Citation: Lao-Bang WANG, Ji-Jiang WANG, Long TANG, Xiao WANG, Xiang-Yang HOU, Er-Lin YUE, Yu-Qi ZHANG. Two Co(Ⅱ) Complexes Constructed from 1-(3, 5-Dicarboxybenzyl)-3, 5-pyrazole Dicarboxylic Acid: Syntheses, Structures and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 885-891. doi: 10.14102/j.cnki.0254-5861.2011-3071 shu

Two Co(Ⅱ) Complexes Constructed from 1-(3, 5-Dicarboxybenzyl)-3, 5-pyrazole Dicarboxylic Acid: Syntheses, Structures and Magnetic Properties

Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an 716000, China

Corresponding author: Ji-Jiang WANG, yadxwjj@126.com Long TANG, ydtanglong@163.com
Received Date: 17 December 2020
Accepted Date: 10 March 2021

Fund Project: the National Natural Science Foundation of China 21373178

Figures(7)

Two new complexes [Co₂(L)(4, 4´-bip)(H₂O)₃]_n (1) and {[Co(L´)₂(phen)]·2H₂O)}_n (2) (H₄L = 1-(3, 5-dicarboxybenzyl)-3, 5-pyrazole dicarboxylic acid, H₃L´ = 1-(3, 5-dicarboxybenzyl)-3-pyrazole carboxylic acid, 4, 4´-bip = 4, 4´-bis(1-imidazolyl)biphenyl, phen = 1, 10-phenanthroline) were synthesized. Complexes 1 and 2 have been characterized by IR spectrography, X-ray single-crystal diffraction, elemental analysis and thermogravimetry. 1 crystallizes in monoclinic system, space group P2₁/c. Complex 2 crystallizes in monoclinic system, space group I2/a. It is remarkable that in situ hydrothermal decarboxylation was observed during preparing complex 2. In addition, magnetic analysis indicates that antiferromagnetic interaction exists among Co(Ⅱ) ions in complexes 1 and 2.
- Co(Ⅱ),
- 1-(3, 5-dicarboxybenzyl)-3, 5-pyrazole dicarboxylic acid,
- magnetic properties
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