan JIA, Qian-Feng ZHANG, Fang-Fang JIAN. A Double Crown Hexakis[(Di-μ-benzylthio) Nickel] Cluster: Synthesis, Structure and Properties[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220304. doi: 10.14102/j.cnki.0254-5861.2011-3309 shu

A Double Crown Hexakis[(Di-μ-benzylthio) Nickel] Cluster: Synthesis, Structure and Properties

E LIU ^{a, b,,} ,
Ai-Quan JIA ^a ,
Qian-Feng ZHANG ^a,, ,
Fang-Fang JIAN ^b

a.
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma'anshan, Anhui 243002, China
b.
School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471000, China

Corresponding author: E LIU, 798233143@haust.edu.cn Qian-Feng ZHANG, zhangqf@ahut.edu.cn
Received Date: 15 July 2021
Accepted Date: 14 September 2021

Fund Project: the Research Initiation Fund for Distinguished Professors of Henan University of Science 13510007

Figures(8)

The double crown hexakis[(di-μ-benzylthio) nickel] cluster, [Ni₆(SCH₂C₆H₅)₁₂]·C₂H₅OH, was obtained by reacting C₆H₅CH₂SNa with [(CH₃)₂CHOCS₂]₂Ni in EtOH. The results of electrochemical studies show that [Ni₆(SCH₂C₆H₅)₁₂] is a quasi-reversible process. The crystal structure of [Ni₆(SCH₂C₆H₅)₁₂]·C₂H₅OH is composed of discrete [Ni₆(SCH₂C₆H₅)₁₂] and C₂H₅OH solvent molecules. Each Ni atom is surrounded by four S atoms of the μ₂-SCH₂C₆H₅ ligands in a distorted square-planar structure. The C₆H₅CH₂S^- side chains are arranged in the axial and equatorial positions, alternately, concerning the pseudo-hexagonal axis of the molecule. Strong π-π and C–H···π effects form the supramolecular nano-channel along the a-axis in the crystal, which wraps the solvent ethanol molecules in it. In addition, a wall is formed along the b- and c-axes, so that the ethanol molecules can freely enter and leave along the a-axis. These effects result in the ability of the title compound to adsorb and desorb ethanol molecules. Thermogravimetric analysis and powder X-ray diffraction at different temperature are provided to demonstrate this point.
- benzylthiol,
- nickel cluster,
- porous materials,
- cyclic voltammetry,
- thermogravimetry
1. [1]
  Diercks, C. S.; Yaghi, O. M. The atom, the molecule and the covalent organic framework. Science 2017, 355, 585.
2. [2]
  Savastano, M.; Bazzicalupi, C.; Bianchi, A. Porous frameworks based on supramolecular ball joints: bringing flexibility to ordered 3D lattices. Chem. Eur. J. 2020, 26, 5994–6005. doi: 10.1002/chem.202000505
3. [3]
  Liu, Y. K.; Zhou, X. H. Synthesis, structure and property of a metal-organic framework based on 9-(2, 6-dicarboxy-pyridin-4-yl)-9H-carbazole-3, 6-dicarboxylic acid. Chin. J. Struct. Chem. 2020, 39, 559–566.
4. [4]
  Wilson, B. H.; Scott, H. S.; Qazvini, O. T.; Telfer, S. G.; Mathoniere, C.; Clerac, R.; Kruger, P. E. A supramolecular porous material comprising Fe(Ⅱ) mesocates. Chem. Commum. 2018, 54, 13391–13394. doi: 10.1039/C8CC07227B
5. [5]
  Yang, K.; Luo J. H.; Yong, S. L.; Li, H. X.; Zhang, X. Y. Synthesis and structure of a new gadolinium porous complex assembled from 2, 3-pyrazinedicarboxylic acid and ammonia. Chin. J. Struct. Chem. 2019, 38, 1773–1778.
6. [6]
  Niel, V.; Munoz, M. C.; Gaspar, A. B. Thermal, pressure, and light-induced spin transition in novel cyanide-bridged Fe^Ⅱ-Ag^I bimetallic compounds with three-dimensional interpenetrating double structures {Fe^ⅡL_x[Ag(CN)₂]₂}⋅G. Chem. Eur. J. 2002, 8, 2446–2453. doi: 10.1002/1521-3765(20020603)8:11<2446::AID-CHEM2446>3.0.CO;2-K
7. [7]
  Tian, J.; Chen, L.; Zhang, D. W.; Liu, Y.; Li, Z. T. Supramolecular organic frameworks: engineering periodicity in water through host-guest chemistry. Chem. Commun. 2016, 52, 6351–6362. doi: 10.1039/C6CC02331B
8. [8]
  Huang, Y. H.; Xu, Y.; Zheng, B. S.; Wang, Z. X.; Dong, Q. B.; Duan, J. G. Molecular sieving of C₂H₄ from C₂H₂ by a supramolecular porous material. Energ. Fuel. 2020, 34, 11315–11321. doi: 10.1021/acs.energyfuels.0c01958
9. [9]
