Citation: Wan-Lu LI, Teng-Teng CHEN, Zhi-Yu JIAING, Lai-Sheng WANG, Jun LI. Recent Progresses in the Investigation of Rare-earth Boron Inverse Sandwich Clusters[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1009-1018. doi: 10.14102/j.cnki.0254-5861.2011-2891 shu

Recent Progresses in the Investigation of Rare-earth Boron Inverse Sandwich Clusters

Wan-Lu LI ^a ,
Teng-Teng CHEN ^b ,
Zhi-Yu JIAING ^a ,
Lai-Sheng WANG ^b,, ,
Jun LI ^{a, c,,}

a.
Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084, China
b.
Department of Chemistry, Brown University, Providence, Rhode Island 02912, USA
c.
Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

Corresponding author: Lai-Sheng WANG, lai-sheng_wang@brown.edu Jun LI, junli@tsinghua.edu.cn
Received Date: 28 May 2020
Accepted Date: 1 June 2020

Fund Project: the National Natural Science Foundation of China 91645203the National Natural Science Foundation of China 21433005the National Natural Science Foundation of China 21590792the experimental work done at Brown University was supported by the U.S. National Science Foundation CHE-1763380The support of Guangdong Provincial Key Laboratory of Catalysis 2020B121201002

Figures(8)

