Citation: Meng-Yao ZHANG, Ying-Ying ZHANG, Hui-Xin ZHANG, Shen WANG, Ya-Qi WANG, Yong-Fei ZENG, Gui-Yan LIU. Synthesis, Crystal Structure and Catalytic Activity Palladium(Ⅱ) Complexes Containing Bulky Azole Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1669-1674. doi: 10.14102/j.cnki.0254-5861.2011-2660 shu

Synthesis, Crystal Structure and Catalytic Activity Palladium(Ⅱ) Complexes Containing Bulky Azole Ligands

Tianjin Key Laboratory of Structure and Performance for Functional Molecules; Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry (Tianjin Normal University), Ministry of Education; College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Corresponding author: Yong-Fei ZENG, yfzeng@nankai.edu.cn Gui-Yan LIU, guiyanliu2013@163.com
Received Date: 6 November 2019
Accepted Date: 19 December 2019

Fund Project: the Natural Science Foundation of Tianjin 16JCYBJC19700the National Natural Science Foundation of China 21771138

Figures(3)

Bulky azole ligands in combination with PdCl₂ provide three new palladium(Ⅱ) complexes. All these complexes, as pre-catalysts, have high catalytic efficiency for the Suzuki-Miyaura cross-coupling reactions of sterically hindered aryl chlorides and good to high yields are obtained with low catalysts loadings (0.1 mol%) under mild conditions in air.
- palladium(Ⅱ) complexes,
- crystal structure,
- catalytic activity,
- Suzuki-Miyaura cross-coupling,
- sterically hindered aryl chlorides
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