Citation: Yu-Quan FENG, Zhi-Guo ZHONG, Jing LI. Synthesis, Structure, Fluorescence and Magnetic Properties of a New Binuclear Cobalt(Ⅱ) Complex Containing Three Kinds of Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1070-1076. doi: 10.14102/j.cnki.0254-5861.2011-2659 shu

Synthesis, Structure, Fluorescence and Magnetic Properties of a New Binuclear Cobalt(Ⅱ) Complex Containing Three Kinds of Ligands

College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China

Corresponding author: Yu-Quan FENG, yqfeng2008@126.com
Received Date: 6 November 2019
Accepted Date: 19 January 2020

Fund Project: the National Natural Science Foundation of China 21601095

Figures(5)

A new binuclear cobalt(Ⅱ) complex, [Co₂(C₁₀H₆NO₂)₂(C₁₂H₈N₂)₂(N₃)₂]·H₂O (1, C₁₀H₆NO₂^-: isoquinoline-1-carboxylate, C₁₂H₈N₂: 1, 10-phenanthroline (phen); N₃^-: azide), has been synthesized though a mixed-solvothermal method using the pentanol and distilled water as solvent. The complex was characterized by elemental analysis, IR spectrum and single-crystal X-ray diffraction. It crystallizes in triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with Z = 2, a = 1.777(5), b = 11.815(5), c = 17.141(7) Å, α = 74.496(6)°, β = 70.537(6)°, γ = 67.861(6)°, V = 2055.4(14) Å³, M_r = 922.66, D_c = 1.491 g/cm³, λ = 0.71073 Å, μ = 0.870 mm^-1, F(000) = 942, R = 0.0455 and wR = 0.1147 for 4960 observed reflections with I > 2σ(I) and S = 1.129. Its molecular structure is constructed by two Co²⁺ cations, two chelating phen ligands, two chelating isoquinoline-1-carboxylate ligands, two bridging linear azide anions and two uncoordinated half-occupied water molecules. The 3-D supramolecular network results from the multiple hydrogen bonds and π-π stacking interactions among three types of ligands. More importantly, its thermal stability, luminescent properties and magnetic properties have also been studied in detail.
- binuclear cobalt(Ⅱ) complex,
- thermal stability,
- fluorescence decay,
- magnetic properties
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