Citation: Qian ZHANG, Yan-Feng CUI, Xia-Mei ZHANG, Ya-Hong LI, Jin-Lei YAO. Manganese(Ⅱ) and Copper(Ⅰ) Compounds Based on Two Derivatives of Imidazo[1, 5-a]pyridine: Synthesis, Structures, Magnetic Properties, and Catalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220314. doi: 10.14102/j.cnki.0254-5861.2011-3296 shu

Manganese(Ⅱ) and Copper(Ⅰ) Compounds Based on Two Derivatives of Imidazo[1, 5-a]pyridine: Synthesis, Structures, Magnetic Properties, and Catalytic Activity

a.
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
b.
Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application, School of Physical Science and Technology, Suzhou University of Science and Technology, Suzhou 215009, China

Corresponding author: Ya-Hong LI, liyahong@suda.edu.cn Jin-Lei YAO, jlyao@usts.edu.cn
Received Date: 25 June 2021
Accepted Date: 12 October 2021

Fund Project: the National Natural Science Foundation of China 21772140the National Natural Science Foundation of China 21771136Natural Science Foundation of Jiangsu Province BK20171213the Project of Scientific and Technologic Infrastructure of Suzhou SZS201905

Figures(4)

The utilization of 2, 6-bis(imidazo[1, 5-a]pyridin-3-yl)pyridine (bipp) and 3-(pyridin-2-yl)imidazo[1, 5-a]pyridine (pip) in the compounds of manganese(Ⅱ) and copper(Ⅰ) ions is presented. Two complexes, [Mn(bipp)(SO₄)(H₂O)]_n (1) and [Cu(pip)₂]ClO₄ (2), were prepared with different characteristics in structure. Compound 1 exhibits a one-dimensional chain topology, and 2 is a homoleptic Cu(Ⅰ) complex. The dc magnetic susceptibility investigations reveal the antiferromagnetic (AF) Mn^Ⅱ…Mn^Ⅱ interactions in complex 1. The catalytic activity of compound 2 toward ketalization reactions was studied. Complex 2 exhibits high activity for the ketalization transformations of aliphatic ketones.
- coordination complexes,
- chain configuration,
- magnetism,
- catalysis
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