Citation: Wan-Lu LI, Teng-Teng CHEN, Zhi-Yu JIAING, Lai-Sheng WANG, Jun LI. Recent Progresses in the Investigation of Rare-earth Boron Inverse Sandwich Clusters[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1009-1018. doi: 10.14102/j.cnki.0254-5861.2011-2891 shu

Recent Progresses in the Investigation of Rare-earth Boron Inverse Sandwich Clusters

Wan-Lu LI ^a ,
Teng-Teng CHEN ^b ,
Zhi-Yu JIAING ^a ,
Lai-Sheng WANG ^b,, ,
Jun LI ^{a, c,,}

a.
Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084, China
b.
Department of Chemistry, Brown University, Providence, Rhode Island 02912, USA
c.
Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

Corresponding author: Lai-Sheng WANG, lai-sheng_wang@brown.edu Jun LI, junli@tsinghua.edu.cn
Received Date: 28 May 2020
Accepted Date: 1 June 2020

Fund Project: the National Natural Science Foundation of China 91645203the National Natural Science Foundation of China 21433005the National Natural Science Foundation of China 21590792the experimental work done at Brown University was supported by the U.S. National Science Foundation CHE-1763380The support of Guangdong Provincial Key Laboratory of Catalysis 2020B121201002

Figures(8)

While rare-earth borides represent a class of important materials in modern industries, there are few fundamental researches on their electronic structures and physicochemical properties. Recently, we have performed combined experimental and theoretical studies on rare-earth boron clusters and their cluster-assembled complexes, revealing a series of rare-earth inverse sandwich clusters with fascinating electronic structures and chemical bonding patterns. In this overview article, we summarize recent progresses in this area and provide a perspective view on the future development of rare-earth boride clusters. Understanding the electronic structures of these clusters helps to design materials of f-element (lanthanide and actinide) borides with critical physiochemical properties.
- rare-earth boron clusters,
- inverse sandwich cluster compounds,
- f-element boride,
- bonding of rare-earth compounds
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