Citation: Hong-Hui TAN, Xiao-Long LV, Jiang-Long LIU, Yu-Fang CHENG, Qing-Lin ZHOU, Yi-Ting LIN, Wei MENG. A 2D Layer Copper(Ⅱ) Coordination Polymer with 3-Nitrophthalic Acid: Synthesis, Crystal Structure and Copper 3-Nitrophthalate Metal-organic Framework-graphene Oxide Nanocomposite[J]. Chinese Journal of Structural Chemistry, ;2021, 40(4): 459-464. doi: 10.14102/j.cnki.0254-5861.2011-2970 shu

A 2D Layer Copper(Ⅱ) Coordination Polymer with 3-Nitrophthalic Acid: Synthesis, Crystal Structure and Copper 3-Nitrophthalate Metal-organic Framework-graphene Oxide Nanocomposite

Department of Materials & Chemistry Engineering, Hunan City University, Yiyang 413000, China

Corresponding author: Wei MENG, mengw198503@163.com
Received Date: 28 August 2020
Accepted Date: 29 September 2020

Fund Project: the National Natural Science Foundation of China 22001064the Natural Science Foundation of Hunan Province 2020JJ4155the 2020 Hunan Province College Students' Innovation Entrepreneurship Training Program 3373the Scientific Research Project of Hunan Province Department of Education 20B105

Figures(4)

A 2D layer Cu(Ⅱ) coordination polymer [Cu(npth)(H₂O)]_n (1) was crystallized from a mixture of 3-nitrophthalic acid and Cu(OAc)₂·H₂O in water under room temperature and structurally characterized by single-crystal X-ray diffraction, FT-IR and TGA. Compound 1 was applied to make a nanocomposite with graphene oxide (GO). A highly dispersible and stable nanocomposite of Cu(npth)-GO was successfully synthesized by a simple ultrasonication method. SEM, TEM, UV-vis, FT-IR and TGA were used to characterize the morphology and structure of the prepared composite. In accordance with the characterization results, we suspected that the binding mechanism of Cu(npth) and GO was assigned to be the cooperative interaction of Cu–O coordination, π-π stacking and hydrogen bonding.
- copper 3-nitrophthalate metal-organic framework,
- crystal structure,
- graphene oxide,
- nanocomposite
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