Citation: Jian-Mei HU, Yong WANG. Synthesis and Characterization of the cis-Dicyanoiron(Ⅱ) Building Block and Its Interactions with Selected Metal Ions[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1714-1722. doi: 10.14102/j.cnki.0254-5861.2011-2666 shu

Synthesis and Characterization of the cis-Dicyanoiron(Ⅱ) Building Block and Its Interactions with Selected Metal Ions

Jian-Mei HU ,
Yong WANG ^,

Hubei Key Laboratory of Drug Synthesis and Optimization, Medical Innovation Research Institute, Jingchu University of Technology, Jingmen, Hubei 444800, China

Corresponding author: Yong WANG, wangyong198711@yahoo.com
Received Date: 9 November 2019
Accepted Date: 13 February 2020

Fund Project: the Science and Technology Research Project of Hubei Provincial Department of Education Q20194301the Cultivating Scientific Research Project of Jingchu University of Technology PY201901the Third Batch of Hubei Provincial Youth Talent Development Plan Project QNYC201901

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In this work, a cis-dicyanoiron(Ⅱ) building block, cis-Fe^Ⅱ(bpy)₂(CN)₂ (1, bpy = 2,2΄-bipyridine), has been prepared and fully characterized by IR, electronic absorption spectra, elemental analysis, cyclic voltammetry and single-crystal X-ray diffraction analysis. The interactions of complex 1 with selected metal ions, such as Cu(Ⅱ), Fe(Ⅲ), Pb(Ⅱ), Fe(Ⅱ), Cr(Ⅲ), Cd(Ⅱ), Co(Ⅱ), Zn(Ⅱ), Ni(Ⅱ) and Mn(Ⅱ), were investigated employing electronic absorption spectroscopy. The electronic absorption spectroscopy indicates Cu(Ⅱ), Fe(Ⅲ), Cr(Ⅲ), Cd(Ⅱ), Co(Ⅱ), Zn(Ⅱ) and Ni(Ⅱ) ions steadily coordinate with 1 via cyanide, respectively. Fluorescent emission intensity of 1 increased upon the addition of Zn(Ⅱ) ion, quenched by adding ions Cu(Ⅱ), Fe(Ⅲ) and Pb(Ⅱ), and it was almost unchanged when adding the Fe(Ⅱ), Cr(Ⅲ), Cd(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Mn(Ⅱ) ions.
- cyanide,
- iron(Ⅱ),
- molecular structure,
- electronic absorption spectroscopy,
- fluorescent spectroscopy
1. [1]
  Das, S.; Rissanen, K.; Sahoo, P. Rare crystal structure of open spirolactam ring along with the closed-ring form of a rhodamine derivative: sensing of Cu²⁺ ions from spinach. ACS Omega 2019, 4, 5270–5274. doi: 10.1021/acsomega.9b00053
2. [2]
  Zhang, C.; Yan, Y.; Pan, Q.; Sun, L.; He, H.; Liu, Y.; Liang, Z.; Li, J. A microporous lanthanum metal-organic framework as a bi-functional chemosensor for the detection of picric acid and Fe³⁺ ions. Dalton Trans. 2015, 44, 13340–13346. doi: 10.1039/C5DT01065A
3. [3]
  Gaggelli, E.; Kozlowski, H.; Valensin, D.; Valensin, G. Copper homeostasis and neurodegenerative disorders (Alzheimer's, Prion, and Parkinson's diseases and amyotrophic lateral sclerosis). Chem. Rev. 2006, 106, 1995–2044. doi: 10.1021/cr040410w
4. [4]
