Citation: Wu-Jiu JIANG, Peng-Hui NI, Fang-Fang MAO, Yu-Xing TAN. Syntheses, Crystal Structures and Property of Pyridine Zinc(Ⅱ) Complexes Based on Halogenated Salicylaldehyde Schiff Base[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220301. doi: 10.14102/j.cnki.0254-5861.2011-3285 shu

Syntheses, Crystal Structures and Property of Pyridine Zinc(Ⅱ) Complexes Based on Halogenated Salicylaldehyde Schiff Base

Key Laboratory of Functional Metal-organic Compounds of Hunan Province, Key Laboratory of Organometallic New Materials, College of Hunan Province, Hunan Provincial Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: Yu-Xing TAN, xulichem@ujs.edu.cn
Received Date: 11 June 2021
Accepted Date: 31 August 2021

Fund Project: the Scientific Research Fund of Hunan Provincial Education Department of China 19C0279

Figures(6)

Schiff base pyridine zinc(Ⅱ) complexes 1~4 were synthesized by the reaction of the 2-((2-hydroxybenzylidene)amino)phenol Schiff base with appended donor functionality, zinc acetate, and pyridine. The results of the structural characterization of the complex show that they have the same coordination mode and similar steric structure. Complexes 1 and 3 form a one-dimensional chain structure and two-dimensional grid structure by lots of hydrogen bonds, respectively. Thermogravimetric analysis shows complexes 1~4 can exist stably below 150 ℃. The results of the fluorescence quenching experiments between the complexes and DNA-EB show that the interaction between them is intercalation, and the effect of complex 1 is the most obvious. It is speculated that the steric hindrance of complex 1 is relatively small, and the aromatic ring on the ligand is more likely to inserted into the base pair of DNA.
- zinc complex,
- Schiff base,
- synthesis,
- crystal structure,
- property
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