Citation: Xin ZHANG, Zhen-Xia CHEN, Yong-Tai YANG, Ming-Li DENG, Lin-Hong WENG. Effect of Fluorination on the Crystal Structure, Stability and Gas Adsorption Property in Zinc(II) Metal-organic Frameworks[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220204. doi: 10.14102/j.cnki.0254-5861.2011-3264 shu

Effect of Fluorination on the Crystal Structure, Stability and Gas Adsorption Property in Zinc(II) Metal-organic Frameworks

Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, China

Corresponding author: Ming-Li DENG, mldeng@fudan.edu.cn
Received Date: 22 May 2021
Accepted Date: 23 July 2021

Fund Project: the NSFC 21971045Natural Science Foundation of Shanghai 18ZR1402900the National Key Technologies R & D Program of China 2017YFA0205103Shanghai Leading Academic Discipline Project B108

Figures(5)

Three zinc(II) metal-organic frameworks (xF-MAC-3) have been synthesized by using Zn(II) salts, 3, 5-dimethyl-1H-1, 2, 4-triazole (Hdmtrz) and different fluorination degree carboxylate ligands, which are analogic structures and can be described as (6, 6)-connected pcu-b net. We find that the fluorine atoms have structural regulation effect on xF-MAC-3, which can not only enlarge the torsion angle ? of carboxylate ligands but also elevate the space group of structures. Besides, the CO₂-273 K uptake increased from 23.21 cm³·g^-1 (MAC-3) to 36.13 cm³·g^-1 (4F-MAC-3) and H₂-77 K uptake increased from 24.33 cm³·g^-1 (MAC-3) to 59.79 cm³·g^-1 (4F-MAC-3), which means fluorination can enhance the gas adsorption uptake of xF-MAC-3 analogues. Furthermore, the results of fluorination in xF-MAC-3 analogues offer a potential way to study the ligand pre-functionalization effect on the structures and properties of MOFs analogues.
- metal-organic frameworks,
- fluorine functionalization,
- X-ray crystallography,
- gas adsorption
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