Citation: Tian ZHANG, Yi-Jing ZHAO, Qiu-Pei QIN. Two N-donor Auxiliary Ligands Mediated Zn(Ⅱ) Coordination Polymers Incorporating 5-Nitro-1, 2, 3-benzenetricarboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(6): 1051-1056. doi: 10.14102/j.cnki.0254-5861.2011-2547 shu

Two N-donor Auxiliary Ligands Mediated Zn(Ⅱ) Coordination Polymers Incorporating 5-Nitro-1, 2, 3-benzenetricarboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties

College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Functionoriented Porous Materials, Luoyang Normal University, Luoyang 471934, China

Corresponding author: Tian ZHANG, tianjia199@163.com
Received Date: 23 July 2019
Accepted Date: 29 November 2019

Fund Project:

Figures(6)

Two N-donor auxiliary ligands mediated Zn(Ⅱ) coordination polymers, namely, {[Zn(Hnbta)-(bimm)](3H₂O)}_n (1) and {[Zn_1.5(nbta)(pyim)(H₂O)](2H₂O)}_n (2) (H₃nbta = 5-nitro-1, 2, 3-benzenetricarboxylic acid, bimm = bis(imidazol-1-yl)methane and pyim = N-(4-pyridylmethyl)imidazole), have been prepared by the hydrothermal reaction. Their structures were determined by single-crystal X-ray diffraction analysis, elemental analyses and infrared spectra. Compound 1 possesses a one-dimensional (1D) chain structure, while compound 2 features a two-dimensional (2D) network. In addition, they both exhibit high thermal stabilities and photoluminescent properties in the solid, and can be explored as potential luminescent materials.
- coordination polymer,
- 5-nitro-1,2,3-benzenetricarboxylic acid,
- bis(imidazol-1-yl)methane,
- N-(4-pyridylmethyl)imidazole,
- photoluminescent properties
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