Citation: Ying-Qun YANG, Wei LI, Pin-Fang YANG, Yun-Fei KUANG. Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb2(C15H11O3)6(phen)2[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1087-1092. doi: 10.14102/j.cnki.0254-5861.2011-2799 shu

Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb2(C15H11O3)6(phen)2

  • Corresponding author: Ying-Qun YANG, yingqunyq@163.com Wei LI, li_weihnxy@163.com Yun-Fei KUANG, 943336711@qq.com
  • Received Date: 9 March 2020
    Accepted Date: 27 April 2020

    Fund Project: the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province, the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Natural Science Foundation of Hunan Province 2019JJ60021the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province, the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Natural Science Foundation of Hunan Province 2019JJ50013the Scientific Research Found of Hunan Provincial Education Department of China 17A049Industry and Research Key Project of Hengyang City 2018kKJ016Industry and Research Key Project of Hengyang City 2017KJ155Industry and Research Key Project of Hengyang City 2017KJ193

Figures(4)

  • A new terbium(Ⅲ) complex Tb2(C15H11O3)6(phen)2 has been synthesized with 2-(4-methylben-zoyl)benzoic acid and 1, 10-phenanthroline as ligands. Crystal data for the complex are as follows: monoclinic, space group P21/n, a = 15.0786(6), b = 13.5762(5), c = 22.9683(9) Å, β = 104.130(4)º, V = 4559.6(3) Å3, Dc = 1.540 g/cm3, Z = 2, μ(Mo) = 1.615 mm–1, F(000) = 2136, the final R = 0.0528 and wR = 0.0740. The Tb(Ⅲ) ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The complex shows four fluorescence emission bands arising from the transitions of Tb3+: 5D47F6 (490 nm), 5D47F5 (546 nm), 5D47F4 (588 nm) and 5D47F3 (622 nm). The complex is an antiferromagnet in the range of 300~2 K. Also reported in the paper is the thermal stability property of the title complex.
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