Citation: Li-Jun ZHAI, Chen-Xu JIAO, Jin-Fang LIANG, Jie ZHANG, Xiao-Yan NIU, Tuo-Ping HU, Yu-Lan NIU. Two New Coordination Polymers Based on H₄BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe³⁺ Ion[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 772-782. doi: 10.14102/j.cnki.0254-5861.2011-2562 shu

Two New Coordination Polymers Based on H₄BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe³⁺ Ion

Li-Jun ZHAI ^{a, b} ,
Chen-Xu JIAO ^a ,
Jin-Fang LIANG ^a ,
Jie ZHANG ^a ,
Xiao-Yan NIU ^a ,
Tuo-Ping HU ^a,, ,
Yu-Lan NIU ^b,,

a.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China
b.
Taiyuan Institute of Technology, Department of Chemistry and Chemical Engineering, Taiyuan 030008, China

Corresponding author: Tuo-Ping HU, hutuoping@nuc.edu.cn Yu-Lan NIU, niuyulan@163.com
Received Date: 6 August 2019
Accepted Date: 14 January 2020

Fund Project: the NSFC 21676258the International Scientific and Technological Cooperation Projects of Shanxi Province 201803D421080

Figures(8)

Based on the solvothermal reaction of 5,5΄-(1,3,6,8-tetraoxobenzo[lmn][3,8] phenanthrolin-2-7-diyl)bis-1,3-benzenedicarboxylic acid (H₄L) linker and Zn(Ⅱ)/Cd(Ⅱ), two new 2D coordination polymers (CPs), namely {[ZnH₂L(4,4΄-bibp)]·H₂O}_n (1) and {[CdL_0.5(1,4-bimb)_0.5(H₂O)]·EtOH}_n (2) (L = BIPA-TC), have been successfully constructed and characterized by EA, PXRD and IR with the aid of 4,4΄-bis(benzoimidazo-1-yl)biphenyl(4,4΄-bbib)/1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bimb). The structural analysis showed that complex 1 exhibits a 3D supramolecular structure with the topology of sql, and complex 2 possesses a 2-nodal (4,6)-c framework with the topology of (3²·4²·5²)(3⁴·4⁴·5⁴·6³)-4,6T26. Fluorescent experiments showed that 1 and 2 have high selectivity and sensitivity for the sensing of nitroaromatic compounds and Fe³⁺ in aqueous solutions.
- fluorescence sensing,
- crystal structure,
- coordination polymers
1. [1]
  Sun, Y. H.; Han, H. A novel 3D AgI cationic metal-organic framework based on 1,2,4,5-tetra(4-pyridyl)benzene with selective adsorption of CO₂ over CH₄, H₂O over C₂H₅OH, and trapping Cr₂O₇^2–. J. Mol. Struct. 2019, 1194, 73–77. doi: 10.1016/j.molstruc.2019.05.070
2. [2]
  Dias, H. R.; Diyabalanage, H. V.; Ghimire, M. M.; Hudson, J. M.; Parasar, D.; Gamage, C. S. P.; Omary, M. A. Brightly phosphorescent tetranuclear copper(Ⅰ) pyrazolates. Dalton Trans. 2019, 48, 14979–14983. doi: 10.1039/C9DT03402A
3. [3]
  Cheng, S.; Wu, Y. L.; Jin, J.; Liu, J.; Wu, D.; Yang, G. P.; Wang, Y. Y. New multifunctional 3D porous metal-organic framework with selective gas adsorption, efficient chemical fixation of CO₂ and dye adsorption. Dalton Trans. 2019, 48, 7612–7618. doi: 10.1039/C9DT01249D
4. [4]
  Gao, L. L.; Zhang, J.; Zhai, L. J.; Wang, X. Q.; Hu, T. P. Gas adsorption and fluorescent sensing properties of two porous lanthanide metal-organic frameworks based on 3,5-bis(2-carboxy-phenoxy)-benzoic acid. Polyhedron. 2019, 165, 171–176. doi: 10.1016/j.poly.2018.12.015
5. [5]
  Holub, J.; Santoro, A.; Lehn, J. M. Electronic absorption and emission properties of bishydrazone [2×2] metallosupramolecular grid-type architectures. Inorg. Chim. Acta. 2019, 494, 223–231. doi: 10.1016/j.ica.2019.05.017
