Citation: Song-Xia WANG, Sa-Sa WANG, Xiao-Yuan WU, Wen-Bin YANG, Can-Zhong LU. Two Polyoxometalate-based Host-guest Compounds: Synthesis, Crystal Structure and Catalytic Performance[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1655-1660. doi: 10.14102/j.cnki.0254-5861.2011-3226 shu

Two Polyoxometalate-based Host-guest Compounds: Synthesis, Crystal Structure and Catalytic Performance

Song-Xia WANG ^{a, b} ,
Sa-Sa WANG ^b ,
Xiao-Yuan WU ^b ,
Wen-Bin YANG ^b ,
Can-Zhong LU ^{b, c,,}

a.
Fujian Normal University, Fuzhou 350007, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Can-Zhong LU, czlu@fjirsm.ac.cn
Received Date: 19 April 2021
Accepted Date: 11 June 2021

Fund Project: the Key Research Program of Frontier Science, CAS QYZDJ-SSW-SLH033the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the National Natural Science Foundation of China 21773247the National Natural Science Foundation of China 21521061the National Natural Science Foundation of China 21875252the National Natural Science Foundation of China 52073286

Figures(4)

Two polyoxometalate-based host-guest compounds, (HL₁)₂(HPW₁₂O₄₀)·~11H₂O (1), (HL₂)₃(PW₁₂O₄₀)·3H₂O (2) (L₁ = guanine, L₂ = 2-(1H-1, 2, 4-triazol-3-yl)pyridine), were synthesized under hydrothermal conditions and characterized by EA, PXRD, TG, FT-IR and X-ray single-crystal diffraction. Compound 1 crystallizes in trigonal space group P-3 with a = 18.2917(5), b = 18.2917(5), c = 13.5441(5) Å, V = 3924.5(3) Å³, Z = 3, M_r = 3383.26 g/mol, ρ_calc = 4.036 g/cm³, F(000) = 4137, μ = 48.532 mm^–1, GOOF = 1.062, the final R = 0.0713 and wR = 0.1865 for 9037 observed reflections with I > 2σ(I). Compound 2 crystallizes in trigonal space group R-3 with a = 19.0017(6), b = 19.0017(6), c = 25.6361(9) Å, V = 8016.2(6) Å³, Z = 6, M_r = 3372.45 g/mol, ρ_calc = 4.188 g/cm, F(000) = 8886, μ = 47.644 mm^–1, GOOF = 1.077, the final R = 0.0380 and wR = 0.0976 for 5904 observed reflections with I > 2σ(I). These two compounds can catalyze selective oxidation of aniline with H₂O₂ as the oxidant. Under optimal conditions, the conversion of aniline with compound 1 can reach up to 91.25%, and the selectivity of nitrosobenzene is 78.81%.
- polyoxometalates,
- catalytic oxidation,
- aniline,
- nitrosobenzene
1. [1]
  Li, T. F.; Miras, H. N.; Song, Y. F. Polyoxometalate (POM)-layered double hydroxides (LDH) composite materials: design and catalytic applications. Catalysts 2017, 7, 260. doi: 10.3390/catal7090260
2. [2]
  Pope, M. T.; Müller, A. Polyoxometalate Chemistry: from Topology via Self-assembly to Applications 2001.
3. [3]
  Mizuno, N.; Yamaguchi, K.; Kamata, K. Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates. Coordin. Chem. Rev. 2004, 249, 1944–1956.
4. [4]
  Miras, H. N.; Yan, J.; Long, D. L.; Cronin, L. Engineering polyoxometalates with emergent properties. Chem. Soc. Rev. 2012, 41, 7403–7430. doi: 10.1039/c2cs35190k
5. [5]
  Barteau, M. A.; Lyons, J. E.; Song, I. K. Surface chemistry and catalysis on well-defined oxide surfaces: nanoscale design bases for single-site heterogeneous catalysts. J. Catal. 2003, 216, 236–245. doi: 10.1016/S0021-9517(02)00114-8
6. [6]
  Deshlahra, P.; Carr, R. T.; Chai, S. H.; Iglesia, E. Mechanistic details and reactivity descriptors in oxidation and acid catalysis of methanol. ACS Catal. 2015, 5, 666–682. doi: 10.1021/cs501599y
7. [7]
  Wang, S. S.; Yang, G. Y. Recent advances in polyoxometalate-catalyzed reactions. Chem. Rev. 2015, 115, 4893–4962. doi: 10.1021/cr500390v
8. [8]
