Citation: Zhi SHEN, Bao-Min LUO, Hai-Quan XIE, Qiang ZHAO. Tricarboxy Ligand Cu^Ⅱ Metal-organic Framework with Magnetic and Proton Conduction Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(9): 1689-1693. doi: 10.14102/j.cnki.0254-5861.2011-2637 shu

Tricarboxy Ligand Cu^Ⅱ Metal-organic Framework with Magnetic and Proton Conduction Properties

College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, China

Corresponding author: Hai-Quan XIE, xie-hq@163.com Qiang ZHAO, zhaoqiang0522@126.com
Received Date: 11 October 2019
Accepted Date: 12 December 2019

Fund Project: University Key Scientific Research Project of Henan Province 19B150014

Figures(4)

Hydrothermal reaction of Cu(NO₃)₂·3H₂O and 4-(4-carboxyphenoxy)isophthalic acid (H₃cpia) results in a two-dimensional coordination polymer based on paddle-wheel-like dinuclear clusters, namely [C₆₀H₅₄Cu₄O₃₉]_n (1). Complex 1 is of triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 10.7318(18), b = 12.267(2), c = 14.528(2) Å, α = 113.560(2)º, β = 96.156(3)º, γ = 103.552(3)º, V = 1660.5(5) Å³, Z = 1, S = 1.057, F(000) = 842, R = 0.0517 and wR = 0.1426 (I > 2σ(I)). In this structure, tricarboxylate liagnds are partial deprotonation and potenial proton carriers. Strong antiferromagnetic interaction between Cu^Ⅱ ions exists within the Cu₂ cluster and complex 1 exhibits relatively high proton conductivity (σ > 1.23 × 10^-5 S⋅cm^-1) at 76% relative humidity (RH).
- metal-organic framework,
- tricarboxylate ligands,
- magnetic properties,
- proton conductivity
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沈阳化工大学材料科学与工程学院沈阳 110142

Tricarboxy Ligand CuⅡ Metal-organic Framework with Magnetic and Proton Conduction Properties

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通讯作者: 陈斌, bchen63@163.com

Tricarboxy Ligand Cu^Ⅱ Metal-organic Framework with Magnetic and Proton Conduction Properties