While rare-earth borides represent a class of important materials in modern industries, there are few fundamental researches on their electronic structures and physicochemical properties. Recently, we have performed combined experimental and theoretical studies on rare-earth boron clusters and their cluster-assembled complexes, revealing a series of rare-earth inverse sandwich clusters with fascinating electronic structures and chemical bonding patterns. In this overview article, we summarize recent progresses in this area and provide a perspective view on the future development of rare-earth boride clusters. Understanding the electronic structures of these clusters helps to design materials of f-element (lanthanide and actinide) borides with critical physiochemical properties.
- rare-earth boron clusters,
- inverse sandwich cluster compounds,
- f-element boride,
- bonding of rare-earth compounds
1. [1]
  Tang, A. C.; Li, Q. S.; Liu, C. W.; Li, J. Symmetrical clusters of carbon and boron. Chem. Phy. Lett. 1993, 5-6, 465-469.
2. [2]
  Zhai, H. J.; Kiran, B.; Li, J.; Wang, L. S. Hydrocarbon analogues of boron clusters-planarity, aromaticity and antiaromaticity. Nat. Mater. 2003, 2, 827–833. doi: 10.1038/nmat1012
3. [3]
  Alexandrova, A. N.; Boldyrev, A. I.; Zhai, H. J.; Wang, L. S.; Steiner, E.; Fowler, P. W. Structure and bonding in B₆^- and B₆: planarity and antiaromaticity. J. Phys. Chem. A 2003, 9, 1359–1369.
4. [4]
  Li, W.; Hu, H.; Zhao, Y.; Chen, X.; Chen, T.; Jian, T.; Wang, L.; Li, J. Recent progress on the investigations of boron clusters and boronbased materials(I): borophene. Sci. Sinica Chim. 2018, 2, 98–107.
5. [5]
  Li, W. L.; Chen, X.; Jian, T.; Chen, T. T.; Li, J.; Wang, L. S. From planar boron clusters to borophenes and metalloborophenes. Nat. Rev. Chem. 2017, 1, 71. doi: 10.1038/s41570-017-0071
6. [6]
  Sergeeva, A. P.; Popov, I. A.; Piazza, Z. A.; Li, W. L.; Romanescu, C.; Wang, L. S.; Boldyrev, A. I. Understanding boron through size-selected clusters: structure, chemical bonding, and fluxionality. Acc. Chem. Res. 2014, 4, 1349–1358.
7. [7]
  Boldyrev, A. I.; Wang, L. S. Beyond organic chemistry: aromaticity in atomic clusters. Phys. Chem. Chem. Phys. 2016, 17, 11589-11605.
8. [8]
  Wang, L. S. Photoelectron spectroscopy of size-selected boron clusters: from planar structures to borophenes and borospherenes. Int. Rev. Phys. Chem. 2016, 1, 69–142.
9. [9]
  Bai, H.; Chen, T. T.; Chen, Q.; Zhao, X. Y.; Zhang, Y. Y.; Chen, W. J.; Li, W. L.; Cheung, L. F.; Bai, B.; Cavanagh, J.; Huang, W.; Li, S. D.; Li, J.; Wang, L. S. Planar B₄₁⁻ and B₄₂⁻ clusters with double-hexagonal vacancies. Nanoscale 2019, 48, 23286–23295.
10. [10]
  Chen, Q.; Chen, T. T.; Li, H. R.; Zhao, X. Y.; Chen, W. J.; Zhai, H. J.; Li, S. D.; Wang, L. S. B₃₁⁻ and B₃₂⁻: chiral quasi-planar boron clusters. Nanoscale 2019, 19, 9698–9704.
11. [11]
  Li, W. L.; Chen, Q.; Tian, W. J.; Bai, H.; Zhao, Y. F.; Hu, H. S.; Li, J.; Zhai, H. J.; Li, S. D.; Wang, L. S. The B₃₅ cluster with a double-hexagonal vacancy: a new and more flexible structural motif for borophene. J. Am. Chem. Soc. 2014, 35, 12257–12260.
12. [12]
  Piazza, Z. A.; Hu, H. S.; Li, W. L.; Zhao, Y. F.; Li, J.; Wang, L. S. Planar hexagonal B₃₆ as a potential basis for extended single-atom layer boron sheets. Nat. Commun. 2014, 5, 3113. doi: 10.1038/ncomms4113
13. [13]
  Mannix, A. J.; Zhou, X. F.; Kiraly, B.; Wood, J. D.; Alducin, D.; Myers, B. D.; Liu, X.; Fisher, B. L.; Santiago, U.; Guest, J. R.; Yacaman, M. J.; Ponce, A.; Oganov, A. R.; Hersam, M. C.; Guisinger, N. P. Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs. Science 2015, 6267, 1513–1516.
14. [14]
  Feng, B.; Zhang, J.; Zhong, Q.; Li, W.; Li, S.; Li, H.; Cheng, P.; Meng, S.; Chen, L.; Wu, K. Experimental realization of two-dimensional boron sheets. Nat. Chem. 2016, 6, 564–569.
15. [15]
  Zhai, H. J.; Zhao, Y. F.; Li, W. L.; Chen, Q.; Bai, H.; Hu, H. S.; Piazza, Z. A.; Tian, W. J.; Lu, H. G.; Wu, Y. B.; Mu, Y. W.; Wei, G. F.; Liu, Z. P.; Li, J.; Li, S. D.; Wang, L. S. Observation of an all-boron fullerene. Nat. Chem. 2014, 8, 727–731.
