Citation: Xiu-Mei LI, Ya-Rua PAN, Bo LIU, Shi ZHOU. Synthesis, Structural Characterization and Fluorescent Properties of a Cadmium Coordination Polymer with 4-Nitrophthalate and 1, 4-Bis(imidazol-1-yl)-benzene[J]. Chinese Journal of Structural Chemistry, ;2020, 39(5): 955-959. doi: 10.14102/j.cnki.0254-5861.2011-2518 shu

Synthesis, Structural Characterization and Fluorescent Properties of a Cadmium Coordination Polymer with 4-Nitrophthalate and 1, 4-Bis(imidazol-1-yl)-benzene

Xiu-Mei LI ^a,, ,
Ya-Rua PAN ^a ,
Bo LIU ^b,, ,
Shi ZHOU ^b

a.
Faculty of Chemistry, Tonghua Normal University, Tonghua 134002, China
b.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China

Corresponding author: Xiu-Mei LI, lixm20032006@163.com Bo LIU, 112363305@qq.com
Received Date: 5 July 2019
Accepted Date: 16 September 2019

Fund Project: the Science and Technology development plan of Jilin Province 2015052006JH

Figures(6)

A new complex [Cd(nph)(bix)]_n (1, H₂nph = 4-nitrophthalic acid, bix = 1, 4-bis(imidazol-1-yl)-benzene) has been successfully synthesized under hydrothermal conditions. Its structure has been characterized by elemental analysis, IR spectrum, TG, single-crystal and powder X-ray diffractions. The Cd²⁺ ion has a distorted octahedral environment with four O atoms from two nph ligands and two N atoms from two bix ligands. Each bix acts as a cis-conformation bridging ligand to link the neighboring [Cd₂(nph)] subunit to form tetranuclear subunits with 42-ring, which are bridged again by bix ligands to yield a two-dimensional network structure. It was stabilized by C–H···O hydrogen bonding and π-π interactions, and extended into a 3D supramolecular architecture. Moreover, the luminescent properties of complex 1 have been investigated in the solid state.
- hydrothermal synthesis,
- crystal structure,
- 4-nitrophthalic acid,
- 1, 4-bis(imidazol-1-yl)-benzene,
- Cd(Ⅱ) complex
1. [1]
  Zhu, Q. L.; Tian, C. B.; Shen, C. J.; Sheng, T. L.; Hu, S. M.; Xu, X. T. A three-dimensional coordination polymer based on linear trinuclear copper(Ⅱ) clusters featuring a ferromagnetic exchange interaction. CrystEngComm. 2013, 15, 2120–2126. doi: 10.1039/c2ce26461g
2. [2]
  Chow, T. W. S.; Liu, Y.; Che, C. M. Practical manganese-catalysed highly enantioselective cis-dihydroxylation of electron-deficient alkenes and detection of a cis-dioxomanganese(V) intermediate by high resolution ESI-MS analysis. Chem. Commun. 2011, 47, 11204–11206. doi: 10.1039/c1cc11999k
3. [3]
  Wang, J.; Higgins, S. L. H.; Winkel, B. S. J.; Brewer, K. J. A new Os, Rh bimetallic with O₂ independent DNA cleavage and DNA photobinding with red therapeutic light excitation. Chem. Commun. 2011, 47, 9786–9788. doi: 10.1039/c1cc11562f
4. [4]
  Xie, L. X.; Hou, X. W.; Fan, Y. T.; Hou, H. W. Four three-dimensional coordination polymers constructed by 2-((1H-1, 2, 4-triazol-1-yl)methyl)-1H-imidazole-4, 5-dicarboxylate: syntheses, topological Structures, and magnetic properties. Cryst. Growth Des. 2012, 12, 1282–1291. doi: 10.1021/cg201287t
5. [5]
  Wen, Z. Z.; Wen, X. L.; Cai, S. L.; Zheng, S. R.; Fan, J.; Zhang, W. G. The construction of Cu(I)/Cu(Ⅱ) coordination polymers based on pyrazine-carboxylate: structural diversity tuned by in situ hydrolysis reaction. CrystEngComm. 2013, 15, 5359–5367. doi: 10.1039/c3ce26817a
6. [6]
  Li, X. M.; Sun, M.; Pan, Y. R. Synthesis, crystal structure and theoretical calculations of a nickel(Ⅱ) coordination polymer assembled by 4, 4΄-oxydibenzoic acid and 1, 3-bis(imidazol-1-ylmethyl)-benzene ligands. Chin. J. Struct. Chem. 2015, 34, 710–718.
7. [7]
  Li, X. M.; Wang, Q. W.; Liu, B. Synthesis and crystal structure of a new nickel(Ⅱ) complex with 2, 4-pyridinedicarboxylic acid and 1, 4-bis(imidazol-1-ylmethyl)-benzene) ligands. Chin. J. Struct. Chem. 2012, 31, 889–893.
8. [8]
  Li, G. F.; Wang, Y. N.; Wang, Q. W. Synthesis and crystal structure of two complexes of manganese, cadmium assembled by bis(imidazol) ligands. Chin. J. Inorg. Chem. 2014, 30, 2577–2583.
