Citation: Zhi YANG, Kun-Rong LI, Yuan-Ye ZHANG, Jia-Le HU, Tian-Yuan LI, Zi-Xiang WENG, Li-Xin WU. Antibiotic Silver Particles Coated Graphene Oxide/polyurethane Nanocomposites Foams and Its Mechanical Properties[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220312. doi: 10.14102/j.cnki.0254-5861.2011-3273 shu

Antibiotic Silver Particles Coated Graphene Oxide/polyurethane Nanocomposites Foams and Its Mechanical Properties

Zhi YANG ^{a, b} ,
Kun-Rong LI ^{a, b} ,
Yuan-Ye ZHANG ^b ,
Jia-Le HU ^{a, b} ,
Tian-Yuan LI ^c ,
Zi-Xiang WENG ^b,, ,
Li-Xin WU ^b,,

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Key Lab for Sport Shoes Upper Materials of Fujian Province, Fujian Huafeng New Material Co., Ltd., Putian 351164, China

Corresponding author: Zi-Xiang WENG, wzx@fjirsm.ac.cn Li-Xin WU, lxwu@fjirsm.ac.cn
Received Date: 1 June 2021
Accepted Date: 6 July 2021

Fund Project: the National Natural Science Foundation of China U1905217the STS Project of Fujian-CAS 2019T3018the Natural Science Foundation of Fujian Province 2020J05084the Regional Development Projects of Fujian Province 2020H4018

Figures(3)

