Citation: Zhao-Hao LI, Yu-Xuan ZHOU, Yuan-Yuan NI. Synthesis, Crystal Structure, and Photoluminescent Property of a 2-Fold Interpenetrating Znic(Ⅱ) Coordination Polymer with 2,5-Dicarboxylic Acid-3,4-ethylene Dioxythiophene[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1729-1734. doi: 10.14102/j.cnki.0254-5861.2011-2691 shu

Synthesis, Crystal Structure, and Photoluminescent Property of a 2-Fold Interpenetrating Znic(Ⅱ) Coordination Polymer with 2,5-Dicarboxylic Acid-3,4-ethylene Dioxythiophene

College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang 471934, China

Corresponding author: Zhao-Hao LI, lylizh@126.com
Received Date: 7 December 2019
Accepted Date: 18 February 2020

Fund Project: the NNSFC 21671094

Figures(5)

A three-dimensional coordination polymer, [Zn₂(L)₂(bpp)(H₂O)₂]_n (H₂L = 2,5-dicarboxylic acid-3,4-ethylene dioxythiophene, bpp = 1,3-di(4-pyridyl)propane), was synthesized with high yield under solvothermal reaction conditions and structurally characterized by elemental analysis, infrared spectra, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction analysis. It crystallizes in orthorhombic space group Pnma with a = 16.6542(9), b = 18.0868(10), c = 10.7528(5) Å, V = 3239.0(3) Å³, Z = 4, D_c = 1.684 g/cm³, M_r = 821.38, D_c = 1.684 g/cm³, µ = 1.683 mm⁻¹, F(000) = 1672, R = 0.0466, wR = 0.0933 and S = 1.066. The compound exhibits a three-dimensional structure, which can be simplified into a 2-fold interpenetrated pcu topological network. Moreover, it displays luminescence emission in the solid state at room temperature.
- coordination polymer,
- 2,5-dicarboxylic acid-3,4-ethylene dioxythiophene,
- 1,3-bis(4-pyridyl)propane,
- crystal structure,
- photoluminescent property
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