Citation: Hai-Su WU, Ti-Fang MIAO, Hai-Xia SHI, Yun XU, Xian-Liang FU, Li QIAN. Probing Photocatalytic Hydrogen Evolution of Cobalt Complexes: Experimental and Theoretical Methods[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1696-1709. doi: 10.14102/j.cnki.0254-5861.2011-3239 shu

Probing Photocatalytic Hydrogen Evolution of Cobalt Complexes: Experimental and Theoretical Methods

Hai-Su WU ^a ,
Ti-Fang MIAO ^a,, ,
Hai-Xia SHI ^a ,
Yun XU ^a,, ,
Xian-Liang FU ^a ,
Li QIAN ^b

a.
School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, China
b.
College of Pharmacy, Youjiang Medical College for Nationalities, Baise 533000, China

Corresponding author: Ti-Fang MIAO, miaotifang@163.com Yun XU, xuyun88@163.com
Received Date: 28 April 2021
Accepted Date: 13 July 2021

Fund Project: the Natural Science Foundation of Anhui Province for Distinguished Young Scholars 1808085J24the Natural Science Foundation of Anhui Province 1808085MB45the Natural Science Foundation of Educational Committee of Anhui Province KJ2020A0022the Excellent Youth Talent Support Program of Anhui Province gxyq2020101

Figures(12)

This work reports on the synthesis and characterization of a series of Schiff-base cobalt(Ⅲ) complexes 1~4 that exhibit an obvious catalytic activity for hydrogen production in aqueous solution using fluorescein (FL) and triethanolamine (TEOA) as photosensitizer and electron donor, respectively. The complexes display the capability of splitting of water for H₂ evolution. Under optimized conditions, complex 3 shows better properties for photocatalysis, 25 mg of which can release 152.3 μmol of H₂ after irradiation for 3 h. The mechanism for light-driven H₂ production was explored by experiments and density functional theory (DFT). Meanwhile, the reason of releasing hydrogen was explained theoretically in detail. The research results will help to understand the interaction of cobalt complexes with the photosensitizer and design new photocatalysis for the future.
- hydrogen production,
- cobalt complex,
- photocatalysis,
- theoretical calculation
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沈阳化工大学材料科学与工程学院沈阳 110142