Silver nanoparticles (AgNPs) are widely adopted in polyurethane foams (PUFs) as a type of antibacterial agent. However, due to its poor interfacial interaction, AgNPs are difficult to be dispersed in the polymer matrix uniformly, which deteriorates the enhancement effect. In this paper, silver-coated graphene nanocomposite (Ag/GO) is prepared by an enzyme reductant which is efficient and non-toxic. Compared with traditional antibacterial agent, the Ag/GO nanoparticles can be uniformly dispersed in the nanocomposite, which means that Ag/GO can be well-dispersed into the polyurethane foams (PUFs). Compared with AgNPs modified PUFs, the as-prepared Ag/GO modified PUFs have a 1.85% improvement in resilience, 7.9% improvement in tensile strength, 6.52% improvement in tensile elongation, and 8.74% improvement in bacteriostats rate at a loading of 0.4%.
- graphene,
- nanocomposite,
- polyurethane foams,
- antibacterials
1. [1]
  Zhu, Y. F.; Xiong, J. P.; Tang, Y. M.; Zuo, Y. EIS study on failure process of two polyurethane composite coatings. Prog. Org. Coat. 2010, 69, 7–11. doi: 10.1016/j.porgcoat.2010.04.017
2. [2]
  Maminski, M. L.; Wieclaw-Midor, A. M.; Parzuchowski, P. G. The effect of silica-filler on polyurethane adhesives based on renewable resource for wood bonding. Polymers 2020, 12, 2177–13. doi: 10.3390/polym12102177
3. [3]
  Feng, C. F.; Yi, Z. F.; Jin, X.; Seraji, S. M.; Dong, Y. J.; Kong, L. X.; Salim, N. Solvent crystallization-induced porous polyurethane/graphene composite foams for pressure sensing. Compos. Pt. B-Eng. 2020, 194, 108065–10. doi: 10.1016/j.compositesb.2020.108065
4. [4]
  Yao, Y. Y.; Jin, S. H.; Ma, X. L.; Yu, R.; Zou, H. M.; Wang, H. J.; Lv, X. J.; Shu, Q. H. Graphene-containing flexible polyurethane porous composites with improved electromagnetic shielding and flame retardancy. Compos. Sci. Technol. 2020, 200, 108457–10. doi: 10.1016/j.compscitech.2020.108457
5. [5]
  Furtwengler, P.; Averous, L. Renewable polyols for advanced polyurethane foams from diverse biomass resources. Polym. Chem. 2018, 9, 4258–4287. doi: 10.1039/C8PY00827B
6. [6]
  Davis, R. L.; Nalepa, C. J. Studies of alkylthio-substituted aromatic diamines as curatives for polyurethane cast elastomers. J. Polym. Sci. Pol. Chem. 1990, 28, 3701–3724. doi: 10.1002/pola.1990.080281315
7. [7]
  Atiqah, A.; Mastura, M. T.; Ali, B. A.; Jawaid, M.; Sapuan, S. M. A review on polyurethane and its polymer composites. Curr. Org. Synth. 2017, 14, 233–248. doi: 10.2174/1570179413666160831124749
8. [8]
  Wang, L.; Hong, Y.; Li, J. X. Durability of running shoes with ethylene vinyl acetate or polyurethane midsoles. J. Sports Sci. 2012, 30, 1787–1792. doi: 10.1080/02640414.2012.723819
9. [9]
  Gheydari, M.; Dorraji, M. S. S.; Fazli, M.; Rasoulifard, M. H.; Almaie, S.; Daneshvar, H.; Ashjari, H. R. Preparation of open-cell polyurethane nanocomposite foam with Ag₃PO₄ and GO: antibacterial and adsorption characteristics. J. Polym. Res. 2021, 28, 02432–12.
10. [10]
  Sportelli, M. C.; Picca, R. A.; Ronco, R.; Bonerba, E.; Tantillo, G.; Pollini, M.; Sannino, A.; Valentini, A.; Cataldi, T. R. I.; Cioffi, N. Investigation of industrial polyurethane foams modified with antimicrobial copper nanoparticles. Materials 2016, 9, 9070544–13.
11. [11]
  Hong, C. H.; Kim, H. S.; Park, H. H.; Kim, Y. H.; Kim, S. B.; Hwang, T. W. Development of antimicrobial polyurethane foam for automotive seat modified by Urushiol. Polym. -Korea 2006, 30, 402–406.
12. [12]
  Udabe, E.; Isik, M.; Sardon, H.; Irusta, L.; Salsamendi, M.; Sun, Z.; Zheng, Z. Q.; Yan, F.; Mecerreyes, D. Antimicrobial polyurethane foams having cationic ammonium groups. J. Appl. Polym. Sci. 2017, 134, 45473–7. doi: 10.1002/app.45473
13. [13]
  Chernousova, S.; Epple, M. Silver as antibacterial agent: ion, nanoparticle, and metal. Angew. Chem. Int. Ed. 2013, 52, 1636–1653. doi: 10.1002/anie.201205923
14. [14]
  Madkour, T. M.; Abdelazeem, E. A.; Tayel, A.; Mustafa, G.; Siam, R. In situ polymerization of polyurethane-silver nanocomposite foams with intact thermal stability, improved mechanical performance, and induced antimicrobial properties. J. Appl. Polym. Sci. 2016, 43125–133.
