Citation: Wei LI, Chang-Hong LI, Yu-Lin LI, Yun-Fei KUANG. Solvothermal Synthesis, Crystal Structure and Characterization of a New Binuclear Nickel(Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid[J]. Chinese Journal of Structural Chemistry, ;2021, 40(7): 878-884. doi: 10.14102/j.cnki.0254-5861.2011-3070 shu

Solvothermal Synthesis, Crystal Structure and Characterization of a New Binuclear Nickel(Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid

Wei LI ^a,, ,
Chang-Hong LI ^b,, ,
Yu-Lin LI ^a ,
Yun-Fei KUANG ^a

a.
School of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
b.
School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Corresponding author: Wei LI, li_weihnxy@163.com Chang-Hong LI, lichanghong4444@126.com
Received Date: 16 December 2020
Accepted Date: 5 January 2021

Fund Project: Natural Science Foundation of Hunan Province 2019JJ60021Industry and Research Key Project of Hengyang City 2019jhzx1093

Figures(7)

A new binuclear nickel(Ⅱ) complex [Ni₂(MBBA)₂(HPT)₂(H₂O)₂]·2H₂O (1) was synthesized with nickel hydroxide, 2-(4-methylbenzoyl)benzoic acid (HMBBA) and 3-(pyridin-2-yl)-1H-1, 2, 4-triazole (HPT). It crystallizes in the monoclinic space group P2₁/n with a = 14.5902(13), b = 8.8191(6), c = 17.6120(14) Å, β = 110.830(9)º, V = 2118.0(3) Å³, M_r = 958.26, D_c = 1.503 g/cm³, Z = 2, μ(MoKa) = 0.959, F(000) = 992, the final GOOF = 1.001, R = 0.0353 and wR = 0.09864. Each central Ni(Ⅱ) ion is coordinated by two oxygen and three nitrogen atoms, forming a distorted square pyramidal geometry. The XRD, TG, spectrum analysis and magnetic properties of 1 were studied.
- binuclear nickel(Ⅱ) complex,
- spectrum analysis,
- thermal stability,
- magnetic property
1. [1]
  (a) Jung, J.; Puget, M.; Cador, O.; Bernot, K.; Calzado, C.; Guennic, B. L. Analysis of the magnetic exchange interactions in yttrium(Ⅲ) complexes containing nitronyl nitroxide radicals. Inorg. Chem. 2017, 56, 6788–6801. (b) Sodpiban, O.; Del Gobbo, S.; Barman, S.; Aomchad, V.; Kidkhunthod, P.; Ould-Chikh, S.; Poater, A.; D Elia, V.; Basset, J. M. Synthesis of well-defined yttrium-based Lewis acids by capturing a reaction intermediate and catalytic application for cycloaddition of CO₂ to epoxides under atmospheric pressure. Catal. Sci. Technol. 2019, 9, 6152–6165. (c) Zhang, J. P.; Chen, X. M. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework. J. Am. Chem. Soc. 2008, 130, 6010–6017. (d) Li, X. X.; Gong, Y. Q.; Zhao, H. X. Anion-directed assemblies of cationic metal-organic frameworks based on 4, 4΄-bis(1, 2, 4-triazole): syntheses, structures, luminescent and anion exchange properties. Inorg. Chem. 2014, 53, 12127–12134.
2. [2]
  (a) Cui, L.; Luan, X. J.; Zhang, C. R.; Kang, Y. F.; Zhang, W. T.; Wang, Y. Y.; Shi, Q. Z. Four 3D "brick-wall"-like metal-organic frameworks with a flexible ligand of (S, S, R, R)-l, 2, 3, 4-cyclopentanetetra carboxylic acid: crystal structures, luminescent and magnetic properties. Dalton Trans. 2013, 42, 1637–1644. (b) Mohapatra, B.; Venkatesh, V.; Verma, S. Crystal engineering with 2-aminopurine containing a carboxylic acid pendant. Cryst. Growth Des. 2014, 14, 5042–5052.
3. [3]
  (a) Song, Y.; Yan, B.; Chen, Z. Synthesis and crystal structure of a novel luminescent zinc complex of 2-benzoylbenzoic acid. J. Cord. Chem. 2005, 58, 1417–1421. (b) Song, Y. S.; Yan, B.; Chen, Z. X. The crystal structures of tributyltin and triphenyltin esters of 2-benzoylbenzoic acid. Poly. 1995, 14, 2281–2285. (c) Li, W.; Li, C. H.; Yang, Y. Q.; Li, Y. L. Hydrothermal synthesis, crystal structure and thermal stability of binuclear cadmium complex with the o-methylbenzoyl-benzoic acid. Chin. J. Inorg. Chem. 2010, 26, 166–170.
4. [4]
