Citation: Qing-Feng YANG, Kai YUE, Zhi-Hui WANG, Xiao-Yong LAI, Xiao-Zhong WANG, Ling QIN. Structural and Magnetic Characterization of Two New Coordination Compounds Based on a Fluorene Derivative Ligand[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220206. doi: 10.14102/j.cnki.0254-5861.2011-3266 shu

Structural and Magnetic Characterization of Two New Coordination Compounds Based on a Fluorene Derivative Ligand

a.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
b.
Chongqing Changfeng Chemical Industrial Co., Ltd., Chongqing 401220, China

Corresponding author: Qing-Feng YANG, yangqf@nxu.edu.cn Xiao-Zhong WANG, xzwang@nxu.edu.cn
Received Date: 25 May 2021
Accepted Date: 10 July 2021

Fund Project: the National Natural Science Foundation of China 21961027the National Natural Science Foundation of China 21461020the Natural Science Foundation of Ningxia 2019AAC03071the National First-rate Discipline Construction Project of Ningxia (Chemical Engineering and Technology) NXYLXK2017A04

Figures(7)

Two new coordination compounds [Co(FDC)₂(H₂O)₂]_n (1) and [Cu(FDC)₂(2, 2΄-bpy)]·DMF·H₂O (2) (HFDC = 9-fluorenone-4-carboxylic acid, bpy = 2, 2΄-bipyridine, DMF = N, N-dimethylformamide) were prepared by the reactions of corresponding metal salts with a fluorene derivative ligand of HFDC. Both compounds were thoroughly analyzed by X-ray single-crystal diffraction, elemental analysis, IR spectra, PXRD and thermal analysis. Compound 1 features a 1D structure. Via two kinds of O‒H···O hydrogen bonds, such 1D chains self-assemble into a 3D supramolecular structure stabilized by the offset face-to-face π···π interactions. Compound 2 features a dinuclear structure which, via O‒H···O and C‒H···O hydrogen bonds, self-assembles into a 2D supramolecular layer strengthened by strong face-to-face π···π interactions. And variable-temperature magnetic susceptibilities of 1 and 2 indicate weak antiferromagnetic interactions between the Co(II) and Cu(II) metal ions.
- low-dimensional coordination compounds,
- fluorene derivative,
- magnetic properties
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