Citation: Li-Jun ZHAI, Chen-Xu JIAO, Jin-Fang LIANG, Jie ZHANG, Xiao-Yan NIU, Tuo-Ping HU, Yu-Lan NIU. Two New Coordination Polymers Based on H₄BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe³⁺ Ion[J]. Chinese Journal of Structural Chemistry, ;2020, 39(4): 772-782. doi: 10.14102/j.cnki.0254-5861.2011-2562 shu

Two New Coordination Polymers Based on H₄BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe³⁺ Ion

Li-Jun ZHAI ^{a, b} ,
Chen-Xu JIAO ^a ,
Jin-Fang LIANG ^a ,
Jie ZHANG ^a ,
Xiao-Yan NIU ^a ,
Tuo-Ping HU ^a,, ,
Yu-Lan NIU ^b,,

a.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China
b.
Taiyuan Institute of Technology, Department of Chemistry and Chemical Engineering, Taiyuan 030008, China

Corresponding author: Tuo-Ping HU, hutuoping@nuc.edu.cn Yu-Lan NIU, niuyulan@163.com
Received Date: 6 August 2019
Accepted Date: 14 January 2020

Fund Project: the NSFC 21676258the International Scientific and Technological Cooperation Projects of Shanxi Province 201803D421080

Figures(8)

Based on the solvothermal reaction of 5,5΄-(1,3,6,8-tetraoxobenzo[lmn][3,8] phenanthrolin-2-7-diyl)bis-1,3-benzenedicarboxylic acid (H₄L) linker and Zn(Ⅱ)/Cd(Ⅱ), two new 2D coordination polymers (CPs), namely {[ZnH₂L(4,4΄-bibp)]·H₂O}_n (1) and {[CdL_0.5(1,4-bimb)_0.5(H₂O)]·EtOH}_n (2) (L = BIPA-TC), have been successfully constructed and characterized by EA, PXRD and IR with the aid of 4,4΄-bis(benzoimidazo-1-yl)biphenyl(4,4΄-bbib)/1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bimb). The structural analysis showed that complex 1 exhibits a 3D supramolecular structure with the topology of sql, and complex 2 possesses a 2-nodal (4,6)-c framework with the topology of (3²·4²·5²)(3⁴·4⁴·5⁴·6³)-4,6T26. Fluorescent experiments showed that 1 and 2 have high selectivity and sensitivity for the sensing of nitroaromatic compounds and Fe³⁺ in aqueous solutions.
- fluorescence sensing,
- crystal structure,
- coordination polymers
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Two New Coordination Polymers Based on H4BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe3+ Ion

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Two New Coordination Polymers Based on H₄BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe³⁺ Ion