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Citation: Jian-Dong-Yong LIU, Xu YU, Jing-Ze BAO, Ying-Xi LIN. A Polyanionic, Quasi-zero-strain and Open-framework K0.76V0.55Nb0.45OPO4 for Sodium-ion Batteries[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1631-1638. doi: 10.14102/j.cnki.0254-5861.2011-3221 shu

A Polyanionic, Quasi-zero-strain and Open-framework K0.76V0.55Nb0.45OPO4 for Sodium-ion Batteries

  • a.

    CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • b.

    College of Chemistry, Fuzhou University, Fuzhou 350108, China

  • Corresponding author: Ying-Xi LIN, linyingxi90@foxmail.com
    • * These authors have contributed equally
  • Received Date: 15 April 2021
    Accepted Date: 31 May 2021

    Fund Project: the National Natural Science Foundation of China 21771180

Figures(5)

  • A carbon-coated K0.76V0.55Nb0.45OPO4 (KVNP@C) polyanion material was successfully synthesized by a simple sol-gel method. The KVNP@C possesses a highly stable inorganic open-framework structure, which is hard to be affected by the Na+ intercalation/deintercalation when used as an anode material for sodium-ion batteries (NIBs). The assembled KVNP@C/Na half-cell shows a capacity retention of 81.2% and an average Coulombic efficiency of 99.8% at a current density of 300 mA/g after 1500 cycles. In-situ XRD analysis reveals a single-phase solid solution reaction mechanism with a lattice expansion of 4.76%. This work sheds insights into the quest for developing novel polyanion-based anode materials for sodium-ion batteries.
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    1. [1]

      Muñoz-Márquez, M. Á.; Saurel, D.; Gómez-Cámer, J. L.; Casas-Cabanas, M.; Castillo-Martínez, E.; Rojo, T. Na-ion batteries for large scale applications: a review on anode materials and solid electrolyte interphase formation. Adv. Energy Mater. 2017, 7, 1700463.  doi: 10.1002/aenm.201700463

    2. [2]

      Kim, J.; Choi, M. S.; Shin, K. H.; Kota, M.; Kang, Y.; Lee, S.; Lee, J. Y.; Park, H. S. Rational design of carbon nanomaterials for electrochemical sodium storage and capture. Adv. Mater. 2019, 31, 1803444.  doi: 10.1002/adma.201803444

    3. [3]

      Ong, S. P.; Chevrier, V. L.; Hautier, G.; Jain, A.; Moore, C.; Kim, S.; Ma, X.; Ceder, G. Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials. Energy Environ. Sci. 2011, 4, 3680–3688.  doi: 10.1039/c1ee01782a

    4. [4]

      Sun, Y.; Guo, S.; Zhou, H. Exploration of advanced electrode materials for rechargeable sodium-ion batteries. Adv. Energy Mater. 2018, 9, 1800212.

    5. [5]

      Cao, Y.; Xiao, L.; Sushko, M. L.; Wang, W.; Schwenzer, B.; Xiao, J.; Nie, Z.; Saraf, L. V.; Yang, Z.; Liu, J. Sodium ion insertion in hollow carbon nanowires for battery applications. Nano Lett. 2012, 12, 3783–3787.  doi: 10.1021/nl3016957

    6. [6]

      Wang, G. Z.; Feng, J. M.; Dong, L.; Li, X. F.; Li, D. J. Porous graphene anchored with Sb/sbox as sodium-ion battery anode with enhanced reversible capacity and cycle performance. J. Alloys Compd. 2017, 693, 141–149.  doi: 10.1016/j.jallcom.2016.09.150

    7. [7]

      Tamaru, M.; Chung, S. C.; Shimizu, D.; Nishimura, S. I.; Yamada, A. Pyrophosphate chemistry toward safe rechargeable batteries. Chem. Mater. 2013, 25, 2538–2543.  doi: 10.1021/cm4010739

    8. [8]

      Ellis, B. L.; Lee, K. T.; Nazar, L. F. Positive electrode materials for Li-ion and Li-batteries. Chem. Mater. 2010, 22, 691–714.  doi: 10.1021/cm902696j

    9. [9]

      Palomares, V.; Serras, P.; Villaluenga, I.; Hueso, K. B.; Carretero-González, J.; Rojo, T. Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ. Sci. 2012, 5, 5884–5901.  doi: 10.1039/c2ee02781j

    10. [10]

      Zhu, C.; Song, K.; van Aken, P. A.; Maier, J.; Yu, Y. Carbon-coated Na3V2(PO4)3 embedded in porous carbon matrix: an ultrafast Na-storage cathode with the potential of outperforming Li cathodes. Nano Lett. 2014, 14, 2175–2180.  doi: 10.1021/nl500548a

    11. [11]

      Bierlein, J. D.; Vanherzeele, H. Potassium titanyl phosphate-properties and new applications. J. Opt. Soc. AM. B 1989, 6, 622–633.  doi: 10.1364/JOSAB.6.000622