6. [6]
  Mocanu, T.; Kiss, L.; Sava, A.; Shova, S.; Silvestru, C.; Andruh, M. Coordination polymers and supramolecular solid-state architectures constructed from an organometallic tecton, bis(4-pyridyl) mercury. Polyhedron. 2019, 166, 7–16. doi: 10.1016/j.poly.2019.03.020
7. [7]
  Xia, Q. Y.; Feng, M. Y.; Ma, D. X.; Shi, S. M.; Xie, Y. C.; Tian, W.; Shi, H. J.; Wang, Q. L.; Wang, W. M. Structures, luminescent properties and magnetic refrigeration of two series of Ln2^Ⅲ compounds. Polyhedron. 2019, 166, 141–145. doi: 10.1016/j.poly.2019.03.040
8. [8]
  Li, Z. H.; Xue, L. P.; Qin, Q. P.; Zhang, J.; Wang, J. M.; Zhang, X. Y.; Zhao, B. T. A zinc(Ⅱ) coordination polymer material with Lewis basic pyridyl sites: structure, photoluminescence, and heterogeneous catalysis. J. Solid State Chem. 2019, 274, 81–85. doi: 10.1016/j.jssc.2019.03.020
9. [9]
  Pandey, S.; Kumar, G.; Gupta, R. Postfunctionalized metalloligand-based catenated coordination polymers: syntheses, structures, and effect of labile sites on catalysis. Cryst. Growth Des. 2019, 19, 2723–2735. doi: 10.1021/acs.cgd.8b01848
10. [10]
  Chen, D. M.; Wu, X. F.; Liu, Y. J.; Huang, C.; Zhu, B. X. Synthesis, crystal structures and vapor adsorption properties of Hg(Ⅱ) and Cd(Ⅱ) coordination polymers derived from two hydrazone Schiff base ligands. Inorg. Chim. Acta. 2019, 494, 181–186. doi: 10.1016/j.ica.2019.05.026
11. [11]
  Zhang, J.; Gao, L. L.; Wang, Y.; Zhai, L. J.; Wang, X. Q.; Niu, X. Y.; Hu, T. P. Fluorescence sensing and magnetic properties of three coordination polymers based on 6-(3,5-dicarboxylphenyl)nicotinic acid and pyridine/imidazole linkers. New J. Chem. 2019, 43, 9376–9383. doi: 10.1039/C9NJ00682F
12. [12]
  Zhang, J.; Gao, L. L.; Wang, Y.; Zhai, L. J.; Wang, X. Q.; Hu, T. P. Two trinuclear cluster-based 3D interpenetrated metal-organic frameworks with selective adsorption and antiferromagnetic properties. J. Solid State Chem. 2019, 271,303–308. doi: 10.1016/j.jssc.2019.01.003
13. [13]
  Zhang, J.; Gao, L. L.; Wang, Y.; Zhai, L. J.; Wang, X. Q.; Niu, X. Y.; Hu, T. P. Luminescent and magnetic properties of two novel coordination polymers based on N-heterocyclic carboxylic acid. J. Solid State Chem. 2019, 277, 356–362. doi: 10.1016/j.jssc.2019.06.030
14. [14]
  Zhang, J.; Gao, L. L.; Wang, Y.; Zhai, L. J.; Niu, X. Y.; Hu, T. P. A bifunctional 3D Tb-based metal-organic framework for sensing and removal of antibiotics in aqueous medium. CrystEngComm. 2019, 21, 7286–7292. doi: 10.1039/C9CE01303B
15. [15]
  Zhang, J.; Gao, L. L.; Zhai, L. J.; Wang, X. Q.; Fan, L. M.; Hu, T. P. Gas adsorption, magnetic, and fluorescent sensing properties of four coordination polymers based on 1,3,5-tris(4-carbonylphenyloxy) benzene and bis(imidazole) linkers. CrystEngComm. 2018, 20, 7666–7676. doi: 10.1039/C8CE01421C
16. [16]
  Xiao, Q. Q.; Liu, D.; Wei, Y. L.; Cui, G. H. A new multifunctional two-dimensional cobalt(Ⅱ) metal-organic framework for electrochemical detection of hydrogen peroxide, luminescent sensing of metal ions, and photocatalysis. Polyhedron 2019, 158, 342–351. doi: 10.1016/j.poly.2018.11.016
17. [17]
