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Citation: Jin-Yang LI, Lin WANG, Zhi-Ying ZHAO, Zhang-Zhen HE. Synthesis, Structure, and Magnetic Properties of a New Selenite Compound CdNi(SeO3)2(H2O)2[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1694-1698. doi: 10.14102/j.cnki.0254-5861.2011-2646 shu

Synthesis, Structure, and Magnetic Properties of a New Selenite Compound CdNi(SeO3)2(H2O)2

  • a.

    College of Chemistry, Fuzhou University, Fuzhou 350108, China

  • b.

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Mater, Chinese Academy of Sciences, Fuzhou 350002, China

  • Corresponding author: Zhang-Zhen HE, hezz@fjirsm.ac.cn; hcz1988@hotmail.com
  • Received Date: 24 October 2019
    Accepted Date: 13 December 2019

    Fund Project: the National Natural Science Foundation of China 21573235the National Natural Science Foundation of China U1632159the National Natural Science Foundation of China 21875249

Figures(5)

  • A new selenite compound CdNi(SeO3)2(H2O)2 has been obtained by a conventional hydrothermal method. This compound crystallizes in monoclinic system of space group C2/c, which exhibits a layer structure built by NiO6 octahedra and SeO3 trigonal pyramids running along the a-axis. The layers show a unique eight-rings hole network. The compound is stable at room temperature while the loss of H2O molecules happens with heating above 523 K. Magnetic measurements indicate that CdNi(SeO3)2(H2O)2 is an antiferromagnet and possesses an antiferromagnetic ordering at TN = 15 K.
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