15. [15]
  Kvitek, L.; Panacek, A.; Prucek, R.; Soukupova, J.; Vanickova, M.; Kolar, M.; Zboril, R. Antibacterial activity and toxicity of silver – nanosilver versus ionic silver. J. Phys. Conf. Ser. 2011, 304, 012029–9. doi: 10.1088/1742-6596/304/1/012029
16. [16]
  Vinay, V. C.; Varma, D. S. M.; Chandan, M. R.; Sivabalan, P.; Jaiswal, A. K.; Swetha, S.; Kaczmarek, B.; Sionkowska, A. Study of silver nanoparticle-loaded auxetic polyurethane foams for medical cushioning applications. Polym. Bull. 2021, 78, 03705–18. doi: 10.1007/s00289-020-03289-y
17. [17]
  Zhao, B.; Qian, Y.; Qian, X.; Fan, J.; Feng, Y. Fabrication and characterization of waterborne polyurethane/silver nanocomposite foams. Polym. Compos. 2019, 40, 1492–1498. doi: 10.1002/pc.24888
18. [18]
  Wattanodorn, Y.; Jenkan, R.; Atorngitjawat, P.; Wirasate, S. Antibacterial anionic waterborne polyurethanes/Ag nanocomposites with enhanced mechanical properties. Polym. Test. 2014, 40, 163–169. doi: 10.1016/j.polymertesting.2014.09.004
19. [19]
  Njuguna, J.; Pielichowski, K. Polymer nanocomposites for aerospace applications: fabrication. Adv. Eng. Mater. 2004, 6, 193–203. doi: 10.1002/adem.200305111
20. [20]
  Maiti, D.; Tong, X. M.; Mou, X. Z.; Yang, K. Carbon-based nanomaterials for biomedical applications: a recent study. Front. Pharmacol. 2019, 9, 01401–16. doi: 10.3389/fphar.2018.01401
21. [21]
  Ravishankar, B.; Nayak, S. K.; Kader, M. A. Hybrid composites for automotive applications - a review. J. Reinf. Plast. Compos. 2019, 38, 835–845. doi: 10.1177/0731684419849708
22. [22]
  Kamran, U.; Heo, Y. J.; Lee, J. W.; Park, S. J. Functionalized carbon materials for electronic devices: a review. Micromachines 2019, 10, 10040234–25.
23. [23]
  Le, B.; Khaliq, J.; Huo, D. H.; Teng, X. Y.; Shyha, I. A review on nanocomposites. Part 1: mechanical properties. J. Manuf. Sci. Eng. -Trans. ASME 2020, 142, 100801–23. doi: 10.1115/1.4047047
24. [24]
  Papageorgiou, D. G.; Li, Z. L.; Liu, M. F.; Kinloch, I. A.; Young, R. J. Mechanisms of mechanical reinforcement by graphene and carbon nanotubes in polymer nanocomposites. Nanoscale 2020, 12, 2228–2267. doi: 10.1039/C9NR06952F
25. [25]
  Ke, K.; Yue, L.; Shao, H. Q.; Yang, M. B.; Yang, W.; Manas-Zloczower, I. Boosting electrical and piezoresistive properties of polymer nanocomposites via hybrid carbon fillers: a review. Carbon 2021, 173, 1020–1040. doi: 10.1016/j.carbon.2020.11.070
26. [26]
  Wang, R.; Zhuo, D.; Weng, Z.; Wu, L.; Cheng, X.; Zhou, Y.; Wang, J.; Xuan, B. A novel nanosilica/graphene oxide hybrid and its flame retarding epoxy resin with simultaneously improved mechanical, thermal conductivity, and dielectric properties. J. Mater. Chem. A 2015, 3, 9826–9836. doi: 10.1039/C5TA00722D
27. [27]
  Dai, X. Y.; Du, Y. Z.; Yang, J. Y.; Wang, D.; Gu, J. W.; Li, Y. F.; Wang, S.; Xu, B. B.; Kong, J. Recoverable and self-healing electromagnetic wave absorbing nanocomposites. Compos. Sci. Technol. 2019, 174, 27–32. doi: 10.1016/j.compscitech.2019.02.018
28. [28]
  Liu, S.; Qin, S. H.; Jiang, Y.; Song, P. A.; Wang, H. Lightweight high-performance carbon-polymer nanocomposites for electromagnetic interference shielding. Compos. Pt. A-Appl. Sci. Manuf. 2021, 145, 106376–30. doi: 10.1016/j.compositesa.2021.106376
29. [29]
  Sun, X.; Huang, C.; Wang, L.; Liang, L.; Cheng, Y.; Fei, W.; Li, Y. Recent progress in graphene/polymer nanocomposites. Adv. Mater. 2021, 33, 2001105–28. doi: 10.1002/adma.202001105
30. [30]
  Rahmani, Z.; Samadi, M. T.; Kazemi, A.; Rashidi, A. M.; Rahmani, A. R. Nanoporous graphene and graphene oxide-coated polyurethane sponge as a highly efficient, superhydrophobic, and reusable oil spill absorbent. J. Environ. Chem. Eng. 2017, 5, 5025–5032. doi: 10.1016/j.jece.2017.09.028
31. [31]
  Zhang, X. T.; Liu, D. Y.; Ma, Y. L.; Nie, J.; Sui, G. X. Super-hydrophobic graphene coated polyurethane (GN@PU) sponge with great oil-water separation performance. Appl. Surf. Sci. 2017, 422, 116–124. doi: 10.1016/j.apsusc.2017.06.009
32. [32]
