Citation: Zi-Wei CAI, Jie SUN, Ye-Ting PAN, Ting-Ting JIANG, Qing LI, Pei-Pei CUI, Jie ZHANG. Synthesis of a Rare Doubly-interpenetrating Zinc(Ⅱ) Coordination Polymer for Applications in Photocatalysis[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 718-726. doi: 10.14102/j.cnki.0254-5861.2011-2617 shu

Synthesis of a Rare Doubly-interpenetrating Zinc(Ⅱ) Coordination Polymer for Applications in Photocatalysis

Zi-Wei CAI ^a ,
Jie SUN ^a,, ,
Ye-Ting PAN ^a ,
Ting-Ting JIANG ^a ,
Qing LI ^a ,
Pei-Pei CUI ^b ,
Jie ZHANG ^a

a.
School of Life Science, Ludong University, Yantai 264025, China
b.
College of Life Science, Dezhou University, Dezhou 253023, China

Corresponding author: Jie SUN,
Received Date: 24 September 2019
Accepted Date: 24 December 2019

Fund Project: the National Natural Science Foundation of China 21401096the National Natural Science Foundation of China 21701021

Figures(6)

A rare doubly-interpenetrating Zn-MOF (complex 1), formulated as {[Zn(tci)-(bpy)(NO₃)·DMF·0.5CH₃CN}_n (H₃tci = tri(2-carboxyethyl) isocyanurate, bpy = 4,4-bipyridine), has been constructed under solvothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy (IR) and powder X-ray diffraction (PXRD). 1 crystallizes in monoclinic system, space group C2/c with a = 21.5759(4), b = 12.87221(18), c = 26.4917(5) Å, β = 109.462(2)°, V = 6937.1(2) Å³, C₅₀H₅₆N₁₄O₂₇Zn₄, M_r = 1546.56, Z = 4, D_c = 1.481 g·cm^-3, μ = 2.325 mm^-1 λ = 1.54178 Å, F(000) = 3160, S = 1.041, R = 0.0621 and wR = 0.1773. 1 features a two-fold interpenetrating 3D hms topology. Moreover, the thermal stabilities, fluorescent and CO₂ adsorption properties were investigated. Complex 1 showed highly encouraging photocatalytic degradation of toxic dye molecules with a potential application in wastewater purification.
- Zn-MOF,
- solvothermal conditions,
- thermal stabilities,
- CO₂ adsorption,
- fluorescent property,
- photocatalytic performance
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