  Wasson, M. C.; Zhang, X.; Otake, K. I.; Rosen, A. S.; Alayoglu, S.; Krzyaniak, M. D.; Chen, Z. J.; Redfern, L. R.; Robison, L.; Son, F. A.; Chen, Y. W.; Islamoglu, T.; Notestein, J. M.; Snurr, R. Q.; Wasielewski, M. R.; Farha, O. K. Supramolecular porous assemblies of atomically precise catalytically active cerium-based clusters. Chem. Mater. 2020, 32, 8522–8529. doi: 10.1021/acs.chemmater.0c02740
10. [10]
  Lu, J.; Paliwala, T.; Lim, S. C. Coordination polymers of Co(NCS)₂ with pyrazine and 4, 4-bipyridine: syntheses and structures. Inorg. Chem. 1997, 36, 923–926. doi: 10.1021/ic961158g
11. [11]
  Kondo, M.; Shimamura, M.; Noro, S. I. Microporous materials constructed from the interpenetrated coordination networks. Structures and methane adsorption properties. Chem. Mater. 2000, 12, 1288–1294. doi: 10.1021/cm990612m
12. [12]
  Katkova, M. A.; Zhigulin, G. Y.; Rumyantcev, R. V.; Zabrodina, G. S.; Shayapov, V. R.; Sokolov, M. N.; Ketkov, S. Y. Water-soluble bismuth(Ⅲ) polynuclear tyrosinehydroximate metallamacrocyclic complex: structural parallels to lanthanide metallacrowns. Molecules 2020, 25, 4379. doi: 10.3390/molecules25194379
13. [13]
  DiStefano, J. G.; Murthy, A. A.; Hao, S. Q.; Roberto, D. R.; Wolverton, C.; Dravid, V. P. Topology of transition metal dichalcogenides: the case of the core-shell architecture. Nanoscale 2020, 12, 23897–23919. doi: 10.1039/D0NR06660E
14. [14]
  Wang, J.; Jian, F. F.; Huang, B. X.; Bai, Z. S. Two molecular wheels 12-MC-6 complexes: synthesis, structure and magnetic property of [Co(μ₂-SEt)₂]₆ and [Fe(μ₂-SEt)₂]₆. J. Solid State Chem. 2013, 204, 272–277. doi: 10.1016/j.jssc.2013.06.007
15. [15]
  Zou, G.; Hu, Z.; Hu, B. Study on synthesis of tert-butyl benzyl mercaptan by urea salt method. Jiangxi Chem. Eng. 2001, 1, 21–25.
16. [16]
  Sheldrick, G. M. Phase annealing in SHELX-90: direct methods for larger structures. Acta Cryst. A46 1990, 467–473.
17. [17]
  Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Cryst. 2009, 42, 339–341. doi: 10.1107/S0021889808042726
18. [18]
  Sheldrick, G. M. SHELXT-Integrated space-group and crystal-structure determination. Acta Cryst. A 2015, 71, 3–8. doi: 10.1107/S2053273314026370
19. [19]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Cryst. C 2015, 71, 3–8. doi: 10.1107/S2053229614024218
20. [20]
  Wilson, A. J. International Table for X-ray Crystallography, Vol. C (Kluwer. Dordrecht. 1994) Tables 6.1. 1.4, 500–502.
21. [21]
  Jian, F. F.; Jiao, K.; Li, Y.; Zhao, P. S.; Lu, L. D. [Ni₆(SCH₂CH₂OH)₁₂]: a double crown [12] metallacrown-6 nickel(Ⅱ) cluster. Angew. Chem. Int. Ed. 2003, 42, 5722–5731. doi: 10.1002/anie.200351896
22. [22]
  Zhang, C.; Takada, S.; Kolzer, M.; Matsumoto, T.; Tatsumi, K. Nickel(Ⅱ) thiolate complexes with a flexible cyclo-{Ni₁₀S₂₀} framework. Angew Chem. Int. Ed. 2006, 45, 3768–3772. doi: 10.1002/anie.200600319
23. [23]
  Woodward, P.; Dahl, L. F.; Abel, E. W.; Crosse, B. C. A new type of cyclic transition metal complex, [Ni(SC₂H₅)₂]₆. J. Am. Chem. Soc. 1965, 87, 5251–5258. doi: 10.1021/ja00950a049
24. [24]
  Sletten, J.; Kovacs, J. A. The structure of a toroidal, neutral, homoleptic Ni(Ⅱ) complex with a chelate dithiolate ligand, [Ni₆(SCH₂CH₂CH₂S)₆]. Acta Chem. Scand. 1994, 48, 929–932. doi: 10.3891/acta.chem.scand.48-0929
25. [25]
  Newton, G. N.; Sato, H.; Shiga, T.; Oshio, H. Stepwise replacement of nickel with cobalt ions in a [Ni₆] cluster. Dalton Trans. 2013, 6701–6704.
26. [26]
  Wang, X. Q.; Liu, S. X.; Liu, Y. W.; He, D. F.; Li, N.; Miao, J.; Ji, Y. J.; Yang, G. Y. Planar {Ni-6} cluster-containing polyoxometalate-based inorganic-organic hybrid compound and its extended structure. Inorg. Chem. 2014, 54, 13130–13135.
27. [27]
  Zhang, X. M.; Fang, R. Q.; Wu, H. S. Extended water tapes of cyclic hexamers encapsulated in the channels of a metal phosphonocarboxylate network. Cryst. Growth Des. 2005, 5, 1335–1339. doi: 10.1021/cg0500829
28. [28]