    12. [12]

      Rangan, K. K.; Verbaere, A.; Gopalakrishnan, J. Structure of KNb0.5V0.5OPO4, a KTiOPO4 analog. Mater. Res. Bull. 1998, 33, 395–399.  doi: 10.1016/S0025-5408(97)00252-3

    13. [13]

      Bommier, C.; Ji, X. Electrolytes, sei formation, and binders: a review of nonelectrode factors for sodium-ion battery anodes. Small. 2018, 14, 1703576.  doi: 10.1002/smll.201703576

    14. [14]

      Kim, J.; Seo, D. H.; Kim, H.; Park, I.; Yoo, J. K.; Jung, S. K.; Park, Y. U.; Goddard Iii, W. A.; Kang, K. Unexpected discovery of low-cost maricite NaFePO4 as a high-performance electrode for Na-ion batteries. Energy Environ. Sci. 2015, 8, 540–545.  doi: 10.1039/C4EE03215B

    15. [15]

      Liu, Y.; Xu, Y.; Han, X.; Pellegrinelli, C.; Zhu, Y.; Zhu, H.; Wan, J.; Chung, A. C.; Vaaland, O.; Wang, C.; Hu, L. Porous amorphous FePO4 nanoparticles connected by single-wall carbon nanotubes for sodium ion battery cathodes. Nano Lett. 2012, 12, 5664–5668.  doi: 10.1021/nl302819f

    16. [16]

      Sun, Q.; Ren, Q. Q.; Fu, Z. W. Nasicon-type Fe2(MoO4)3 thin film as cathode for rechargeable sodium ion battery. Electrochem. Commun. 2012, 23, 145–148.  doi: 10.1016/j.elecom.2012.07.023

    17. [17]

      Tripathi, R.; Wood, S. M.; Islam, M. S.; Nazar, L. F. Na-ion mobility in layered Na2FePO4F and olivine Na[Fe, Mn]PO4. Energy Environ. Sci. 2013, 6, 2257–2264.  doi: 10.1039/c3ee40914g

    18. [18]

      Chen, C. Y.; Matsumoto, K.; Nohira, T.; Hagiwara, R. Na2MnSiO4 as a positive electrode material for sodium secondary batteries using an ionic liquid electrolyte. Electrochem. Commun. 2014, 45, 63–66.  doi: 10.1016/j.elecom.2014.05.017

    19. [19]

      Kim, H.; Shakoor, R. A.; Park, C.; Lim, S. Y.; Kim, J. S.; Jo, Y. N.; Cho, W.; Miyasaka, K.; Kahraman, R.; Jung, Y.; Choi, J. W. Na2FeP2O7 as a promising iron-based pyrophosphate cathode for sodium rechargeable batteries: a combined experimental and theoretical study. Adv. Funct. Mater. 2013, 23, 1147–1155.  doi: 10.1002/adfm.201201589

    20. [20]

      Fang, Y.; Liu, Q.; Xiao, L.; Ai, X.; Yang, H.; Cao, Y. High-performance olivine NaFePO4 microsphere cathode synthesized by aqueous electrochemical displacement method for sodium ion batteries. ACS Appl. Mater. Interfaces 2015, 7, 17977–17984.  doi: 10.1021/acsami.5b04691

    21. [21]

      Yang, J.; Wang, H.; Hu, P.; Qi, J.; Guo, L.; Wang, L. A high-rate and ultralong-life sodium-ion battery based on NaTi2(PO4)3 nanocubes with synergistic coating of carbon and rutile TiO2. Small. 2015, 11, 3744–3749.  doi: 10.1002/smll.201500144

    22. [22]

      Patoux, S.; Rousse, G.; Leriche, J. B.; Masquelier, C. Structural and electrochemical studies of rhombohedral Na2TiM(PO4)3 and Li1.6Na0.4TiM(PO4)3 (M: Fe, Cr) phosphates. Chem. Mater. 2003, 15, 2084–2093.  doi: 10.1021/cm020479p

    23. [23]

      Chen, N.; Gao, Y.; Zhang, M.; Meng, X.; Wang, C.; Wei, Y.; Du, F.; Chen, G. Electrochemical properties and sodium-storage mechanism of Ag2Mo2O7 as the anode material for sodium-ion batteries. Chem-Eur. J. 2016, 22, 7248–7254.  doi: 10.1002/chem.201600224

    24. [24]

      Gnanavel, M.; Raveau, B.; Pralong, V. Electrochemical Li/Na intercalation in TiOSO4, first member of the phosphate tungsten bronze-type family. J. Electrochem. Soc. 2015, 162, A465–A469.  doi: 10.1149/2.0831503jes

    25. [25]

      Senguttuvan, P.; Rousse, G.; Vezin, H.; Tarascon, J. M.; Palacín, M. R. Titanium(Ⅲ) sulfate as new negative electrode for sodium-ion batteries. Chem. Mater. 2013, 25, 2391–2393.  doi: 10.1021/cm401181b

    26. [26]

      Mu, L.; Ben, L.; Hu, Y. S.; Li, H.; Chen, L.; Huang, X. Novel 1.5 V anode materials, ATiOPO4 (A = NH4, K, Na), for room-temperature sodium-ion batteries. J. Mater. Chem. A 2016, 4, 7141–7147.  doi: 10.1039/C6TA00891G

    27. [27]

      Chen, C.; Wen, Y.; Hu, X.; Ji, X.; Yan, M.; Mai, L.; Hu, P.; Shan, B.; Huang, Y. Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling. Nat. Commun. 2015, 6, 1–8.