  Luggar, R. D.; Farquharson, M. J.; Horrocks, J. A.; Lacey, R. J. X-ray Spectrom. 1998, 27, 87. doi: 10.1002/(SICI)1097-4539(199803/04)27:2<87::AID-XRS256>3.0.CO;2-0
18. [18]
  Wang, R.; Zhang, M.; Liu, X.; Zhang, L.; Kang, Z.; Wang, W.; Sun, D. Tuning the dimensionality of interpenetration in a pair of framework-catenation isomers to achieve selective adsorption of CO₂ and fluorescent sensing of metal ions. Inorg. Chem. 2015, 54,6084–6086. doi: 10.1021/acs.inorgchem.5b00934
19. [19]
  Wang, W.; Yang, J.; Wang, R.; Zhang, L.; Yu, J.; Sun, D. Luminescent terbium-organic framework exhibiting selective sensing of nitroaromatic compounds (NACs). Cryst. Growth Des. 2015, 15, 2589–2592. doi: 10.1021/acs.cgd.5b00381
20. [20]
  Anferov, V. P.; Mozjoukhine, G. V.; Fisher, R. Pulsed spectrometer for nuclear quadrupole resonance for remote detection of nitrogen in explosives. Rev. Sci. Instrum. 2000, 71, 1656–1659. doi: 10.1063/1.1150514
21. [21]
  Ren, G. H.; Gao, L. L.; Wang, X. Q.; Hu, T. P. Highly fluorescent selectivity of two Cd(Ⅱ) coordination networks with active sites for nitroaromatic compounds and Fe³⁺ and Hg²⁺. Inorg. Chim. Acta 2018, 471, 746–753. doi: 10.1016/j.ica.2017.12.018
22. [22]
  Dallas, P.; Rašović, I.; Puchtler, T.; Taylor, R. A.; Porfyrakis, K. Long Stokes Shifts and vibronic couplings in perfluorinated polyanilines. Chem. Commun. 2017, 53, 2602–2605. doi: 10.1039/C7CC00471K
23. [23]
  Hu, Y.; Ding, M.; Liu, X. Q.; Sun, L. B.; Jiang, H. L. Rational synthesis of an exceptionally stable Zn(Ⅱ) metal-organic framework for the highly selective and sensitive detection of picric acid. Chem. Commun. 2016, 52, 5734–5737. doi: 10.1039/C6CC01597B
24. [24]
  Bogale, R. F.; Ye, J.; Sun, Y.; Sun, T.; Zhang, S.; Rauf, A.; Hang, C.; Tian, P.; Ning, G. Highly selective and sensitive detection of metal ions and nitroaromatic compounds by an anionic europium(Ⅲ) coordination polymer. Dalton Trans. 2016, 45, 11137–11144. doi: 10.1039/C6DT01636G
25. [25]
  Xu, H.; Hu, H. C.; Cao, C. S.; Zhao, B. Lanthanide organic framework as a regenerable luminescent probe for Fe³⁺. Inorg. Chem. 2015, 54,4585–4587. doi: 10.1021/acs.inorgchem.5b00113
26. [26]
  Xu, H.; Cao, C. S.; Kang, X. M.; Zhao, B. Lanthanide-based metal-organic frameworks as luminescent probes. Dalton Trans. 2016, 45, 18003–18017. doi: 10.1039/C6DT02213H
27. [27]
  Pan, M.; Lin, X. M.; Li, G. B.; Su, C. Y. Progress in the study of metal-organic materials applying naphthalene diimide (NDI) ligands. Coord. Chem. Rev. 2011, 255(15–16), 1921–1936.
28. [28]
  Li, D. S.; Zhang, P.; Zhao, J.; Fang, Z. F.; Du, M.; Zou, K.; Mu, Y. Q. Two unique entangling Cd^Ⅱ-coordination frameworks constructed by square Cd4-building blocks and auxiliary N, N΄-donor ligands. Cryst. Growth Des. 2012, 12, 1697–1702. doi: 10.1021/cg300036y
29. [29]
  Li, D. S.; Wu, Y. P.; Zhao, J.; Zhang, J.; Lu, J. Y. Metal-organic frameworks based upon non-zeotype 4-connected topology. Coord. Chem. Rev. 2016, 261, 1–27.
30. [30]
  Pang, L. Y.; Yang, G. P.; Jin, J. C.; Kang, M.; Fu, A. Y.; Wang, Y. Y.; Shi, Q. Z. A rare L1D + R1D → 3D luminescent dense polymer as multifunctional sensor to nitro aromatic compounds, Cu²⁺, and bases. Cryst. Growth Des. 2014, 14, 2954–2961. doi: 10.1021/cg5002418