  Shabani, A. M. H.; Dadfarnia, S.; Dehghani, Z. On-line solid phase extraction system using 1,10-phenanthroline immobilized on surfactant coated alumina for the flame atomic absorption spectrometric determination of copper and cadmium. Talanta 2009, 79, 1066–1070. doi: 10.1016/j.talanta.2009.02.008
5. [5]
  Zhang, J. F.; Zhou, Y.; Yoon, J.; Kim, J. S. Recent progress in fluorescent and colorimetric chemosensors for detection of precious metal ions (silver, gold and platinum ions). Chem. Soc. Rev. 2011, 40, 3416–3429. doi: 10.1039/c1cs15028f
6. [6]
  Si, H.; Sheng, R.; Li, Q.; Feng, J.; Li, L.; Tang, B. Highly sensitive fluorescence imaging of Zn²⁺ and Cu²⁺ in living cells with signal amplification based on functional DNA self-assembly. Anal. Chem. 2018, 90, 8785–8792. doi: 10.1021/acs.analchem.7b05268
7. [7]
  Gabr, M. T.; Pigge, F. C. A fluorescent turn-on probe for cyanide anion detection based on an AIE active cobalt(Ⅱ) complex. Dalton Trans. 2018, 47, 2079–2085. doi: 10.1039/C7DT04242F
8. [8]
  Zhu, X. D.; Zhang, K.; Wang, Y.; Long, W. W.; Sa, R. J.; Liu, T. F.; Lü, J. Fluorescent metal-organic framework (MOF) as a highly sensitive and quickly responsive chemical sensor for the detection of antibiotics in simulated wastewater. Inorg. Chem. 2018, 57, 1060–1065. doi: 10.1021/acs.inorgchem.7b02471
9. [9]
  Griesbeck, S.; Michail, E.; Wang, C.; Ogasawara, H.; Lorenzen, S.; Gerstner, L.; Zang, T.; Nitsch, J.; Sato, Y.; Bertermann, R.; Taki, M.; Lambert, C.; Yamaguchi, S.; Marder, T. B. Tuning the π-bridge of quadrupolar triarylborane chromophores for one- and two-photon excited fluorescence imaging of lysosomes in live cells. Chem. Sci. 2019, 10, 5405–5422 doi: 10.1039/C9SC00793H
10. [10]
  Bhalla, V.; Tejpal, R.; Kumar, M.; Puri, R. K.; Mahajan, R. K. Terphenyl based 'turn on΄fluorescent sensor for mercury. Tetra. Lett. 2009, 50, 2649–2652. doi: 10.1016/j.tetlet.2009.03.110
11. [11]
  Chorazy, S.; Wang, J.; Ohkoshi, S. I. Yellow to greenish-blue colour-tunable photoluminescence and 4f-centered slow magnetic relaxation in a cyanido-bridged Dy^Ⅲ(4-hydroxypyridine)-Co^Ⅲ layered material. Chem. Commun. 2016, 52, 10795–10798. doi: 10.1039/C6CC05337H
12. [12]
  Barthelmes, K.; Jäger, M.; Kübel, J.; Friebe, C.; Winter, A.; Wächtler, M.; Dietzek, B.; Schubert, U. S. Efficient energy transfer and metal coupling in cyanide-bridged heterodinuclear complexes based on (bipyridine)(terpyridine)ruthenium(Ⅱ) and (phenylpyridine)iridium(Ⅲ) complexes. Inorg. Chem. 2016, 55, 5152–5167. doi: 10.1021/acs.inorgchem.5b02919
13. [13]
  Büldt, L. A.; Guo, X.; Vogel, R.; Prescimone, A.; Wenger, O. S. A tris(diisocyanide)chromium(0) complex is a luminescent analog of [Fe(2, 2΄-bipyridine)₃]²⁺. J. Am. Chem. Soc. 2017, 139, 985–992. doi: 10.1021/jacs.6b11803
14. [14]
  Comte, V.; Vahrenkamp, H. Cyanide bridged oligonuclear complexes containing CuCl and CuCl₂. J. Organomet. Chem. 2001, 627, 153–158. doi: 10.1016/S0022-328X(01)00739-2
