Citation: Jian-Hua LI, Xiao-Zhong WANG, Hai-Wen WEI, Qin HOU, Xiao-Yong LAI, Xiang-Yu LIU, Qing-Feng YANG. Syntheses, Crystal Structures and Magnetic Properties of Two New Low-dimensional Manganese(Ⅱ) Coordination Compounds[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1077-1086. doi: 10.14102/j.cnki.0254-5861.2011-2656 shu

Syntheses, Crystal Structures and Magnetic Properties of Two New Low-dimensional Manganese(Ⅱ) Coordination Compounds

a.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering Ningxia University Yinchuan 750021, China
b.
College of Chemistry and Materials Science, Shandong Agricultural University, Taian 271018, China

Corresponding author: Xiao-Zhong WANG, xzwang@nxu.edu.cn Qing-Feng YANG, yangqf@nxu.edu.cn
Received Date: 4 November 2019
Accepted Date: 2 January 2020

Fund Project: the Scientific Research Foundation of the Higher Education Institutions of Ningxia NGY2017042the National Natural Science Foundation of China 21961027the National Natural Science Foundation of China 21461020the Natural Science Foundation of Ningxia 2019AAC03071the National First-rate Discipline Construction Project of Ningxia (Chemical Engineering and Technology) NXYLXK2017A04

Figures(9)

Two new low-dimensional Mn(Ⅱ) coordination compounds of Mn(H₂pimdc)₂(phen) (compound 1) and [Mn(Hpimdc)(phen)]_n·nH₂O (compound 2) were synthesized, where H₃pimdc is a 2-propyl-imidazole-4, 5-dicarboxylic acid and phen is 1, 10-phenanthroline. Both compounds were thoroughly analyzed by X-ray single-crystal diffraction, element analysis, IR spectra, PXRD and thermal analysis. X-ray single-crystal diffraction analyses indicate that the phen ligands terminate metal ions on two sides to prevent the linkage between the neighboring metal ions into a higher dimensional structure in compounds 1 and 2. Compound 1 is constructed from mononuclear molecules which form the 1D helical supramolecular chain by N–H···O hydrogen bonds. In compound 2, Hpimdc is a tetradentate bridging ligand, which binds Mn(Ⅱ) ions to generate a single-stranded right helical chain parallel to the b axis. These 1D chains are additionally coupled by H-bonds as well as π···π stacking interactions, which formed a 3D supramolecular structure. Additionally, compound 2 demonstrated temperature-dependent magnetic susceptibility and negative value of θ (equal to –9.09 K), which is indicative of weak antiferromagnetic interactions between Mn(Ⅱ) ions.
- low-dimensional coordination compounds,
- helical structure,
- magnetic properties
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