31. [31]
  Sheldrick, G. M. SHELXL-97, Germany 1997.
32. [32]
  Blatov, V. A. Nanocluster analysis of intermetallic structures with the program package TOPOS. Struct. Chem. 2012, 23, 955. doi: 10.1007/s11224-012-0013-3
33. [33]
  Wang, X. X.; Wang, X. Q.; Niu, X. Y.; Hu, T. P. Three novel metal-organic frameworks based on an unsymmetrical rigid carboxylate ligand for luminescence sensing of nitrobenzene derivatives and magnetic properties. CrystEngComm. 2016, 18, 7471–7477. doi: 10.1039/C6CE01457G
34. [34]
  Sohn, H.; Sailor, M. J.; Magde, D.; Trogler, W. C. Detection of nitroaromatic explosives based on photoluminescent polymers containing metalloles. J. Am. Chem. Soc. 2003, 125, 3821–3830. doi: 10.1021/ja021214e
35. [35]
  Gole, B.; Shanmugaraju, S.; Bar, A. K.; Mukherjee, P. S. Supramolecular polymer for explosives sensing: role of H-bonding in enhancement of sensitivity in the solid state. Chem. Commun. 2011, 47, 10046–10048. doi: 10.1039/c1cc13925h
36. [36]
  Dalapati, S.; Jin, S.; Gao, J.; Xu, Y.; Nagai, A.; Jiang, D. An azine-linked covalent organic framework. J. Am. Chem. Soc. 2013, 135, 17310–17313. doi: 10.1021/ja4103293
37. [37]
  Ganguly, A.; Paul, B. K.; Ghosh, S.; Kar, S.; Guchhait, N. Selective fluorescence sensing of Cu(Ⅱ) and Zn(Ⅱ) using a new Schiff base-derived model compound: naked eye detection and spectral deciphering of the mechanism of sensory action. Analyst 2013, 138, 6532–6541. doi: 10.1039/c3an00155e
38. [38]
  Liu, J.; Zhong, Y.; Lu, P.; Hong, Y.; Lam, W. Y.; Faisal, M.; Yu, Y.; Wong, K. S.; Tang, B. Z. A superamplification effect in the detection of explosives by a fluorescent hyperbranched poly(silylenephenylene) with aggregation-enhanced emission characteristics. Poly. Chem. 2010, 1,426–429. doi: 10.1039/C0PY00046A
39. [39]
  Dai, Y.; Zhou, H.; Song, X. D.; Zhang, J. J.; Hao, C.; Di, L.; Wang, Y. X.; Ni, J.; Wang, H. L. Two (5,5)-connected isomeric frameworks as highly selective and sensitive photoluminescent probes of nitroaromatics. CrystEngComm. 2017, 19, 2786–2794. doi: 10.1039/C7CE00236J
40. [40]
  Gong, W. J.; Ren, Z. G.; Li, H. X.; Zhang, J. G.; Lang, J. P. Cadmium(Ⅱ) coordination polymers of 4-pyr-poly-2-ene and carboxylates: construction, structure, and photochemical double [2+2] cycloaddition and luminescent sensing of nitroaromatics and mercury(Ⅱ) ions. Cryst. Growth Des. 2017, 17, 870–881. doi: 10.1021/acs.cgd.6b01728
41. [41]
  Rachuri, Y.; Parmar, B.; Bisht, K. K.; Suresh, E. Mixed ligand two dimensional Cd(Ⅱ)/Ni(Ⅱ) metal organic frameworks containing dicarboxylate and tripodal N-donor ligands: Cd(Ⅱ) MOF is an efficient luminescent sensor for detection of picric acid in aqueous media. Dalton Trans. 2016, 45, 7881–7892. doi: 10.1039/C6DT00753H
42. [42]
  Nagarkar, S. S.; Desai, A. V.; Samanta, P.; Ghosh, S. K. Aqueous phase selective detection of 2, 4,6-trinitrophenol using a fluorescent metal-organic framework with a pendant recognition site. Dalton Trans. 2019, 44, 15175–15180.
43. [43]
  Gole, B.; Bar, A. K.; Mukherjee, P. S. Modification of extended open frameworks with fluorescent tags for sensing explosives: competition between size selectivity and electron deficiency. Chem. Eur. J. 2014, 20, 2276–2291. doi: 10.1002/chem.201302455
