Citation: Yi-Fan DING, Fei LI, Jin-Xia YANG, Ye-Yan QIN, Yuan-Gen YAO. Study on the Synthesis and Properties of Metal-organic Complex Containing Samarium[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 851-856. doi: 10.14102/j.cnki.0254-5861.2011-3076 shu

Study on the Synthesis and Properties of Metal-organic Complex Containing Samarium

Yi-Fan DING ^{a, b} ,
Fei LI ^b ,
Jin-Xia YANG ^b ,
Ye-Yan QIN ^b ,
Yuan-Gen YAO ^{a, b,,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350116, China
b.
Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Yuan-Gen YAO, yyg@fjirasm.ac.cn
Received Date: 25 December 2020
Accepted Date: 26 February 2021

Figures(5)

A new rare earth organic complex with a double interleaved structure, namely [Sm(BDC)_1.5(DMF)(H₂O)]_n (H₂BDC = 1, 4-benzenedicarboxylic acid, DMF = N, N΄-dimethyl formamide) was synthesized. The crystal structure is of triclinic, space group P\begin{document}$ \overline 1 $\end{document} with a = 8.6343(6), b = 10.1470(5), c = 11.2073(6) Å, α = 65.495(5), β = 71.626(5), γ = 78.130(5)°, V = 844.70(9) Å³, C₁₅H₁₅NO₈Sm, M_r = 487.64, Z = 2, D_c = 1.917 g/cm³, F(000) = 476, μ = 3.519 mm^-1, R = 0.0380 and wR = 0.0864 for 3504 observed reflections (I > 2σ(I)). The structure has been determined by single-crystal X-ray diffraction analyses and displays a 2-fold interpenetrated 3D network with the classical pcu topology. The compound was analyzed by X-ray powder, infrared spectroscopy, thermogravimetric analysis and fluorescent spectroscopy. The fluorescent property makes it a good candidate for photoactive materials.
- samarium,
- fluorescent,
- earth organic compound
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