  Baek, S. H.; Kim, J. H. Polyurethane composite foams including silicone-acrylic particles for enhanced sound absorption via increased damping and frictions of sound waves. Compos. Sci. Technol. 2020, 198, 108325–7. doi: 10.1016/j.compscitech.2020.108325
33. [33]
  Tang, Y. M.; Guo, Q. Q.; Chen, Z. M.; Zhang, X. X.; Lu, C. H. In-situ reduction of graphene oxide-wrapped porous polyurethane scaffolds: synergistic enhancement of mechanical properties and piezoresistivity. Compos. Pt. A-Appl. Sci. Manuf. 2019, 116, 106–113. doi: 10.1016/j.compositesa.2018.10.025
34. [34]
  Shao, W.; Liu, X. F.; Min, H. H.; Dong, G. H.; Feng, Q. Y.; Zuo, S. L. Preparation, characterization, and antibacterial activity of silver nanoparticle-decorated graphene oxide nanocomposite. ACS Appl. Mater. Interfaces 2015, 7, 6966–6973. doi: 10.1021/acsami.5b00937
35. [35]
  Shuai, C. J.; Guo, W.; Wu, P.; Yang, W. J.; Hu, S.; Xia, Y.; Feng, P. A graphene oxide-Ag co-dispersing nanosystem: dual synergistic effects on antibacterial activities and mechanical properties of polymer scaffolds. Chem. Eng. J. 2018, 347, 322–333. doi: 10.1016/j.cej.2018.04.092
36. [36]
  Bao, Q.; Zhang, D.; Qi, P. Synthesis and characterization of silver nanoparticle and graphene oxide nanosheet composites as a bactericidal agent for water disinfection. J. Colloid Interface Sci. 2011, 360, 463–470. doi: 10.1016/j.jcis.2011.05.009
37. [37]
  Jeronsia, J. E.; Ragu, R.; Sowmya, R.; Mary, A. J.; Das, S. J. Comparative investigation on camellia sinensis mediated green synthesis of Ag and Ag/GO nanocomposites for its anticancer and antibacterial efficacy. Surf. Interfaces 2020, 21, 100787–10. doi: 10.1016/j.surfin.2020.100787
38. [38]
  Chen, Y. N.; Hsueh, Y. H.; Hsieh, C. T.; Tzou, D. Y.; Chang, P. L. Antiviral activity of graphene-silver nanocomposites against non-enveloped and enveloped viruses. Int. J. Environ. Res. Public. Health 2016, 13, 040430–12.
39. [39]
  Marcano, D. C.; Kosynkin, D. V.; Berlin, J. M.; Sinitskii, A.; Sun, Z. Z.; Slesarev, A.; Alemany, L. B.; Lu, W.; Tour, J. M. Improved synthesis of graphene oxide. ACS Nano 2010, 4, 4806–4814. doi: 10.1021/nn1006368
40. [40]
  Yoo, M. J.; Park, H. B. Effect of hydrogen peroxide on properties of graphene oxide in Hummers method. Carbon 2019, 141, 515–522. doi: 10.1016/j.carbon.2018.10.009
41. [41]
  Dong, L.; Yang, J.; Chhowalla, M.; Loh, K. P. Synthesis and reduction of large sized graphene oxide sheets. Chem. Soc. Rev. 2017, 46, 7306–7316. doi: 10.1039/C7CS00485K
42. [42]
  Kalishwaralal, K.; Deepak, V.; Pandian, S. R. K.; Gurunathan, S. Biological synthesis of gold nanocubes from Bacillus licheniformis. Bioresour. Technol. 2009, 100 21, 5356–5358.
43. [43]
  Agata, Y.; Iwao, Y.; Miyagishima, A.; Itai, S. Novel mathematical model for predicting the dissolution profile of spherical particles under non-sink conditions. Chem. Pharm. Bull. 2010, 58, 511–515. doi: 10.1248/cpb.58.511
44. [44]
  Lobos, J.; Velankar, S. How much do nanoparticle fillers improve the modulus and strength of polymer foams? J. Cell. Plast. 2016, 52, 57–88. doi: 10.1177/0021955X14546015
1. [1]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
2. [2]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
5. [5]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
6. [6]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
7. [7]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
8. [8]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
9. [9]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
10. [10]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
11. [11]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
12. [12]
  Fangzhou Wang , Wentong Gao , Chenghui Li . A weak but inert hindered urethane bond for high-performance dynamic polyurethane polymers. Chinese Chemical Letters, 2024, 35(5): 109305-. doi: 10.1016/j.cclet.2023.109305
13. [13]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
14. [14]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
15. [15]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(469)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142