Citation: Yuan-Da LI, Jin-Hao KUANG, Hai-Bo QIN, Ke-Xiang LIU, Xu FAN, Zhong-Yan LI, Lin YUAN. A Novel Salicylaldehyde Schiff-base Fluorescent Probe for Selective Detection of Cu²⁺Ion[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220313. doi: 10.14102/j.cnki.0254-5861.2011-3288 shu

A Novel Salicylaldehyde Schiff-base Fluorescent Probe for Selective Detection of Cu²⁺Ion

Hunan University of Science and Engineering, Yongzhou 425199, China

Corresponding author: Lin YUAN, tcyl431102@163.com
Received Date: 19 June 2021
Accepted Date: 3 September 2021

Fund Project: the Natural Science Foundation of Hunan Province 2021JJ30291Undergraduate Training Program for Innovation and Entrepreneurship of Hunan Province [2021]197-3585Undergraduate Training Program for Innovation and Entrepreneurship of Hunan University of Science and Engineering 2021

Figures(8)

A novel Schiff-base fluorescent probe 6, 6'-((1E, 1'E)-(ethane-1, 2-diylbis(azaneylylidene))bis-(methaneylylidene))bis(3-(diethylamino)phenol) (L) was derived from the 2:1 M condensation of 4-(diethylamino)-2-hydroxybenzaldehyde with ethylenediamine and characterized by ¹H NMR, ¹³C NMR and FT-IR spectroscopies. The results of spectral analysis showed that the probe L is selective and sensitive to Cu²⁺. The detection limit of L is found to be 19 nmol·L^-1. There is a good linear relationship between the fluorescence intensity of probe L and the concentration of Cu²⁺ in the range of 0 to 20 μmol·L^-1. X-ray crystal structure of the L-Cu²⁺ complex and the Job plot revealed a 1:1 L-Cu²⁺ identification.
- Cu²⁺,
- salicylaldehyde,
- Schiff-base,
- fluorescent probe
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A Novel Salicylaldehyde Schiff-base Fluorescent Probe for Selective Detection of Cu2+Ion

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通讯作者: 陈斌, bchen63@163.com

A Novel Salicylaldehyde Schiff-base Fluorescent Probe for Selective Detection of Cu²⁺Ion