Citation: Zhe AN, Jun-Jiang TENG. A 3D Supramolecular Cu(Ⅰ) Compound Obtained by in situ Hydrolysis, Deaminization, Reduction and Self-assemble Reaction[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1735-1739. doi: 10.14102/j.cnki.0254-5861.2011-2697 shu

A 3D Supramolecular Cu(Ⅰ) Compound Obtained by in situ Hydrolysis, Deaminization, Reduction and Self-assemble Reaction

Zhe AN ,
Jun-Jiang TENG ^,

School of Chemistry, Guangdong University of Petrochemical Technology, Maoming 525000, China

Corresponding author: Jun-Jiang TENG, junjiangteng@163.com
Received Date: 11 December 2019
Accepted Date: 4 March 2020

Fund Project:

Figures(3)

A new Cu(Ⅰ) coordination polymer, [Cu₄(MA)₂(HCA)₂]_n (1, MA = melamine, H₃CA = cyanuric acid), has been synthesized under hydrothermal conditions using CuCl₂·2H₂O and MA as the starting materials. Interestingly, cyanuric acid was obtained by the in situ hydrolysis and the deaminization of melamine, and the Cu(Ⅰ) ion was obtained by the in situ reduction of Cu(Ⅱ) ion during the self-assembly process. The crystal structure is of monoclinic, space group P_c with a = 3.539(3), b = 22.377(2), c = 15.844(1) Å, β = 90.723(1)º, V = 1254.6(2) Å³, C₁₂H₁₄Cu₄N₁₈O₆, M_r = 760.61, Z = 2, D_c = 2.013 g/cm³, F(000) = 752, μ = 3.426 mm^-1, R = 0.0479 and wR = 0.1243 for 3172 observed reflections (I > 2σ(I)). The crystal structural analysis revealed that the cooperation of coordinate-covalent bonds, intermolecular hydrogen bonds and π-π interactions give rise to a 3D supramolecular framework with 5-connected BN topology. Moreover, the thermal stability and luminescent property of 1 were also investigated.
- Cu(Ⅰ),
- solvothermal synthesis,
- supramolecular framework,
- luminescent property
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