  Mirceski, V.; Stojanov, L.; Ogorevc, B. Step potential as a diagnostic tool in square-wave voltammetry of quasi-reversible electrochemical processes. Electrochim. Acta 2019, 327, 134997. doi: 10.1016/j.electacta.2019.134997
29. [29]
  Duval, J. F. L.; Buffle, J.; van Leeuwen, H. P. Quasi-reversible faradaic depolarization processes in the electrokinetics of the metal/solution interface. J. Phy. Chem. B 2006, 110, 6081–6094. doi: 10.1021/jp055650+
30. [30]
  Simonov, A. N.; Morris, G. P.; Mashkina, E. A.; Bethwaite, B.; Gillow, K.; Baker, R. E.; Gavaghan, D. J.; Bond, A. M. Inappropriate use of the quasi-reversible electrode kinetic model in simulation-experiment comparisons of voltammetric processes that approach the reversible limit. Anal. Chem. 2014, 86, 8408–8417. doi: 10.1021/ac5019952
1. [1]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
2. [2]
  Yi Liu , Peng Lei , Yang Feng , Shiwei Fu , Xiaoqing Liu , Siqi Zhang , Bin Tu , Chen Chen , Yifan Li , Lei Wang , Qing-Dao Zeng . Topologically engineering of π-conjugated macrocycles: Tunable emission and photochemical reaction toward multi-cyclic polymers. Chinese Chemical Letters, 2024, 35(10): 109571-. doi: 10.1016/j.cclet.2024.109571
3. [3]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
4. [4]
  Shulei Hu , Yu Zhang , Xiong Xie , Luhan Li , Kaixian Chen , Hong Liu , Jiang Wang . Rh(Ⅲ)-catalyzed late-stage C-H alkenylation and macrolactamization for the synthesis of cyclic peptides with unique Trp(C7)-alkene crosslinks. Chinese Chemical Letters, 2024, 35(8): 109408-. doi: 10.1016/j.cclet.2023.109408
5. [5]
  Ruilong Geng , Lingzi Peng , Chang Guo . Dynamic kinetic stereodivergent transformations of propargylic ammonium salts via dual nickel and copper catalysis. Chinese Chemical Letters, 2024, 35(8): 109433-. doi: 10.1016/j.cclet.2023.109433
6. [6]
  Haoran Shi , Jiaxin Wang , Yuqin Zhu , Hongyang Li , Guodong Ju , Lanlan Zhang , Chao Wang . Highly selective α-C(sp³)-H arylation of alkenyl amides via nickel chain-walking catalysis. Chinese Chemical Letters, 2024, 35(7): 109333-. doi: 10.1016/j.cclet.2023.109333
7. [7]
  Haibin Yang , Duowen Ma , Yang Li , Qinghe Zhao , Feng Pan , Shisheng Zheng , Zirui Lou . Mo doped Ru-based cluster to promote alkaline hydrogen evolution with ultra-low Ru loading. Chinese Journal of Structural Chemistry, 2023, 42(11): 100031-100031. doi: 10.1016/j.cjsc.2023.100031
8. [8]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
9. [9]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
10. [10]
  Chao-Long Chen , Rong Chen , La-Sheng Long , Lan-Sun Zheng , Xiang-Jian Kong . Anchoring heterometallic cluster on P-doped carbon nitride for efficient photocatalytic nitrogen fixation in water and air ambient. Chinese Chemical Letters, 2024, 35(4): 108795-. doi: 10.1016/j.cclet.2023.108795
11. [11]
  Shaohua Zhang , Liyao Liu , Yingqiao Ma , Chong-an Di . Advances in theoretical calculations of organic thermoelectric materials. Chinese Chemical Letters, 2024, 35(8): 109749-. doi: 10.1016/j.cclet.2024.109749
12. [12]
  Junjie Wang , Yan Wang , Zhengdong Li , Changqiang Xie , Musammir Khan , Xingzhou Peng , Fabiao Yu . Triphenylamine-AIEgens photoactive materials for cancer theranostics. Chinese Chemical Letters, 2024, 35(6): 108934-. doi: 10.1016/j.cclet.2023.108934
13. [13]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
14. [14]
  Uttam Pandurang Patil . Porous carbon catalysis in sustainable synthesis of functional heterocycles: An overview. Chinese Chemical Letters, 2024, 35(8): 109472-. doi: 10.1016/j.cclet.2023.109472
15. [15]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
16. [16]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
17. [17]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
18. [18]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
19. [19]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
20. [20]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(424)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142