  (a) Zhang, J. P.; Lin, Y. Y.; Huang, X. C.; Chen, X. M. Supramolecular isomerism within three-dimensional 3-connected nets: unusual synthesis and characterization of trimorphic copper(Ⅰ) 3, 5-dimethyl-1, 2, 4-triazolate. Dalton Trans. 2005, 22, 3681–3685. (b) Wu, X. X.; Wang, Y. Y.; Yang, P.; Xu, Y. Y.; Huo, J. Z.; Ding, B.; Wang, Y.; Wang, X. G. Syntheses, structural variation, and characterization of a series of crystalline coordination compounds with 4-benzene-1, 2, 4-triazole: polymorph, incomplete spin transition, and single crystal-to-single crystal transformation. Cryst. Growth Des. 2014, 14, 477−490. (c) Yang, Y.; Du, P.; Liu, Y. Y.; Ma, J. F. A series of coordination polymers constructed by flexible 4-substituted bis(1, 2, 4-triazole) ligands and polycarboxylate anions: syntheses, structures, and photoluminescent properties. Cryst. Growth Des. 2013, 13, 4781–4795. (d) Li, W.; Li, C. H.; Yang, Y. Q.; Li, H. F. Crystal structure, magnetic, fluorescent, electrochemical properties and thermal stability of a new copper(Ⅱ) coordination polymer [Cu₂(C₅H₄NCOO)₂(C₇H₅N₄)₂]_n. Z. Naturforschung, Section B 2015, 70, 215–219.
5. [5]
  (a) Fang, Z. Y.; Zhang, L.; Ma, J. P.; Zhao, L.; Wang, S. L.; Xie, N. H.; Liu, Y. Q.; Guo, X. Y.; Qin, J. Dinuclear cobalt and nickel complexes of a mercaptoacetic acid substituted 1, 2, 4-triazole ligand: syntheses, structures and urease inhibitory studies. Acta Cryst. Sect. C 2019, 75, 1658–1664. (b) Zhang, Y. J.; Yin, L.; Li, J.; Hu, Z. B.; Ouyang, Z. W.; Song, Y.; Wang, Z. X. Synthesis, crystal structures, HF-EPR, and magnetic properties of six-coordinate transition metal (Co, Ni, and Cu) compounds with a 4-amino-1, 2, 4-triazole Schiff-base ligand. RSC Advances 2020, 10, 12833–12840. (c) Liu, F. Y.; Zhou, D. M.; Zhao, X. L.; Kou, J. F. Complexes of nickel(Ⅱ) and copper(Ⅱ) with 1, 2, 4-triazole-3-carboxylic acid and of cobalt(Ⅲ) with 3-amino-1, 2, 4-triazole-5-carboxylic acid. Acta Cryst. Sect. C 2017, 73, 1010–1029. (d) Li, C. H.; Li, W.; Tan, X. W.; Li, Y. L. Hydrothermal synthesis, crystal structure and properties of one tetranuclear nickel(Ⅱ) complex with 3-(2-pyridiyl)-1H-1, 2, 4-triazole(Hpt). Chin. J. Struct. Chem. 2018, 37, 1004–1008. (e) Li, C. H.; Li, Y. L.; Li, W.; Kuang, Y. F. Hydrothermal synthesis, crystal structure and properties of a new binuclear nickel(Ⅲ) complex with 3-(pyridin-2-yl)-1, 2, 4-triazole. Chin. J. Struct. Chem. 2021, 40, 350–355.
6. [6]
  (a) Ratz, G. C.; Triazines, R. N. A new synthesis for 1, 2, 4-triazoles. J. Org. Chem. 1956, 21, 1037–1038. (b) Xu, Y. J.; McLaughlin, M.; Bolton, E. N.; Reamer, R. A. Practical synthesis of functionalized 1, 5-disubstituted 1, 2, 4-triazole derivatives. J. Org. Chem. 2010, 75, 8666–8669.
7. [7]
  Sheldrick, G. M. Program for Bruker Area Detector Absorption Correction. University of Göttingen: Göttingen, Germany 2015.
8. [8]
  Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of Göttingen: Göttingen, Germany 2015.
9. [9]
  Chen, X. M.; Cai, J. W. Principle and Practice of Single Crystal Structural Analysis. The first edition, Beijing, Science press 2004.
10. [10]
  Nakamota, K. Translated by Huang, D. R.; Wang, R. Q. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd edn. Beijing: Chemical Industry Press 1986.
11. [11]
  (a) Nagao, K.; Heiman, L. W.; Andrew, N.; Pave, J.; Clifford, C. L.; Hirofusa, S. Synthesis, spectroscopy, electrochemistry, spectroelectrochemistry, Langmuir-Blodgett film formation, and molecular orbital calculations of planar binuclear phthalocyanines. J. Am. Chem. Soc. 1994, 116, 879–890. (b) Liu, Y. Z.; Gao, H. Y.; Yi, X. G.; Li, D. P.; Li, Y. X. Crystal structures and DNA binding properties of 2-naphthoxyacetic acid Cu(Ⅱ) complexes. Chin. J. Struct. Chem. 2019, 38, 1362–16369. (c) Li, C. H.; Li, W.; Hu, H. X.; Jiang, M. L. Synthesis, crystal structure and fluorescent and thermal stability properties of the zinc(Ⅱ) complex [Zn(C₁₅H₁₁O₃)₂(C₁₂H₈N₂)₂]·5H₂O. Chin. J. Struct. Chem. 2014, 33, 947–951.
12. [12]
