Citation: Ying-Qun YANG, Wei LI, Pin-Fang YANG, Yun-Fei KUANG. Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb₂(C₁₅H₁₁O₃)₆(phen)₂[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1087-1092. doi: 10.14102/j.cnki.0254-5861.2011-2799 shu

Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb₂(C₁₅H₁₁O₃)₆(phen)₂

Ying-Qun YANG ^{a, b,,} ,
Wei LI ^{a, b,,} ,
Pin-Fang YANG ^b ,
Yun-Fei KUANG ^{a, b,,}

a.
Key Laboratory of Functional Metal-organic Compounds of Hunan Province & Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Hengyang 421008, China
b.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

Corresponding author: Ying-Qun YANG, yingqunyq@163.com Wei LI, li_weihnxy@163.com Yun-Fei KUANG, 943336711@qq.com
Received Date: 9 March 2020
Accepted Date: 27 April 2020

Fund Project: the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province, the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Natural Science Foundation of Hunan Province 2019JJ60021the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province, the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province, Natural Science Foundation of Hunan Province 2019JJ50013the Scientific Research Found of Hunan Provincial Education Department of China 17A049Industry and Research Key Project of Hengyang City 2018kKJ016Industry and Research Key Project of Hengyang City 2017KJ155Industry and Research Key Project of Hengyang City 2017KJ193

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A new terbium(Ⅲ) complex Tb₂(C₁₅H₁₁O₃)₆(phen)₂ has been synthesized with 2-(4-methylben-zoyl)benzoic acid and 1, 10-phenanthroline as ligands. Crystal data for the complex are as follows: monoclinic, space group P2₁/n, a = 15.0786(6), b = 13.5762(5), c = 22.9683(9) Å, β = 104.130(4)º, V = 4559.6(3) Å³, D_c = 1.540 g/cm³, Z = 2, μ(MoKα) = 1.615 mm^–1, F(000) = 2136, the final R = 0.0528 and wR = 0.0740. The Tb(Ⅲ) ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The complex shows four fluorescence emission bands arising from the transitions of Tb³⁺: ⁵D₄ → ⁷F₆ (490 nm), ⁵D₄ → ⁷F₅ (546 nm), ⁵D₄ → ⁷F₄ (588 nm) and ⁵D₄ → ⁷F₃ (622 nm). The complex is an antiferromagnet in the range of 300~2 K. Also reported in the paper is the thermal stability property of the title complex.
- terbium(Ⅲ) complex,
- crystal structure,
- fluorescence and magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis, Structure and Properties of a New Terbium(Ⅲ) Complex Tb₂(C₁₅H₁₁O₃)₆(phen)₂