16. [16]
  Chen, Q.; Li, W. L.; Zhao, Y. F.; Zhang, S. Y.; Hu, H. S.; Bai, H.; Li, H. R.; Tian, W. J.; Lu, H. G.; Zhai, H. J.; Li, S. D.; Li, J.; Wang, L. S. Experimental and theoretical evidence of an axially chiral borospherene. ACS Nano. 2015, 1, 754–760.
17. [17]
  Jian, T.; Chen, X.; Li, S. D.; Boldyrev, A. I.; Li, J.; Wang, L. S. Probing the structures and bonding of size-selected boron and doped-boron clusters. Chem. Soc. Rev. 2019, 13, 3550–3591.
18. [18]
  Zhai, H. J.; Wang, L. S.; Alexandrova, A. N.; Boldyrev, A. I. Electronic structure and chemical bonding of B₅⁻ and B₅ by photoelectron spectroscopy and ab initio calculations. J. Chem. Phys. 2002, 17, 7917–7924.
19. [19]
  Alexandrova, A. N.; Boldyrev, A. I.; Zhai, H. J.; Wang, L. S.; Steiner, E.; Fowler, P. W. Structure and bonding in B₆⁻ and B₆: planarity and antiaromaticity. J. Phys. Chem. A 2003, 9, 1359–1369.
20. [20]
  Zhai, H. J.; Alexandrova, A. N.; Birch, K. A.; Boldyrev, A. I.; Wang, L. S. Hepta‐and octacoordinate boron in molecular wheels of eight‐and nine‐atom boron clusters: observation and confirmation. Angew. Chem. Int. Ed. 2003, 48, 6004–6008.
21. [21]
  Li, W. L.; Zhao, Y. F.; Hu, H. S.; Li, J.; Wang, L. S. [B₃₀]: a quasiplanar chiral boron cluster". Angew. Chem. Int. Ed. 2014, 53, 5540–5545. doi: 10.1002/anie.201402488
22. [22]
  Zhai, H. J.; Wang, L. S.; Alexandrova, A. N.; Boldyrev, A. I.; Zakrzewski, V. G. Photoelectron spectroscopy and ab initio study of B₃^- and B₄^- anions and their neutrals. J. Phys. Chem. A 2003, 44, 9319–9328.
23. [23]
  Alexandrova, A. N.; Boldyrev, A. I.; Zhai, H. J.; Wang, L. S. Electronic structure, isomerism, and chemical bonding in B₇⁻ and B₇. J. Phys. Chem. A 2004, 16, 3509–3517.
24. [24]
  Dennington, R.; Keith, T.; Millam, J. GaussView, version 4.1; Semichem, Inc., Shawnee Mission, KS 2007.
25. [25]
  Chung, H. Y.; Weinberger, M. B.; Levine, J. B.; Kavner, A.; Yang, J. M.; Tolbert, S. H.; Kaner, R. B. Synthesis of ultra-incompressible superhard rhenium diboride at ambient pressure. Science 2007, 5823, 436–439.
26. [26]
  Carenco, S.; Portehault, D.; Boissière, C.; Mézailles, N.; Sanchez, C. Nanoscaled metal borides and phosphides: recent developments and perspectives. Chem. Rev. 2013, 10, 7981–8065.
27. [27]
  Sussardi, A.; Tanaka, T.; Khan, A. U.; Schlapbach, L.; Mori, T. Enhanced thermoelectric properties of samarium boride. J. Materiomics 2015, 3, 196–204.
28. [28]
  Scheifers, J. P.; Zhang, Y.; Fokwa, B. P. T. Boron: enabling exciting metal-rich structures and magnetic properties. Acc. Chem. Res. 2017, 9, 2317–2325.
29. [29]
  Akopov, G.; Yeung, M. T.; Kaner, R. B. Rediscovering the crystal chemistry of borides. Adv. Mater. 2017, 21, 1604506.
30. [30]
  Paderno, Y. B.; Pokrzywnicki, S.; Staliński, B. Magnetic properties of some rare earth hexaborides. Phys. Status Solidi b-Basic Res. 1967, 1, K73–K76.
31. [31]
  Geballe, T. H.; Matthias, B. T.; Andres, K.; Maita, J. P.; Cooper, A. S.; Corenzwit, E. Magnetic ordering in the rare-earth hexaborides. Science 1968, 3835, 1443–1444.
32. [32]
  Zhitomirsky, M. E.; Rice, T. M.; Anisimov, V. I. Ferromagnetism in the hexaborides. Nature 1999, 6759, 251–253.
33. [33]
  Mori, T. Thermoelectric and magnetic properties of rare earth borides: boron cluster and layered compounds. J. Solid State Chem. 2019, 70–82.
34. [34]
  Pyykkö, P. Dirac-Fock One-centre calculations part 8. The¹Σ states of ScH, YH, LaH, AcH, TmH, LuH and LrH. Physica Scripta 1979, 5-6, 647–651.
35. [35]
  Kaupp, M. The role of radial nodes of atomic orbitals for chemical bonding and the periodic table. J. Comput. Chem. 2007, 1, 320–325.
36. [36]
  Tang, Y.; Zhao, S.; Long, B.; Liu, J. C.; Li, J. On the nature of support effects of metal dioxides MO₂ (M = Ti, Zr, Hf, Ce, Th) in single-atom gold catalysts: importance of quantum primogenic effect. J. Phys. Chem. C 2016, 31, 17514–17526.
37. [37]
  Lu, J. B.; Cantu, D. C.; Nguyen, M. T.; Li, J.; Glezakou, V. A.; Rousseau, R. Norm-conserving pseudopotentials and basis sets to explore lanthanide chemistry in complex environments. J. Chem. Theory Comput. 2019, 11, 5987–5997.
