Citation: Han ZHANG, Xiang LI, Yaseen MUHAMMAD, Hui-Feng XIE, Yi-Han ZANG, Ming-Lu FANG, Shao-Jie LIU, Hao WANG. Synthesis, Crystal Structure and Fluorescent Properties of a 1D Europium Coordination Polymer with 2,5-Furandicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220309. doi: 10.14102/j.cnki.0254-5861.2011-3303 shu

Synthesis, Crystal Structure and Fluorescent Properties of a 1D Europium Coordination Polymer with 2,5-Furandicarboxylic Acid

a.
Beijing Key Lab of Special Elastomer Composite Materials, College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
b.
Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, KP, Pakistan

Corresponding author: Hao WANG, wangh@bipt.edu.cn
Received Date: 6 July 2021
Accepted Date: 23 August 2021

Fund Project: the High-level Teachers in Beijing Municipal Universities in the Period of 13th Five-year Plan CIT & TCD201904044URT program of Beijing Institute of Petrochemical Technology 2021J00003

Figures(9)

By using solvothermal method, a one-dimensional chain compound [KEu₂(FDCA)₃(H₂O)₉·0.5(FDCA)] (1) was synthesized. Single-crystal X-ray diffraction data reveal that 1 crystallizes in monoclinic system, space group P2₁/n with a = 12.1996(1), b = 18.6454(2), c = 17.7123(2) Å, β = 98.8460(10)°, D_c = 1.753 g/cm³, Z = 2, V = 3981.03(7) Å³, R = 0.0544 and wR = 0.1511 for 7886 observed reflections with I > 2σ(I). In 1, three FDCA^2– ligands construct a "23-crown-9-like" structure as the second building units (SBUs) to further form an infinite 1D chain. Meanwhile, the fluorescent result reveals that compound 1 can selectively and sensitively sense Fe³⁺ by the fluorescence quenching.
- 2,5-furandicarboxylic acid,
- solvothermal synthesis,
- Fe³⁺,
- fluorescence quenching
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