Citation: Xu-Min CAI, Xin-Fei CHEN, Tian-Qi MU, Yu-Ting LIN, Shen-Lin HUANG, Min-Xia YAO. Syntheses, Crystal Structures, and Electrochemical Properties of Dehydroabietic Acid-based Schiff Bases[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1699-1706. doi: 10.14102/j.cnki.0254-5861.2011-2639 shu

Syntheses, Crystal Structures, and Electrochemical Properties of Dehydroabietic Acid-based Schiff Bases

a.
College of Chemical Engineering, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, China
b.
School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

Corresponding author: Xu-Min CAI, xumin.cai@njfu.edu.cn Shen-Lin HUANG, shuang@njfu.edu.cn Min-Xia YAO, yaomx@njtech.edu.cn
Received Date: 14 October 2019
Accepted Date: 8 February 2020

Fund Project: the National Natural Science Foundation of China 21601087the National Natural Science Foundation of China 21401101the Topnotch Academic Programs Project TAPPthe Priority Academic Program Development of Jiangsu Higher Education Institution PAPD

Figures(3)

Two Schiff bases (DAMBA-Fc and DAA-Fc) derived from dehydroabietic acid have been successfully synthesized and characterized by means of FT-IR, elemental analysis, HRMS, and NMR spectroscopy. The crystal structure of DAA-Fc can be determined by single-crystal X-ray diffraction. The compound is of monoclinic system, space group P2₁ with a = 10.7379(6), b = 7.5004(4), c = 33.3294(18) Å, β = 97.996(3)º, Z = 4, V = 2658.2(3) Å³, M_r = 481.48, D_c = 1.203 g/cm³, S = 1.034, μ = 0.585 mm^-1, F(000) = 1032, the final R = 0.0566 and wR = 0.0701 for 5645 observed reflections (I > 2σ(I)). In addition, cyclic and differential pulse voltammogram techniques have been applied to differentiate the redox properties of the aromatic- and aliphatic-connected Schiff bases DAMBA-Fc and DAA-Fc, respectively.
- dehydroabietic acid,
- ferrocene,
- Schiff base,
- crystal structure,
- electrochemical properties
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