44. [44]
  Nagarkar, S. S.; Joarder, B.; Chaudhari, A. K.; Mukherjee, S.; Ghosh, S. K. Highly selective detection of nitro explosives by a luminescent metal-organic framework. Angew. Chem. Int. Ed. 2013, 52, 2881–2885. doi: 10.1002/anie.201208885
45. [45]
  Wang, H. J.; Cheng, F. J.; Zou, C. C.; Li, Q. Q.; Hua, Y. Y.; Duan, J. G. Design and synthesis of luminescent porous coordination polymers for chromaticity modulation, sensing of nitrobenzene and iodine encapsulation. CrystEngComm. 2016, 18, 5639–5646. doi: 10.1039/C6CE00960C
46. [46]
  Wei, X. J.; Liu, D.; Li, Y. H.; Cui, G. H. New 2D and 3D Cd(Ⅱ) coordination polymers from aromatic dicarboxylate and 1,3-bis(5, 6-dimethylbenzimidazol-1-yl)-2-propanol ligands: syntheses, structures, photocatalytic, and luminescence sensing properties. J. Solid State Chem. 2019, 272, 138–147. doi: 10.1016/j.jssc.2019.02.011
47. [47]
  Zhao, J.; Wang, Y. N.; Dong, W. W.; Wu, Y. P.; Li, D. S.; Zhang, Q. C. A robust luminescent Tb(Ⅲ)-MOF with Lewis basic pyridyl sites for the highly sensitive detection of metal ions and small molecules. A robust luminescent Tb(Ⅲ)-MOF with Lewis basic pyridyl sites for the highly sensitive detection of metal ions and small molecules. Inorg. Chem. 2016, 55, 3265–3271. doi: 10.1021/acs.inorgchem.5b02294
48. [48]
  Hou, B. L.; Tian, D.; Liu, J.; Dong, L. Z.; Li, S. L.; Li, D. S.; Lan, Y. Q. A water-stable metal-organic framework for highly sensitive and selective sensing of Fe³⁺ ion. Inorg. Chem. 2016, 55, 10580–10586. doi: 10.1021/acs.inorgchem.6b01809
1. [1]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
2. [2]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
3. [3]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
4. [4]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
5. [5]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
6. [6]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
7. [7]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
10. [10]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
11. [11]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
12. [12]
  Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
13. [13]
  Shuwen SUN , Gaofeng WANG . Design and synthesis of a Zn(Ⅱ)-based coordination polymer as a fluorescent probe for trace monitoring 2, 4, 6-trinitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 753-760. doi: 10.11862/CJIC.20240399
14. [14]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
15. [15]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
16. [16]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
17. [17]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
18. [18]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
19. [19]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
20. [20]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(337)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Two New Coordination Polymers Based on H4BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe3+ Ion

Metrics

通讯作者: 陈斌, bchen63@163.com

Two New Coordination Polymers Based on H₄BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe³⁺ Ion