Citation: Song-Xia WANG, Sa-Sa WANG, Xiao-Yuan WU, Wen-Bin YANG, Can-Zhong LU. Two Polyoxometalate-based Host-guest Compounds: Synthesis, Crystal Structure and Catalytic Performance[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1655-1660. doi: 10.14102/j.cnki.0254-5861.2011-3226 shu

Two Polyoxometalate-based Host-guest Compounds: Synthesis, Crystal Structure and Catalytic Performance

Song-Xia WANG ^{a, b} ,
Sa-Sa WANG ^b ,
Xiao-Yuan WU ^b ,
Wen-Bin YANG ^b ,
Can-Zhong LU ^{b, c,,}

a.
Fujian Normal University, Fuzhou 350007, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Can-Zhong LU, czlu@fjirsm.ac.cn
Received Date: 19 April 2021
Accepted Date: 11 June 2021

Fund Project: the Key Research Program of Frontier Science, CAS QYZDJ-SSW-SLH033the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the National Natural Science Foundation of China 21773247the National Natural Science Foundation of China 21521061the National Natural Science Foundation of China 21875252the National Natural Science Foundation of China 52073286

Figures(4)

Two polyoxometalate-based host-guest compounds, (HL₁)₂(HPW₁₂O₄₀)·~11H₂O (1), (HL₂)₃(PW₁₂O₄₀)·3H₂O (2) (L₁ = guanine, L₂ = 2-(1H-1, 2, 4-triazol-3-yl)pyridine), were synthesized under hydrothermal conditions and characterized by EA, PXRD, TG, FT-IR and X-ray single-crystal diffraction. Compound 1 crystallizes in trigonal space group P-3 with a = 18.2917(5), b = 18.2917(5), c = 13.5441(5) Å, V = 3924.5(3) Å³, Z = 3, M_r = 3383.26 g/mol, ρ_calc = 4.036 g/cm³, F(000) = 4137, μ = 48.532 mm^–1, GOOF = 1.062, the final R = 0.0713 and wR = 0.1865 for 9037 observed reflections with I > 2σ(I). Compound 2 crystallizes in trigonal space group R-3 with a = 19.0017(6), b = 19.0017(6), c = 25.6361(9) Å, V = 8016.2(6) Å³, Z = 6, M_r = 3372.45 g/mol, ρ_calc = 4.188 g/cm, F(000) = 8886, μ = 47.644 mm^–1, GOOF = 1.077, the final R = 0.0380 and wR = 0.0976 for 5904 observed reflections with I > 2σ(I). These two compounds can catalyze selective oxidation of aniline with H₂O₂ as the oxidant. Under optimal conditions, the conversion of aniline with compound 1 can reach up to 91.25%, and the selectivity of nitrosobenzene is 78.81%.
- polyoxometalates,
- catalytic oxidation,
- aniline,
- nitrosobenzene
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