Citation: Xiu-Mei LI, Ya-Rua PAN, Bo LIU, Shi ZHOU. Synthesis, Structural Characterization and Fluorescent Properties of a Cadmium Coordination Polymer with 4-Nitrophthalate and 1, 4-Bis(imidazol-1-yl)-benzene[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 955-959. doi: 10.14102/j.cnki.0254-5861.2011-2518 shu

Synthesis, Structural Characterization and Fluorescent Properties of a Cadmium Coordination Polymer with 4-Nitrophthalate and 1, 4-Bis(imidazol-1-yl)-benzene

Xiu-Mei LI ^a,, ,
Ya-Rua PAN ^a ,
Bo LIU ^b,, ,
Shi ZHOU ^b

a.
Faculty of Chemistry, Tonghua Normal University, Tonghua 134002, China
b.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China

Corresponding author: Xiu-Mei LI, lixm20032006@163.com Bo LIU, 112363305@qq.com
Received Date: 5 July 2019
Accepted Date: 16 September 2019

Fund Project: the Science and Technology development plan of Jilin Province 2015052006JH

Figures(6)

A new complex [Cd(nph)(bix)]_n (1, H₂nph = 4-nitrophthalic acid, bix = 1, 4-bis(imidazol-1-yl)-benzene) has been successfully synthesized under hydrothermal conditions. Its structure has been characterized by elemental analysis, IR spectrum, TG, single-crystal and powder X-ray diffractions. The Cd²⁺ ion has a distorted octahedral environment with four O atoms from two nph ligands and two N atoms from two bix ligands. Each bix acts as a cis-conformation bridging ligand to link the neighboring [Cd₂(nph)] subunit to form tetranuclear subunits with 42-ring, which are bridged again by bix ligands to yield a two-dimensional network structure. It was stabilized by C–H···O hydrogen bonding and π-π interactions, and extended into a 3D supramolecular architecture. Moreover, the luminescent properties of complex 1 have been investigated in the solid state.
- hydrothermal synthesis,
- crystal structure,
- 4-nitrophthalic acid,
- 1, 4-bis(imidazol-1-yl)-benzene,
- Cd(Ⅱ) complex
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