Citation: Jing-Jing HUANG, Dan ZHAO, Guo-Jie YIN. Functionalized Metal-organic Frameworks for White Light Emission and Highly Sensitive Sensing of PA and Fe³⁺/Al³⁺[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220303. doi: 10.14102/j.cnki.0254-5861.2011-3304 shu

Functionalized Metal-organic Frameworks for White Light Emission and Highly Sensitive Sensing of PA and Fe³⁺/Al³⁺

Luoyang Institute of Science and Technology, Luoyang 471023, China

Corresponding author: Guo-Jie YIN, 13523612522@163.com
Received Date: 7 July 2021
Accepted Date: 24 January 2022

Fund Project: the High-level Talents Initiation Project of Luoyang Institute of Technology 2018BZ17the Pre-research Project of Luoyang Institute of Technology 2018YZ15the Key Scientific Research Project of Higher Education of Henan Province 20B150016the Training Program for Young Backbone Teachers of Higher Education of Henan Province 2020GGJS243the Science and Technology Project of Henan Province 182102210102the Science and Technology Project of Henan Province 202102210058

Figures(9)

Three isomorphic Ln-MOFs [Ln(bcbob)(H₂O)(DMF)] (Ln = Tb for 1, Eu for 2, Gd for 3; DMF = N, N-dimethylformamide) have been constructed from a semi-rigid V-shaped organic linker 3, 5-bis((4′-carboxyl-benzyl)oxy)benzoilate acid (H₃bcbob) under solvothermal conditions. X-ray single-crystal diffraction analysis reveals that they exhibit a two-dimensional (2D) layered structure. Compounds 1~3 show the characteristic green and red emissions of Ln³⁺ and blue emission arising from the organic ligand, respectively. Based on their photoluminescence properties, the white-light emitting materials 4 and 5 with longer fluorescence lifetime (ms grade) and higher quantum yield (e.g. 40.61% for 4) are fabricated. Remarkably, 1 exhibits good sensing ability on nitroaromatic compounds, especially for picric acid (PA). In addition, 1 is still a highly selective sensing material for Fe³⁺ and Al³⁺.
- lanthanide organic frameworks,
- aromatic carboxylic acid,
- fluorescence,
- doping,
- chemical sensingdiiron
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Functionalized Metal-organic Frameworks for White Light Emission and Highly Sensitive Sensing of PA and Fe3+/Al3+

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通讯作者: 陈斌, bchen63@163.com

Functionalized Metal-organic Frameworks for White Light Emission and Highly Sensitive Sensing of PA and Fe³⁺/Al³⁺