15. [15]
  Qin, Z. T.; Sheng, T. L.; Hu, S. M.; Xiang, S. C.; Fu, R. B.; Wang, X.; Shen, C. J.; Wu, X. T. Design, synthesis and crystal structure of two one-dimensional zigzag chain-like compounds. Chin. J. Struc. Chem. 2008, 27, 1013–1019.
16. [16]
  Sheldrick, G. M. Program for X-ray Crystal Structure Refinement. University of Göttingen: Germany 2016.
17. [17]
  Anderson, K. M.; Orpen, A. G. On the relative magnitudes of cis and trans influences in metal complexes. Chem. Commun. 2001, 2682–2683.
18. [18]
  Ma, B. Q.; Sun, H. L.; Gao, S. Vertex-sharing water tape consisting of cyclic hexamers. Eur. J. Inorg. Chem. 2005, 2005, 3902–3906. doi: 10.1002/ejic.200500374
19. [19]
  Wang, Y.; Ma, X.; Hu, S. M.; Wen, Y. H.; Xue, Z. Z.; Zhu, X. Q.; Zhang, X. D.; Sheng, T. L.; Wu, X. T. Syntheses, crystal structures, MMCT and magnetic properties of four one-dimensional cyanide-bridged complexes comprised of M^Ⅱ-CN-Fe^Ⅲ (M = Fe, Ru, Os). Dalton Trans. 2014, 43, 17453–17462. doi: 10.1039/C4DT02272F
20. [20]
  Hunter, C. A.; Sanders, J. K. M. The nature of. π-π interactions. J. Am. Chem. Soc. 1990, 112, 5525–5534. doi: 10.1021/ja00170a016
21. [21]
  Główka, M. L.; Martynowski, D.; Kozłowska, K. Stacking of six-membered aromatic rings in crystals. J. Mol. Struct. 1999, 474, 81–89. doi: 10.1016/S0022-2860(98)00562-6
22. [22]
  Wang, Y.; Ma, X.; Hu, S. M.; Xue, Z. Z.; Wen, Y. H.; Sheng, T. L.; Wu, X. T. Syntheses, crystal structures, spectroscopy, electrochemical and magnetic properties of four cyanido-bridged M^Ⅱ–Mn^Ⅲ (M = Fe, Ru, Os) complexes. J. Coord. Chem. 2015, 68, 55–70. doi: 10.1080/00958972.2014.981537
23. [23]
  Bryant, G.; Fergusson, J.; Powell, H. Charge-transfer and intraligand electronic spectra of bipyridyl complexes of iron, ruthenium, and osmium. I. Bivalent complexes. Aust. J. Chem. 1971, 24, 257–273. doi: 10.1071/CH9710257
24. [24]
  Schilte, A. A. Proton affinities of some cyanide and aromatic diimine complexes of iron, ruthenium and osmium. J. Am. Chem. Soc. 1963, 85, 904–908. doi: 10.1021/ja00890a016
25. [25]
  Schilt, A. A. Unusual proton affinities of some mixed ligand iron(Ⅱ) complexes. J. Am. Chem. Soc. 1960, 82, 5779–5783. doi: 10.1021/ja01507a004
26. [26]
  Qiao, N.; Wei, N. N.; Zhang, J. N.; Hao, C. The dual-luminescence mechanism of the ESIPT chemosensor tetrasubstituted imidazole core compound: a TDDFT study. New J. Chem. 2018, 42, 11804–11810. doi: 10.1039/C8NJ01162A
27. [27]
  Ernsting, N. P.; Breffke, J.; Vorobyev, D. Y.; Duncan, D. A.; Pfeffer, I. Sub-picosecond. fluorescence evolution of amino-cyano-stilbenes in methanol: polar solvation obeys continuum theory without evidence of twisting. Phys. Chem. Chem. Phys. 2008, 10, 2043–2049. doi: 10.1039/b717541h
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