38. [38]
  Takao Mori: encyclopedia of inorganic and bioinorganic chemistry. John Wiley & Sons, Ltd: Online 2012, DOI: 10.1002/9781119951438.eibc2028.
39. [39]
  Chen, X.; Chen, T. T.; Li, W. L.; Lu, J. B.; Zhao, L. J.; Jian, T.; Hu, H. S.; Wang, L. S.; Li, J. Lanthanides with unusually low oxidation states in the PrB₃^- and PrB₄^- boride clusters. Inorg. Chem. 2019, 1, 411–418.
40. [40]
  Robinson, P. J.; Zhang, X.; McQueen, T.; Bowen, K. H.; Alexandrova, A. N. SmB₆ cluster anion: covalency involving f orbitals. J. Phys. Chem. A 2017, 8, 1849–1854.
41. [41]
  Chen, T. T.; Li, W. L.; Jian, T.; Chen, X.; Li, J.; Wang, L. S. PrB₇^-: a praseodymium-doped boron cluster with a Pr^Ⅱ center coordinated by a doubly aromatic planar η⁷-B₇^3- ligand. Angew. Chem. Int. Ed. 2017, 24, 6916–6920.
42. [42]
  Li, W. L.; Chen, T. T.; Xing, D. H.; Chen, X.; Li, J.; Wang, L. S. Observation of highly stable and symmetric lanthanide octa-boron inverse sandwich complexes. Proc. Natl. Acad. Sci. USA 2018, 30, E6972–E6977.
43. [43]
  Chen, T. T.; Li, W. L.; Li, J.; Wang, L. S. [La(η^x-B_x)La]⁻ (x = 7~9): a new class of inverse sandwich complexes. Chem. Sci. 2019, 8, 2534–2542.
44. [44]
  Chen, T. T.; Li, W. L.; Chen, W. J.; Li, J.; Wang, L. S. La₃B₁₄⁻: an inverse triple-decker lanthanide boron cluster. Chem. Commun. 2019, 54, 7864–7867.
45. [45]
  Duff, A. W.; Jonas, K.; Goddard, R.; Kraus, H. J. and Krueger, C. The first triple-decker sandwich with a bridging benzene ring. J. Am. Chem. Soc. 1983, 5479–5480.
46. [46]
  Schier, A.; Wallis, J. M.; Müller, G.; Schmidbaur, H. [C₆H₃(CH₃)₃][BiCl₃] and [C₆(CH₃)₆][BiCl₃]₂, arene complexes of bismuth with half-sandwich and "inverted" sandwich structures. Angew. Chem. Int. Ed. Engl. 1986, 8, 757–759.
47. [47]
  Streitwieser, A.; Smith, K. A. Inverse sandwich compounds. J. Mol. Struct. Theochem. 1988, 259–265.
48. [48]
  Arliguie, T.; Lance, M.; Nierlich, M.; Vigner, J.; Ephritikhine, M. Inverse cycloheptatrienyl sandwich complexes. Crystal structure of [U(BH₄)₂(OC₄H₈)₅][(BH₄)₃U(μ-η⁷, η⁷-C₇H₇)U(BH₄)₃]. J. Chem. Soc., Chem. Commun. 1994, 7, 847–848.
49. [49]
  Krieck, S.; Görls, H.; Yu, L.; Reiher, M.; Westerhausen, M. Stable "inverse" sandwich complex with unprecedented organocalcium(I): crystal structures of [(thf)₂Mg(Br)-C₆H₂-2, 4, 6-Ph₃] and [(thf)₃Ca{μ-C₆H₃-1, 3, 5-Ph₃}Ca(thf)₃]. J. Am. Chem. Soc. 2009, 8, 2977–2985.
50. [50]
  Diaconescu, P. L.; Arnold, P. L.; Baker, T. A.; Mindiola, D. J.; Cummins, C. C. Arene-bridged diuranium complexes: inverted sandwiches supported by δ backbonding. J. Am. Chem. Soc. 2000, 25, 6108–6109.
51. [51]
  Li, J.; Liu, C. W.; Lu, J. X. Quantum chemical studies on the bonding characteristics of some M₃X₄ transition-metal halogenide clusters. J. Cluster Sci. 1994, 505–521.
52. [52]
  Li, J.; Liu, C. W.; Lu, J. X. Abinitio studies on the electronic-structures of certain 10-π-electron 6-membered ring compounds. J. Mol. Struct. Theochem. 1993, 2-3, 223–231.
53. [53]
  Zubarev, D. Y.; Boldyrev, A. I. Developing paradigms of chemical bonding: adaptive natural density partitioning. Phys. Chem. Chem. Phys. 2008, 34, 5207–5217.
54. [54]
  Li, W. L.; Chen, T. T.; Xing, D. H.; Chen, X.; Li, J.; Wang, L. S. Observation of highly stable and symmetric lanthanide octa-boron inverse sandwich complexes. Proc. Natl. Acad. Sci. USA 2018, 30, E6972–E6977.
55. [55]
  Li, W. L.; Ertural, C.; Bogdanovski, D.; Li, J.; Dronskowski, R. Chemical bonding of crystalline LnB₆ (Ln = LaLu) and its relationship with Ln₂B₈ gas-phase complexes. Inorg. Chem. 2018, 20, 12999–13008.
56. [56]
  Wyckoff, R. W. G. : The Structure of Crystals. Chemical Catalog Company 1924.
57. [57]
  Lu, J. X.; Zhuang, B. T. A unit conrstruction approach to the rational synthese of transition metal cabane-lake clusters by the use of reactive fragments as buioding blocks. Chin. J. Struct. Chem. 1989, 04, 233–248.
58. [58]
  Cao, C. S.; Hu, H. S.; Li, J.; Schwarz, W. H. E. Physical origin of chemical periodicities in the system of elements. Pure and Appl. Chem. 2019, 12, 1969–1999.
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