Citation: Jun-Yu ZHANG, Hong-Gang LIAO, Shi-Gang SUN. Construction of 1D/1D WO₃ Nanorod/TiO₂ Nanobelt Hybrid Heterostructure for Photocatalytic Application[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1019-1028. doi: 10.14102/j.cnki.0254-5861.2011-2553 shu

Construction of 1D/1D WO₃ Nanorod/TiO₂ Nanobelt Hybrid Heterostructure for Photocatalytic Application

State Key Lab of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Corresponding author: Hong-Gang LIAO, hgliao@xmu.edu.cn Shi-Gang SUN, sgsun@xmu.edu.cn
Received Date: 29 July 2019
Accepted Date: 5 November 2019

Fund Project: the National Natural Science Foundation of China 21673198the National Natural Science Foundation of China 21373008the National Natural Science Foundation of China 21621091

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In this work, well-defined 1D/1D WO₃ nanorod/TiO₂ nanobelt (WNR/TNB) hybrid heterostructure was fabricated by a simple electrostatic self-assembly method. The structure-property correlation was clarified by characterizing the crystal phases, morphologies, optical properties, photoluminescence and photocatalytic performances of the WNR/TNB heterostructures. It was demonstrated that photocatalytic performances of WNR/TNB heterostructure toward mineralization was superior to blank TNB, WNR and randomly mixed counterparts under simulated solar light irradiation, owing predominantly to the intimate interfacial contact between WNR and TNB, forming intimately integrated heterojunction, which promotes the spatial charge carriers transfer and electron relay, hence prolonging the lifetime of photogenerated electron-hole pairs. Moreover, photocatalytic mechanism was elucidated. It is anticipated that our work would provide an alternative strategy to construct diverse heterostructured photocatalysts for solar energy conversion.
- TiO₂ nanobelt,
- WO₃ nanorod,
- photocatalysis,
- intimate interfacial contact
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Construction of 1D/1D WO3 Nanorod/TiO2 Nanobelt Hybrid Heterostructure for Photocatalytic Application

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Construction of 1D/1D WO₃ Nanorod/TiO₂ Nanobelt Hybrid Heterostructure for Photocatalytic Application