9. [9]
  Li, X. M.; Pan, Y. R.; Ji, J. Y.; Niu, Y. L.; Wang, Q. W. Synthesis, crystal structure and theoretical calculations of a cadmium(Ⅱ) coordination polymer assembled by 5-nitroisophthalic acid and 1, 3-bis(imidazol-1-ylmethyl)-benzene ligands. J. Inorg. Organomet. Polym. 2015, 25, 1069–1076. doi: 10.1007/s10904-015-0213-6
10. [10]
  Li, X. M.; Wang, Z. T.; Pan, Y. R.; Wang, Q. W.; Liu, B. Synthesis, crystal structure and theoretical calculations of two zinc, cobalt coordination polymers with 5-nitroisophthalic acid and 1, 4-bis(1H-benzimidazolyl)butane ligands. J. Inorg. Organomet. Poly. 2018, 28, 258–267. doi: 10.1007/s10904-017-0738-y
11. [11]
  Pan, Y. R.; Li, X. M.; Ji, J. Y.; Wang, Q. W. Synthesis, crystal structure, and theoretical calculations of two cobalt, nickel coordination polymers with 5-nitroisophthalic acid and bis(imidazol) ligands. Aust. J. Chem. 2016, 69, 1296-1304. doi: 10.1071/CH16110
12. [12]
  Sheldrick, G. M. SHELXS 97, Program for the Solution of Crystal Structure. University of Göttingen, Germany 1997.
13. [13]
  Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structure. University of Göttingen, Germany 1997.
14. [14]
  Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Duyne, R. P. V.; Hupp, J. T. Metal-organic framework materials as chemical sensors. Chem. Rev. 2012, 112, 1105–1125. doi: 10.1021/cr200324t
15. [15]
  Lin, J. D.; Long, X. F.; Lin, P.; Du, S. W. A series of cation-templated, polycarboxylate-based Cd(Ⅱ) or Cd(Ⅱ)/Li(I) frameworks with second-order nonlinear optical and ferroelectric properties. Cryst. Growth Des. 2010, 10, 146–157. doi: 10.1021/cg9007476
16. [16]
  Wen, L.; Lu, Z.; Lin, J.; Tian, Z.; Zhu, H.; Meng, Q. Syntheses, structures, and physical properties of three novel metal-organic frameworks constructed from aromatic polycarboxylate acids and flexible imidazole-based synthons. Cryst. Growth Des. 2007, 7, 93–99. doi: 10.1021/cg0604982
17. [17]
  Lin, J. G.; Zang, S. Q.; Tian, Z. F.; Li, Y. Z.; Xu, Y. Y.; Zhu, H. Z.; Meng, Q. J. Metal-organic frameworks constructed from mixed-ligand 1, 2, 3, 4-tetra-(4-pyridyl)-butane and benzene-polycarboxylate acids: syntheses, structures and physical properties. CrystEngComm. 2007, 9, 915–921. doi: 10.1039/b708389k
18. [18]
  Mohamed, G. G.; El-Gamel, N. E. A. Synthesis, investigation and spectroscopic characterization of piroxicam ternary complexes of Fe(Ⅱ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) with glycine and dl-phenylalanine. Spectrochim. Acta, Part A 2004, 60, 3141–3154. doi: 10.1016/j.saa.2004.01.035
19. [19]
  Mukhopadhyay, U.; Bernal, I. Self-assembled hexameric water clusters stabilized by a cyano-bridged trimetallic complex. Cryst. Growth Des. 2005, 5, 1687–1689. doi: 10.1021/cg0501940
20. [20]
  Li, G. L.; Liu, G. Z.; Huang, L. L.; Li, L.; Zhang, X. Ancillary ligand-mediated syntheses, structures and fluorescence of three Zn/Cd(Ⅱ) coordination polymers based on nitrobenzene dicarboxylate. J. Inorg. Organomet. Poly. 2014, 24, 617–623. doi: 10.1007/s10904-014-0024-1
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2. [2]
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9. [9]
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  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
12. [12]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
13. [13]
  Bairu Meng , Zongji Zhuo , Han Yu , Sining Tao , Zixuan Chen , Erik De Clercq , Christophe Pannecouque , Dongwei Kang , Peng Zhan , Xinyong Liu . Design, synthesis, and biological evaluation of benzo[4,5]thieno[2,3-d]pyrimidine derivatives as novel HIV-1 NNRTIs. Chinese Chemical Letters, 2024, 35(6): 108827-. doi: 10.1016/j.cclet.2023.108827
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  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
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19. [19]
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