  Kumar, A.; Gupta, A. K.; Devi, M.; Gonsalves, K. E.; Pradeep, C. P. Engineering multifunctionality in hybrid polyoxometalates: aromatic sulfonium octamolybdates as excellent photochromic materials and self-separating catalysts for epoxidation. Inorg. Chem. 2017, 56, 10325–10336. doi: 10.1021/acs.inorgchem.7b01143
9. [9]
  Wilke, T.; Barteau, M. A. Dehydration and oxidation of alcohols by supported polyoxometalates: effects of mono- and multivalent cation exchange on catalyst acidity and activity. Ind. Eng. Chem. Res. 2019, 58, 14752–14760. doi: 10.1021/acs.iecr.9b03084
10. [10]
  Wilke, T.; Barteau, M. A. Cation exchange effects on methanol oxidation and dehydration by supported polyoxometalates. J. Catal. 2019, 371, 357–367. doi: 10.1016/j.jcat.2019.02.006
11. [11]
  Uchida, S. Frontiers and progress in cation-uptake and exchange chemistry of polyoxometalate-based compounds. Chem. Sci. 2019, 10, 7670–7679. doi: 10.1039/C9SC02823D
12. [12]
  Derouich, S. G.; Rinfray, C.; Izzet, G.; Pinson, J.; Gallet, J. J.; Kanoufi, F.; Proust, A.; Combellas, C. Control of the grafting of hybrid polyoxometalates on metal and carbon surfaces: toward submonolayers. Langmuir. 2014, 30, 2287–2296. doi: 10.1021/la500067e
13. [13]
  Zhang, M.; Li, H. J.; Zhang, J. H.; Lv, H. J.; Yang, G. Y. Research advances of light-driven hydrogen evolution using polyoxometalate-based catalysts. Chin. J. Catal. 2021, 42, 855–871. doi: 10.1016/S1872-2067(20)63714-7
14. [14]
  Gong, Y.; Hu, C. W.; Liang, H. Research progress in synthesis and catalysis of polyoxometalates. Prog. Nat. Sci-Mater. 2005, 15, 385–394. doi: 10.1080/10020070512331342280
15. [15]
  Liu, P.; Wang, C. H.; Li, C. Epoxidation of allylic alcohols on self-assembled polyoxometalates hosted in layered double hydroxides with aqueous H₂O₂ as oxidant. J. Catal. 2009, 262, 159–168. doi: 10.1016/j.jcat.2008.12.018
16. [16]
  Li, J.; Huang, Y.; Han, Q. X. Decatungstate incorporated metal-organic framework for degradation of Rhodamine B under sunlight irradiation. Chin. J. Struct. Chem. 2013, 32, 1897–1903.
17. [17]
  Sakaue, S.; Sakata, Y.; Nishiyama, Y.; Ishii, Y. Oxidation of aliphatic and aromatic amines with hydrogen peroxide catalyzed by peroxoheteropoly oxometalates. Chem. Lett. 1992, 21, 289–292. doi: 10.1246/cl.1992.289
18. [18]
  Tang, G. Q.; Sun, J.; Wu, F. K.; Sun, Y.; Zhu, X. W.; Geng, Y. J.; Wang, Y. S. Organic composition of gasoline and its potential effects on air pollution in North China. Sci. China Chem. 2015, 58, 1416-1425. doi: 10.1007/s11426-015-5464-0
19. [19]
  Trautwein, G.; El Bakkali, B.; Alcaniz-Monge, J.; Artetxe, B.; Reinoso, S.; Gutierrez-Zorrilla, J. M. Dimeric assemblies of lanthanide-stabilised dilacunary Keggin tungstogermanates: a new class of catalysts for the selective oxidation of aniline. J. Catal. 2015, 331, 110–117. doi: 10.1016/j.jcat.2015.09.004
20. [20]
  Gowenlock, B. G.; Richter-Addo, G. B. Preparations of C-nitroso compounds. Chem. Rev. 2004, 104, 3315–3340.
21. [21]
  Rao, G. R.; Rajkumar, T. Investigation of 12-tungstophosphoric acid supported on Ce_0.5Zr_0.5O₂ solid solution. Catal. Lett. 2008, 120, 261–273. doi: 10.1007/s10562-007-9279-2
22. [22]
  Oza, M. D.; Meena, R.; Prasad, K.; Paul, P.; Siddhanta, A. K. Functional modification of agarose: a facile synthesis of a fluorescent agarose-guanine derivative. Carbohyd. Polym. 2010, 81, 878–884. doi: 10.1016/j.carbpol.2010.03.062
23. [23]
  Ma, W. D.; Li, H. L.; Yang, G. Y. A new 3-D supramolecular framework built by Co₄-substituted sandwiched phosphortungstates, organoamines and Co-complexes: synthesis, structure, and property. Chin. J. Struct. Chem. 2019, 38, 1585–1592.
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