    28. [28]

      Zhao, G.; Zhang, Y.; Yang, L.; Jiang, Y.; Zhang, Y.; Hong, W.; Tian, Y.; Zhao, H.; Hu, J.; Zhou, L.; Hou, H.; Ji, X.; Mai, L. Nickel chelate derived NiS2 decorated with bifunctional carbon: an efficient strategy to promote sodium storage performance. Adv. Funct. Mater. 2018, 28, 1803690.  doi: 10.1002/adfm.201803690

    29. [29]

      Zou, G.; Hou, H.; Foster, C. W.; Banks, C. E.; Guo, T.; Jiang, Y.; Zhang, Y.; Ji, X. Advanced hierarchical vesicular carbon co-doped with S, P, N for high-rate sodium storage. Adv. Sci. 2018, 5, 1800241.  doi: 10.1002/advs.201800241

    30. [30]

      Lindström, H.; Södergren, S.; Solbrand, A.; Rensmo, H.; Hjelm, J.; Hagfeldt, A.; Lindquist, S. E. Li+ ion insertion in TiO2 (anatase). 2. Voltammetry on nanoporous films. J. Phys. Chem. B 1997, 101, 7717–7722.  doi: 10.1021/jp970490q

    31. [31]

      Augustyn, V.; Come, J.; Lowe, M. A.; Kim, J. W.; Taberna, P. L.; Tolbert, S. H.; Abruna, H. D.; Simon, P.; Dunn, B. High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat. Mater. 2013, 12, 518–522.  doi: 10.1038/nmat3601

    32. [32]

      Xiao, Y.; Wang, P. F.; Yin, Y. X.; Zhu, Y. F.; Niu, Y. B.; Zhang, X. D.; Zhang, J.; Yu, X.; Guo, X. D.; Zhong, B. H.; Guo, Y. G. Exposing active facets by multiple-layer oriented stacking nanosheets for high-performance capacitive sodium-ion oxide cathode. Adv. Mater. 2018, 30, 1803765.  doi: 10.1002/adma.201803765

    33. [33]

      Gu, M.; Kushima, A.; Shao, Y.; Zhang, J. G.; Liu, J.; Browning, N. D.; Li, J.; Wang, C. Probing the failure mechanism of SnO2 nanowires for sodium-ion batteries. Nano Lett. 2013, 13, 5203–5211.  doi: 10.1021/nl402633n

    34. [34]

      Liu, Y.; Zhang, N.; Jiao, L.; Chen, J. Tin nanodots encapsulated in porous nitrogen-doped carbon nanofibers as a free-standing anode for advanced sodium-ion batteries. Adv. Mater. 2015, 27, 6702–6707.  doi: 10.1002/adma.201503015

    35. [35]

      Liu, J.; Kopold, P.; Wu, C.; van Aken, P. A.; Maier, J.; Yu, Y. Uniform yolk-shell Sn4P3@C nanospheres as high-capacity and cycle-stable anode materials for sodium-ion batteries. Energy Environ. Sci. 2015, 8, 3531–3538.  doi: 10.1039/C5EE02074C

    36. [36]

      Liang, L.; Xu, Y.; Wang, C.; Wen, L.; Fang, Y.; Mi, Y.; Zhou, M.; Zhao, H.; Lei, Y. Large-scale highly ordered sb nanorod array anodes with high capacity and rate capability for sodium-ion batteries. Energy Environ. Sci. 2015, 8, 2954–2962.  doi: 10.1039/C5EE00878F

    37. [37]

      Zhang, N.; Han, X.; Liu, Y.; Hu, X.; Zhao, Q.; Chen, J. 3D porous γ-Fe2O3@C nanocomposite as high-performance anode material of Na-ion batteries. Adv. Energy Mater. 2015, 5, 1401123.  doi: 10.1002/aenm.201401123

    38. [38]

      Sun, J.; Lee, H. W.; Pasta, M.; Yuan, H.; Zheng, G.; Sun, Y.; Li, Y.; Cui, Y. A phosphorene-graphene hybrid material as a high-capacity anode for sodium-ion batteries. Nat. Nanotechnol. 2015, 10, 980–985.  doi: 10.1038/nnano.2015.194

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