  (a) Li, Z. M.; Qiao, Y.; Liu, C. B.; Zhou, Y. F.; Wang, X. Y.; Charpentier, P. A.; Che, G. B.; Xu, W. Z.; Liu, L. H.; Zhu, E. W. Syntheses, crystal structures, adsorption properties and visible photocatalytic activities of highly stable Pb-based coordination polymers constructed by 2-(2-carboxyphenyl)imidazo(4, 5-f)-(1, 10)phenanthroline and bridging linkers. Dalton Trans. 2018, 47, 7761–7775. (b) Jiang, W.; Yang, J. Q.; Yan, G. S.; Zhou, S.; Liu, B.; Qiao, Y.; Zhou, T. Y.; Wang, J. J.; Che, G. B. A novel 3-fold interpenetrated dia metal-organic framework as a heterogeneous catalyst for CO₂ cycloaddition. Inorg. Chem. Comm. 2020, 113, 107770–107776.
13. [13]
  Feng, X.; Ma, L. F.; Wang, L. Y.; Zhao, J. S. A unique tetranuclear nickel(Ⅱ) complex containing pyridine-2-carboxaldehyde derivative bearing an intramolecular acetato: synthesis, crystal structure and magnetic property. Inorg. Chem. Comm. 2011, 14, 584–589.
14. [14]
  Ma, L. F.; Li, X. Q.; Wang, L. Y.; Hou, H. W. Syntheses and characterization of nickel(Ⅱ) and cobalt(Ⅱ) coordination polymers based on 5-bromoisophthalate anion and bis(imidazole) ligands. Cryst. Eng. Comm. 2011, 13, 4625–4634.
15. [15]
  (a) Lian, Q. Y.; Hu, H. N.; Li, C. H.; Li, D. P.; Jiao, X. Y.; Li, Y. X. A new tetranuclear cubane-like Ni(Ⅱ) complex based on Schiff-base ligand: synthesis, crystal structure and magnetic properties. Chin. J. Struct. Chem. 2017, 36, 273–279. (b) Yan, J. J.; Li, C. H.; Li, W.; Yang, Z. T.; Li, L.; Liu, H. B. Hydrothermal synthesis, crystal structure and properties of a new copper coordination polymer [Cu₂I(C₇H₅N₄)₂]_n with 3-(2-pyridiyl)-1, 2, 4-triazole Ligand. Chin. J. Struct. Chem. 2019, 38, 1823–1827. (c) Li, C. H.; Li, W.; Hu, H. X.; Hu, B. N. Hydrothermal synthesis, crystal structure, thermal stability and magnetic properties of dinuclear copper(Ⅱ) complex. Chin. J. Struct. Chem. 2015, 34, 1553–1557.
1. [1]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
4. [4]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
5. [5]
  Xueling Yu , Lixing Fu , Tong Wang , Zhixin Liu , Na Niu , Ligang Chen . Multivariate chemical analysis: From sensors to sensor arrays. Chinese Chemical Letters, 2024, 35(7): 109167-. doi: 10.1016/j.cclet.2023.109167
6. [6]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
7. [7]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
8. [8]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
9. [9]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
10. [10]
  Neng Shi , Haonan Jia , Jixiang Zhang , Pengyu Lu , Chenglong Cai , Yixin Zhang , Liqiang Zhang , Nongyue He , Weiran Zhu , Yan Cai , Zhangqi Feng , Ting Wang . Accurate expression of neck motion signal by piezoelectric sensor data analysis. Chinese Chemical Letters, 2024, 35(9): 109302-. doi: 10.1016/j.cclet.2023.109302
11. [11]
  Yuxin Li , Chengbin Liu , Qiuju Li , Shun Mao . Fluorescence analysis of antibiotics and antibiotic-resistance genes in the environment: A mini review. Chinese Chemical Letters, 2024, 35(10): 109541-. doi: 10.1016/j.cclet.2024.109541
12. [12]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
13. [13]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
14. [14]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
15. [15]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
16. [16]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
17. [17]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
18. [18]
  Tao LIU , Yuting TIAN , Ke GAO , Xuwei HAN , Ru'nan MIN , Wenjing ZHAO , Xueyi SUN , Caixia YIN . A photothermal agent with high photothermal conversion efficiency and high stability for tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1622-1632. doi: 10.11862/CJIC.20240107
19. [19]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
20. [20]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(201)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142